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2,4,6-Collidine Suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86-571-85586718
Products Intro: Product Name:2,4,6-Trimethylpyridine
Purity:98%(Min,GC) Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Products Intro: Product Name:2,4,6-Collidine
Purity:99% Package:100g,500g,1kg,5kg,10kg
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Products Intro: CAS:108-75-8
Purity:99% Package:500G;1KG;5KG;25KG
Company Name: Nanjing ChemLin Chemical Industry Co., Ltd.
Tel: 025-83697070;
Products Intro: CAS:108-75-8
Purity:98% Package:g-Kg
Tel: +86 21 5161 9050/ 5187 7795
Products Intro: Product Name:2,4,6-Collidine
Purity:98% Package:25G;50G;100G;500G;1KG;10KG;50KG

Lastest Price from 2,4,6-Collidine manufacturers

  • 2,4,6-Collidine
  • US $0.00-0.00 / KG
  • 2020-01-07
  • CAS:108-75-8
  • Min. Order: 1g
  • Purity: 99%
  • Supply Ability: 2000tons
  • 2,4,6-Collidine
  • US $1.00 / KG
  • 2019-07-12
  • CAS:108-75-8
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 25kg
  • 2,4,6-Collidine
  • US $7.00 / KG
  • 2019-07-06
  • CAS:108-75-8
  • Min. Order: 1KG
  • Purity: 99%
  • Supply Ability: 1T
2,4,6-Collidine Basic information
Product Name:2,4,6-Collidine
Synonyms:2,4,6-Kollidin;2,4,6-trimethyl-pyridin;a,g,a'-Collidine;alpha,gamma,alpha’-collidine;alpha,gamma,alpha'-Collidine;g-Collidine;Pyridine,2,4,6-trimethyl-;2 Minus 2-3 Methyl pyridine
Product Categories:Heterocyclic Compounds;TCI
Mol File:108-75-8.mol
2,4,6-Collidine Structure
2,4,6-Collidine Chemical Properties
Melting point −43 °C(lit.)
Boiling point 171-172 °C(lit.)
density 0.917 g/mL at 25 °C(lit.)
vapor pressure 4 hPa (20 °C)
refractive index n20/D 1.498(lit.)
Fp 135 °F
storage temp. 2-8°C
solubility 35g/l
pka7.43(at 25℃)
form Liquid
color Clear colorless to yellow
Water Solubility 35 g/L (20 ºC)
Sensitive Hygroscopic
Merck 14,9718
BRN 107283
Stability:Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference108-75-8(CAS DataBase Reference)
NIST Chemistry ReferencePyridine, 2,4,6-trimethyl-(108-75-8)
EPA Substance Registry System2,4,6-Trimethylpyridine (108-75-8)
Safety Information
Hazard Codes Xn
Risk Statements 10-20/21/22-36/37/38
Safety Statements 26-36/37-36
RIDADR UN 1992 3/PG 3
WGK Germany 3
RTECS UU0970000
HazardClass 3
PackingGroup III
HS Code 29333999
Hazardous Substances Data108-75-8(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 400 mg/kg
MSDS Information
2,4,6-Trimethylpyridine English
ACROS English
SigmaAldrich English
ALFA English
2,4,6-Collidine Usage And Synthesis
Chemical Propertiescolourless liquid
Uses2,4,6-Collidine is an reagent used for various synthetic preparations such as the synthesis of methylated pyridines by three-componet catalytic condensation of acetylene, acetone and ammonia.
DefinitionMethyl, ethyl, propyl, and trimethyl homologs of pyridine.
