9-(4,6-Diphenyl-1,3,5-triazin-2-yl)-9'-phenyl-3,3'-dicarbazole synthesis
- Product Name:9-(4,6-Diphenyl-1,3,5-triazin-2-yl)-9'-phenyl-3,3'-dicarbazole
- CAS Number:1266389-01-8
- Molecular formula:C45H29N5
- Molecular Weight:639.75
![9-Phenyl-9H,9'H-[3,3']bicarbazolyl](/CAS/GIF/1060735-14-9.gif)
1060735-14-9
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Yield:1266389-01-8 75%
Reaction Conditions:
Stage #1: 9-phenyl-3,3'-bicarbazolewith sodium hydride in N,N-dimethyl-formamide at 20; for 1 h;Inert atmosphere;
Stage #2: 2-chloro-4,6-diphenyltriazine in N,N-dimethyl-formamide at 20;Reflux;
Steps:
1
Synthesis of 9-(4,6-diphenyl-l,3,5-triazin-2-yl)-3-(9-phenyl-9H-carbazol-3-yl)-9H- carbazole (Compound 1). To a solution of sodium hydride (100 mg, 3.0 mmol) and 3-(9- phenyl-9H-carbazol-3-yl)-9H-carbazole (816 mg, 2.0 mmol) in dry DMF (40 mL) was stirred at room temperature for 1 h under argon atmosphere. 2-Chloro-4,6-diphenyl-l,3,5-triazine (448 mg, 1.67mmol ) was added to the solution at room temperature, then refluxed overnight. The mixture was poured into water and the precipitation was collected by filtration and washed with water, methanol and DCM to get 800 mg (75%) yellow solid.
References:
WO2012/23947,2012,A1 Location in patent:Page/Page column 142-143
1060735-14-9
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854952-58-2
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1153-85-1
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