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| | 2-FLUORO-6-NITROBENZYL BROMIDE Basic information |
| Product Name: | 2-FLUORO-6-NITROBENZYL BROMIDE | | Synonyms: | 2-FLUORO-6-NITROBENZYL BROMIDE;2-Bromomethyl-1-fluoro-3-nitrobenzene;Benzene, 2-(bromomethyl)-1-fluoro-3-nitro-;2-Fluoro-6-nitrobenzyl bromide 98%;2-Fluoro-6-nitrobenzylbromide98%;2-(Bromomethyl)-1-fluoro-3-nitrobenzene, alpha-Bromo-2-fluoro-6-nitrotoluene;2-FLUORO-6-NITROBENZYL BROMIDE ISO 9001：2015 REACH;2-fluoro-6-nitrobenzyl bromide2-fluoro-6-nitrobenzyl bromide | | CAS: | 1958-93-6 | | MF: | C7H5BrFNO2 | | MW: | 234.02 | | EINECS: | 217-801-8 | | Product Categories: | API intermediates | | Mol File: | 1958-93-6.mol |  |
| | 2-FLUORO-6-NITROBENZYL BROMIDE Chemical Properties |
| Melting point | 53-54°C | | Boiling point | 275.5±25.0 °C(Predicted) | | density | 1.733±0.06 g/cm3(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | crystalline powder | | color | Yellow | | Water Solubility | Insoluble in water. | | Sensitive | Lachrymatory | | BRN | 2503670 | | CAS DataBase Reference | 1958-93-6(CAS DataBase Reference) |
| Hazard Codes | C | | Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39-45 | | RIDADR | 3261 | | Hazard Note | Corrosive/Lachrymatory | | HazardClass | 8 | | PackingGroup | II | | HS Code | 2904990090 |
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ALFA
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| | 2-FLUORO-6-NITROBENZYL BROMIDE Usage And Synthesis |
| Uses | Nitobenzyl ester based nonionic PAGs (NIPAG 2) NIPAG 2 was prepared from 2-fluoro-6-nitrobenzyl bromide with silver sulfonate. | | Synthesis | Add 1/3 kettle capacity of carbon tetrachloride solvent and measured azodiisobutyronitrile, 48% hydrogen bromide to the reaction kettle, stirring and heated with steam; heated to about 75 , at the same time, drop-addition of measured o-nitrotoluene and 30% hydrogen peroxide, to keep the temperature does not drop to maintain reflux, drop-addition time of about 3-4 hours; drop-addition is completed, continue to hold the reflux reaction for 1-2 hours, turn off the steam, reduce the temperature to Room temperature, take samples to analyze the content of o-nitrobenzyl bromide: liquid separation, the organic layer is washed three times with 20% NaHSO3 aqueous solution and water, and then distilled at atmospheric pressure to remove the carbon tetrachloride solvent; petroleum ether is used for recrystallization of the reaction solution, and then centrifuged the crystals, and cold petroleum ether is used for rinsing, and then the solid product of o-nitrobenzyl bromide is obtained as white color. |
| | 2-FLUORO-6-NITROBENZYL BROMIDE Preparation Products And Raw materials |
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