4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE synthesis
- Product Name:4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CHLOROBENZENE
- CAS Number:195062-61-4
- Molecular formula:C12H16BClO2
- Molecular Weight:238.52
76-09-5
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$8.19/250mg
1679-18-1
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$10.00/1g
195062-61-4
136 suppliers
$8.00/1g
Yield: 92%
Reaction Conditions:
with magnesium sulfate in diethyl ether at 20; for 16 h;Inert atmosphere;Schlenk technique;
Steps:
Synthesis of Pinacol Boronic Esters from Boronic Acids; General Procedure (GP1)
General procedure: A mixture of boronic acid (1.0 equiv), pinacol (1.0 equiv) and anhydrous MgSO4 (4.0 equiv) in Et2O (0.5 M) was stirred at r.t. for 16 h. The reaction mixture was filtered and the solvent removed in vacuo. The crude material was purified by distillation or flash column chromatography to give the pure boronic ester.
References:
Casoni, Giorgia;Myers, Eddie L.;Aggarwal, Varinder K. [Synthesis,2016,vol. 48,# 19,art. no. SS-2016-C0356-OP,p. 3241 - 3253]
637-87-6
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73183-34-3
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$6.00/5g
195062-61-4
136 suppliers
$8.00/1g
106-47-8
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$5.00/5 g
73183-34-3
586 suppliers
$6.00/5g
195062-61-4
136 suppliers
$8.00/1g
637-87-6
302 suppliers
$38.00/10 G
![Bis[(pinacolato)boryl]Methane](/CAS/GIF/78782-17-9.gif)
78782-17-9
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$22.00/1g
195062-61-4
136 suppliers
$8.00/1g
106-39-8
475 suppliers
$14.00/5g
73183-34-3
586 suppliers
$6.00/5g
195062-61-4
136 suppliers
$8.00/1g