ChemicalBook > Product Catalog >Chemical Reagents >Organic reagents >Ethers >Glycidyl phenyl ether

Glycidyl phenyl ether

Glycidyl phenyl ether Suppliers list
Tel: +86 21 5161 9050/ 5187 7795
Products Intro: CAS:122-60-1
Purity:98% HPLC Package:5MG;10MG;50MG;100MG,1G,5G
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Products Intro: Product Name:Glycidyl phenyl ether
Purity:99% Package:5KG;1KG
Company Name: Xiamen AmoyChem Co., Ltd
Tel: +86 592-605 1114
Products Intro: Product Name:Glycidyl phenyl ether
Company Name: Hubei xin bonus chemical co. LTD
Tel: 86-13657291602
Products Intro: Product Name:Glycidyl phenyl ether
Purity:0.99 Package:5KG;1KG
Company Name: Alchem Pharmtech,Inc.
Tel: 8485655694
Products Intro: Product Name:2-(Phenoxymethyl)oxirane
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-21954

Lastest Price from Glycidyl phenyl ether manufacturers

  • Glycidyl phenyl ether
  • US $1.00 / KG
  • 2020-01-13
  • CAS:122-60-1
  • Min. Order: 1KG
  • Purity: 98%-99.9%
  • Supply Ability: 100kg
Glycidyl phenyl ether Basic information
Product Name:Glycidyl phenyl ether
Product Categories:Oxiranes;Simple 3-Membered Ring Compounds
Mol File:122-60-1.mol
Glycidyl phenyl ether Structure
Glycidyl phenyl ether Chemical Properties
Melting point 3.5 °C(lit.)
Boiling point 245-247 °C(lit.)
density 1.109 g/mL at 25 °C(lit.)
vapor density 5.2 (vs air)
vapor pressure 0.03 mm Hg ( 20 °C)
refractive index n20/D 1.531
Fp >230 °F
storage temp. Store below +30°C.
solubility 2.4g/l
form Liquid
color Clear colorless to yellow
Water Solubility 2.4 g/L (20 ºC)
BRN 2744
Exposure limitsTLV-TWA 6 mg/m3 (1 ppm) (ACGIH); 1 ppm (15 min) (NIOSH).
Stability:Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference122-60-1(CAS DataBase Reference)
NIST Chemistry ReferenceOxirane, (phenoxymethyl)-(122-60-1)
IARC2B (Vol. 47, 71) 1999
EPA Substance Registry SystemPhenyl glycidyl ether (122-60-1)
Safety Information
Hazard Codes T
Risk Statements 45-20-37/38-43-52/53-68
Safety Statements 53-45-61
WGK Germany 3
RTECS TZ3675000
Autoignition Temperature430 °C
HazardClass IRRITANT
HS Code 29109000
Hazardous Substances Data122-60-1(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 2150 mg/kg LD50 dermal Rabbit 1500 mg/kg
MSDS Information
2,3-Epoxypropylphenylether English
SigmaAldrich English
ACROS English
ALFA English
Glycidyl phenyl ether Usage And Synthesis
DescriptionThis monoglycidyl derivative is a reactive diluent in epoxy resins of the bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization was observed in many professions, such as in construction workers, marble workers, ceramic workers, and in a shoemaker.
Chemical Propertiescolourless liquid
Chemical PropertiesPhenyl glycidyl ether is a colorless liquid with an unpleasant sweet odor
UsesChemical intermediate with high solvency for halogenated materials
UsesPhenyl glycidyl ether (PGE) is used as anintermediate in organic syntheses.
Uses2-Phenylglycidyl ether is an organic synthesis; chemical intermediate with high solvency for halogenated materials; reactive diluent of epoxy-resin systems; forms chemical bonds with the resin during cure and accelerates the curing process.
Production MethodsPGE is synthesized by condensation of phenol with epichlorohydrin, with subsequent dehydrochlorination with caustic to form the epoxy ring.
Synthesis Reference(s)The Journal of Organic Chemistry, 50, p. 1784, 1985 DOI: 10.1021/jo00210a053
General DescriptionColorless liquid.
Air & Water ReactionsEthers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Slightly soluble in water.
Reactivity ProfileGlycidyl phenyl ether, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Health HazardPGE is a toxic compound exhibiting moderate irritant action and carcinogenicity inanimals. Application of 0.25 mg resulted insevere eye irritation in rabbits, while 500 mgcaused moderate skin irritation over a periodof 24 hours. Prolonged or repeated contactcan cause moderate irritation and skin sensitization in humans.
The symptoms of its toxicity in animalswere depression of the central nervous system and paralysis of the respiratory tract.Prolonged exposure caused changes in thekidney, liver, thymus, and testes, and lossof hair in rats. The toxicity of this compound in humans is low and the health hazardcan arise primarily from its skin-sensitizationaction.
LD50 value, oral (mice): 1400 mg/kg
DGE showed carcinogenicity in rats, causingnasal cancer.
Fire HazardGlycidyl phenyl ether is probably combustible.
Contact allergensThis monoglycidyl derivative is a reactive diluent in epoxy resins Bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization has been observed in many professions, such as in construction workers, marble workers, ceramic workers, and shoemakers.
Safety ProfileConfirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe eye and skin irritant. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a chemical intermediate. See also ETHERS
Potential ExposurePGE is used to increase storage time and stability of halogenated compounds; as a reactive diluent in uncured epoxy resins to reduce the viscosity of the uncured system for ease in casting; adhesive, and laminating applications. NIOSH once estimated that 8000 workers are potentially exposed to PGE.
CarcinogenicityChronic exposure of rats to 1 or 12ppm 6 hours/day, 5 days/week for 2 years caused an increased incidence of rhinitis, squamous metaplasia, and epidermal carcinomas of the nasal cavity.4 The IARC has determined that there is sufficient evidence for the carcinogenicity of PGE in animals and that it is possibly carcinogenic to humans.
ShippingUN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
IncompatibilitiesIncompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, amines, and curing agents. PGE can presumably form explosive peroxides
Waste DisposalConcentrated waste containing no peroxides-discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxidesperforation of a container of the waste from a safe distance followed by open burning.
Glycidyl phenyl ether Preparation Products And Raw materials
Raw materialsPotassium carbonate-->Epichlorohydrin
Preparation ProductsCORTEX ALDEHYDE 50 BENZYL ALCOHOL-->(S)-2-Oxiranylanisole-->3-Phenoxy-1-propanol-->TRANS-1,2-CYCLOHEXANEDIOL
Tag:Glycidyl phenyl ether(122-60-1) Related Product Information
[(2,4-dibromophenoxy)methyl]oxirane (S)-GLYCIDYL PHENYL ETHER,(S)-α-(2-Oxiranyl)anisole, (S)-Glycidyl phenyl ether 1-(2,3-Epoxypropoxy)-2-(1-methylpropyl) benzene Cresyl glycidyl ether (R)-α-(2-Oxiranyl)anisole, (R)-Glycidyl phenyl ether,(R)-GLYCIDYL PHENYL ETHER N,N-DIGLYCIDYL-4-GLYCIDYLOXYANILINE Hexafluoropropylene oxide 2-Ethylhexyl glycidyl ether PHENYL VALERATE PHENYL RESIN Resin epoxy BENZYL GLYCIDYL ETHER EPOXY ISOPROPYLPHENYLDIPHENYL PHOSPHATE Guaifenesin Phenyl salicylate Ethylene glycol diglycidyl ether 1,2,3-PROPANETRIOL GLYCIDYL ETHER