2-(4-METHOXY-PHENYL)-1H-PYRROLO[2,3-B]PYRIDINE synthesis
- Product Name:2-(4-METHOXY-PHENYL)-1H-PYRROLO[2,3-B]PYRIDINE
- CAS Number:139962-68-8
- Molecular formula:C14H12N2O
- Molecular Weight:224.26
13534-99-1
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$4.00/1g
100-06-1
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$18.19/25g
139962-68-8
20 suppliers
$65.00/500mg
Yield:139962-68-8 87%
Reaction Conditions:
Stage #1: 1-(4-methoxyphenyl)ethanonewith allyl(1,3-bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene)palladium(IV) chloride;sodium hexamethyldisilazane in tetrahydrofuran at 20; for 0.0833333 h;Inert atmosphere;
Stage #2: 2-Amino-3-bromopyridine in tetrahydrofuran at 20 - 105; for 4 h;Inert atmosphere;regioselective reaction;
References:
Spergel, Steven H.;Okoro, Danielle R.;Pitts, William [Journal of Organic Chemistry,2010,vol. 75,# 15,p. 5316 - 5319] Location in patent:supporting information; experimental part
108-99-6
342 suppliers
$9.00/5g
874-90-8
335 suppliers
$8.00/10g
139962-68-8
20 suppliers
$65.00/500mg
![2-bromo-1H-pyrrolo[2,3-b]pyridine](/CAS2/GIF/1083181-25-2.gif)
1083181-25-2
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$65.00/50mg
5720-07-0
469 suppliers
$6.00/5g
139962-68-8
20 suppliers
$65.00/500mg
104830-06-0
239 suppliers
$7.00/250mg
768-60-5
231 suppliers
$6.00/1g
139962-68-8
20 suppliers
$65.00/500mg
109-06-8
421 suppliers
$16.00/25g
874-90-8
335 suppliers
$8.00/10g
139962-68-8
20 suppliers
$65.00/500mg