|
|
| | 2-(Trimethylsiloxy)-1,3-butadiene Basic information |
| | 2-(Trimethylsiloxy)-1,3-butadiene Chemical Properties |
| Melting point | <0°C | | Boiling point | 50 °C | | density | 0.807 | | refractive index | 1.4480 | | Fp | 12°C | | storage temp. | Store at +2°C to +8°C. | | solubility | sol most standard organic solvents. | | form | clear liquid | | color | Colorless to Light yellow to Light orange | | Specific Gravity | 0.807 | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | | InChI | 1S/C7H14OSi/c1-6-7(2)8-9(3,4)5/h6H,1-2H2,3-5H3 | | InChIKey | JOAPBVRQZQYKMS-UHFFFAOYSA-N | | SMILES | [Si](OC(=C)C=C)(C)(C)C | | CAS DataBase Reference | 38053-91-7(CAS DataBase Reference) |
| Risk Statements | 11-23/24/25 | | Safety Statements | 16-23-36/37/39-45 | | RIDADR | 1992 | | WGK Germany | WGK 3 highly water endangering | | Autoignition Temperature | 350 °C | | TSCA | No | | HS Code | 2931 90 00 | | HazardClass | 3 | | PackingGroup | II | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Flam. Liq. 2 |
| | 2-(Trimethylsiloxy)-1,3-butadiene Usage And Synthesis |
| Physical properties | bp 50–55 °C/50 mmHg; d 0.811 g cm3. | | Uses | 2-Trimethylsilyloxy-1,3-butadiene is easily prepared reactive diene for Diels–Alder reactions and other cycloadditions; reactive silyl enol ether for aldol,Michael reactions, and electrophilic additions. It participates in the reactions of Diels–Alder Reactions, Heterodienophiles, [2 + 2] and Other Cycloadditions, Carbene Additions, Aldol Condensations and Electrophilic Additions. | | Preparation | 2-Trimethylsilyloxy-1,3-butadiene can be prepared easily from methyl vinyl
ketone. | | Precautions |
2-(Trimethylsiloxy)-1,3-butadiene is a flammable liquid and is moisture sensitive.
|
| | 2-(Trimethylsiloxy)-1,3-butadiene Preparation Products And Raw materials |
|