ChemicalBook CAS DataBase List 1-HEPTENE

1-HEPTENE synthesis

13synthesis methods

Product Name:1-HEPTENE
CAS Number:592-76-7
Molecular formula:C7H14
Molecular Weight:98.19

Heptene is produced in a process involving the oligomerization of ethene in the presence of aluminum alkyls.

628-71-7 Synthesis

628-71-7
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$55.50/25g

592-76-7
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$25.10/u

Yield:592-76-7 93%

Reaction Conditions:

with hydrogen at 40; under 3000.3 Torr; for 0.333333 h;Kinetics;Reagent/catalyst;Temperature;

Steps:

Catalytic reaction study
To test the performance of the catalysts, the liquid-phase hydro-genation of 1-heptyne under mild reaction conditions was carriedout using approximately 5 mg of reduced catalyst dispersed in10 cm3reactant mixture of 1-heptyne (Aldrich) in toluene (2%v/v).The reaction was performed in a 100 cm3stainless steel autoclavereactor (JASCO, Tokyo, Japan) at a pressure of 4 bar H2and at tem-perature of 30C for 5-120 min. After that, the liquid product wascollected and analyzed by using gas chromatography equippedwith a flame ionization detector (FID) and GS-alumina capillary col-umn. The catalytic reaction tests were conducted under the absenceof mass transfer/diffusion resistance. The highest stirring speed(1000 rpm) was used to eliminate the external mass transfer resis-tance and the effect due to pore diffusion was minimized by usingsmall particle size catalysts. The catalysts were thoroughly grindedinto powder form prior to the reaction tests.

References:

Pongthawornsakun, Boontida;Mekasuwandumrong, Okorn;Prakash, Swamy;Ehret, Eric;Santos Aires, Francisco J. Cadete;Panpranot, Joongjai [Applied Catalysis A: General,2015,vol. 506,p. 278 - 287]

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