Purification MethodsCommercial samples may be grossly impure. Likely contaminants include 3,5-dimethylpyridine, 2,3,6-trimethylpyridine and water. Brown, Johnson and Podall [J Am Chem Soc 76 5556 1954] fractionally distilled 2,4,6-trimethylpyridine under reduced pressure through a 40cm Vigreux column (p 11) and added to 430mL of the distillate slowly, with cooling to 0o, 45g of BF3-diethyl etherate. The mixture was again distilled, and an equal volume of dry *benzene was added to the distillate. Dry HCl was passed into the solution, which was kept cold in an ice-bath, and the hydrochloride was filtered off. It was recrystallised from absolute EtOH (1.5mL/g) to m 286-287o[m 256o(sealed tube), also m 293-294o subliming slowly]. The free base was regenerated by treatment with aqueous NaOH, then extracted with *benzene, dried (MgSO4) and distilled under reduced pressure. Sisler et al. [J Am Chem Soc 75 446 1953] precipitated trimethylpyridine as its phosphate from a solution of the base in MeOH by adding 85% H3PO4, shaking and cooling. The free base was regenerated as above. Garrett and Smythe [J Chem Soc 763 1903] purified the trimethylpyridine via the HgCl2 complex. It is more soluble in cold than hot H2O [the solubility is 20.8% at 6o, 3.5% at 20o, 1.8% at 100o]. Alternatively, purify it by dissolving it in CHCl3, adding solid K2CO3 and Drierite, filtering and fractionally distilling through an 8in helix-packed column. The sulfate has m 205o, and the picrate (from hot H2O) has m 155-156o. [Frank & Meikle J Am Chem Soc 72 4184 1950, Beilstein 20 H 250, 20 I 87, 20 II 164, 20 III/IV 2810, 20/6 V 93.]
2,4,6-Collidine Preparation Products And Raw materials
Preparation Products1,3,5(10)-Estratrien-3-ol-17-one-->4,6-DIMETHYL-PYRIDINE-2-CARBOXYLIC ACID-->2-Cyclopentenone
Raw materialsSulfuric acid -->Acetone-->Ammonia-->Benzene-->Urea-->Zinc chloride-->Phosphorus pentoxide
Tag:2,4,6-Collidine(108-75-8) Related Product Information
2,4,6-TRI-TERT-BUTYLPYRIDINE 2-(4-METHOXYPHENYL)-4-PHENYL-6-(4-TOLYL)PYRIDINE 2-(4-METHOXYPHENYL)-4,6-DIPHENYLPYRIDINE Pyrroloquinoline quinone 2-(4-CHLOROPHENYL)-6-(4-METHOXYPHENYL)-4-PHENYLPYRIDINE DIMETHYL 4-(4-METHOXYPHENYL)-2,6-DIMETHYLPYRIDINE-3,5-DICARBOXYLATE 2.4.6-TRIMETHYL-3-NITROPYRIDINE HYDROGEN FLUORIDE 2,4,6-TRIMETHYLPYRIDINE,2,4,6-Trimethylpyridine hydrofluoride, Hydrogen fluoride sym.-collidine, sym.-Collidine hydrofluoride,2,4,6-Trimethylpyridine hydrogen fluoride,2,4,6-Collidine hydrogen fluoride,2,4,6-Trimethylpyridine hydrofluoride, Hydrogen fluoride sym.-collidine, sym.-Collidine hydrofluoride,COLLIDINE-HYDROGEN FLUORIDE COMPLEX (1:2, COLLIDINE:HF),COLLIDINE-HYDROGEN FLUORIDE COMPLEX (APPROX 1:2 COLLIDINE:HF),COLLIDINE-HYDROGEN FLUORIDE COMPLEX,HYDROGEN FL 1-FLUORO-2,4,6-TRIMETHYLPYRIDINIUM TRIFLATE Streptonigrin 2,6-Di-tert-butyl-4-methylpyridine 3-Acetyl-2,4,6-trimethylpyridine 2,6-Lutidine trimethylpyridine,MIX-COLLIDINE,collidine(combustibleliquid,n.o.s. Pyridine sulfur trioxide 2,4,6-Collidine 4-Methylpyridine Azamethiphos