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3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate)

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3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Basic information
Product Name:3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate)
Synonyms:3,4,6-Tri-O-benzyl--D-mannopyranose 1,2-(Methyl Orthoacetate);3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate);1,2-O-(1-Methoxyethylidene)-3,4,6-tris-O-(phenylMethyl)-β-D-Mannopyranose;3,4,6-Tri-O-benzyl-1,2-O-(1-methoxyethylidene)-beta-D-mannopyranose min. 98%;β-D-Mannopyranose, 1,2-O-(1-Methoxyethylidene)-3,4,6-tris-O-(phenylMethyl)-;3,4,6-Tri-o-benzyl-1,2-o-(1-methoxyethylidene)-beta-D-mannopyranose;3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate);3,4,6-Tri-O-benzyl-1,2-O-(1-methoxyethylidene)-β-D-mannopyranose
CAS:16697-49-7
MF:C30H34O7
MW:506.59
EINECS:
Product Categories:Aromatics;Carbohydrates & Derivatives
Mol File:16697-49-7.mol
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Structure
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Chemical Properties
Melting point 74-76°C
Boiling point 601.1±55.0 °C(Predicted)
density 1.22±0.1 g/cm3(Predicted)
storage temp. Refrigerator
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Solid
color White to Off-White
Safety Information
MSDS Information
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Usage And Synthesis
Description3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(methyl orthoacetate) is a synthetic intermediate used in glycosylation reactions. Typically, the methyl orthoester protecting group is first removed by mild acid hydrolysis, producing a glycosyl donor. Removal of the O-benzyl protecting groups is performed late in the synthesis.
Chemical PropertiesWhite Solid
Uses3,4,6-Tri-O-benzyl-β-D-mannopyranose 1,2-(Methyl Orthoacetate) (cas# 16697-49-7) is a compound useful in organic synthesis.
References[1] JOSé R. MARINO-ALBERNAS. Synthesis and Growth Inhibitory Properties of Glycosides of 1-O-Hexadecyl-2-O-methyl-sn-glycerol, Analogs of the Antitumor Ether Lipid ET-18-OCH3 (Edelfosine)[J]. Journal of Medicinal Chemistry, 1996, 39 17: 3241-3247. DOI: 10.1021/jm960164j
[2] NILANJANA CHAKRABORTY  Marc d’Alarcao. An anionic inositol phosphate glycan pseudotetrasaccharide exhibits high insulin-mimetic activity in rat adipocytes[J]. Bioorganic & Medicinal Chemistry, 2005, 13 24: Pages 6732-6741. DOI: 10.1016/j.bmc.2005.07.020
3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate) Preparation Products And Raw materials
Tag:3,4,6-Tri-O-benzyl-beta-D-mannopyranose-1,2-(methyl orthoacetate)(16697-49-7) Related Product Information
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