Lithium dimethylamide

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Lithium dimethylamide Basic information
Product Name:Lithium dimethylamide
Synonyms:LITHIUM DIMETHYLAMIDE, 5 WT. % SUSPENSIO N IN HEXANES;Lithiumdimethylamide,95%;Methanamine, N-methyl-, lithium salt;lithium dimethylamide preparation;(Dimethylamino) lithium;Dimethylaminolithium;Dimethyllithioamine;N-Lithiodimethylamine
CAS:3585-33-9
MF:C2H8LiN
MW:53.03
EINECS:222-714-3
Product Categories:Chemical Synthesis;Organic Bases;Synthetic Reagents;metal amide
Mol File:3585-33-9.mol
Lithium dimethylamide Structure
Lithium dimethylamide Chemical Properties
Boiling point 68-70 °C
density 0.68 g/mL at 25 °C
Fp -23 °C
form Slurry
color White
Water Solubility Reacts violently with water.
Sensitive Air & Moisture Sensitive
BRN 3618233
CAS DataBase Reference3585-33-9
Safety Information
Hazard Codes F,C,N,Xn
Risk Statements 17-34-67-65-62-51/53-48/20-11-36/38
Safety Statements 9-16-26-29-33-36/37/39-45-62-27-61-36/37
RIDADR UN 3394 4.2/PG 1
WGK Germany 3
F 1-10
HazardClass 4.2
PackingGroup I
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
Lithium dimethylamide Usage And Synthesis
UsesIt is used in the synthesis of some d0 organoimido complexes of the early transition metals and in meta rearrangement in the reaction of triphenyl-(p-bromophenyl)-silane.
Lithium dimethylamide Preparation Products And Raw materials
Preparation ProductsTetrakis(dimethylamino)silane-->2-Dimethylaminopyridine-->Tris(i-propoxy)dimethylaminotitanium, 97%
Tag:Lithium dimethylamide(3585-33-9) Related Product Information
Lithium sulfide ALUMINUM CHLOROHYDRATE Aluminum hydroxide Lithium Aluminum Hydride Lithium (S)-4-Benzyl-2-oxazolidinone lithium salt Lithium diethylamide Lithium tetramethylpiperidide Lithium dicyclohexylamide Lithium dimethylamide Hexanes (R)-4-Benzyl-2-oxazolidinone lithium salt Hexane Lithium diisopropylamide mono(tetrahydrofuran) complex solution Lithium diisopropylamide