Dibenzyl diselenide
- CAS No.
- 1482-82-2
- Chemical Name:
- Dibenzyl diselenide
- Synonyms
- BENZYL DISELENIDE;Dibenzyldiselenium;DIBENZYL DISELENIDE;1,2-Dibenzyldiselane;Dibenzyl perselenide;DibenzylDiselenide>Dibenzyl perdiselenide;Bis(benzyl) perselenide;Dibenzyldiselenide, 99+%;Diselenide,bis(phenylmethyl)
- CBNumber:
- CB0309404
- Molecular Formula:
- C14H14Se2
- Molecular Weight:
- 340.18
- MDL Number:
- MFCD00004767
- MOL File:
- 1482-82-2.mol
Melting point | 91-93 °C(lit.) |
---|---|
Boiling point | 427.3±48.0 °C(Predicted) |
storage temp. | Inert atmosphere,Room Temperature |
solubility | almost transparency in hot Toluene |
form | solid |
color | Light yellow to Yellow to Orange |
Water Solubility | Soluble in water. |
Sensitive | Air Sensitive |
BRN | 1877745 |
Exposure limits |
ACGIH: TWA 0.2 mg/m3 NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3 |
InChIKey | HYAVEDMFTNAZQE-UHFFFAOYSA-N |
CAS DataBase Reference | 1482-82-2(CAS DataBase Reference) |
NIST Chemistry Reference | Diselenide, bis(phenylmethyl)(1482-82-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS08,GHS09 |
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Signal word | Danger | |||||||||
Hazard statements | H301+H331-H373-H410-H301-H331-H400 | |||||||||
Precautionary statements | P260-P264-P270-P271-P273-P301+P310+P330-P304+P340+P311-P314-P391-P403+P233-P405-P501-P301+P310a-P304+P340-P311a-P501a | |||||||||
Hazard Codes | T,N | |||||||||
Risk Statements | 23/25-33-50/53 | |||||||||
Safety Statements | 20/21-28-45-60-61 | |||||||||
RIDADR | UN 3283 6.1/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29310099 | |||||||||
NFPA 704 |
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Dibenzyl diselenide price More Price(20)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TCI Chemical | D2717 | Dibenzyl Diselenide >95.0%(T) | 1482-82-2 | 5g | $142 | 2024-03-01 | Buy |
Alfa Aesar | B21278 | Dibenzyl diselenide, 95% | 1482-82-2 | 1g | $19.65 | 2024-03-01 | Buy |
Alfa Aesar | B21278 | Dibenzyl diselenide, 95% | 1482-82-2 | 5g | $67.65 | 2024-03-01 | Buy |
Alfa Aesar | B21278 | Dibenzyl diselenide, 95% | 1482-82-2 | 25g | $260.65 | 2024-03-01 | Buy |
TRC | D423085 | Dibenzyl Diselenide | 1482-82-2 | 2.5g | $75 | 2021-12-16 | Buy |
Dibenzyl diselenide Chemical Properties,Uses,Production
Chemical Properties
Light yellow to Yellow to Orange powder to crystaline.
Uses
Dibenzyl diselenide is used as a source of the PhSe unit in organic synthesis. It is also used to introduce PhSe groups by reaction with a variety of nucleophilic, including enolates, enol silyl ethers, Grignard reagents, organolithium reagents, alkenes and amines.
Preparation
Dibenzyl diselenide was synthesized from bis(methoxymagnesium) diselenide reagent as reported by Gunther using benzyl chloride (6.3 g, 0.05 mole) and a methanolic solution of bis(methoxymagnesium) diselenide reagent (from 0.05 gatom of selenium). After 10 min stirring, water (100 mL) and concentrated hydrochloric acid (5 mL) were added, the solution was cooled, and the black solid was collected by filtration. This black solid was then extracted with ethanol to yield a bright yellow solution which, upon solvent removal, gave a yellow crystalline product. The 1H NMR of the yellow solid (in CDCl3) was identical to that of commercially available dibenzyl diselenide.
Dibenzyl diselenide Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Nanjing Kaitian Chemical Co., LTD | +undefined13337835376 | kt_chem@126.com | China | 40 | 58 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9294 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Fuxin Pharmaceutical | +86-021-021-50872116 +8613122107989 | contact@fuxinpharm.com | China | 10297 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34571 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
changzhou huayang technology co., ltd | +8615250961469 | 2571773637@qq.com | China | 9817 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +8619930503259 | cherry@crovellbio.com | China | 18419 | 58 |
View Lastest Price from Dibenzyl diselenide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-04-11 | Dibenzyldiselenide
1482-82-2
|
US $0.00-0.00 / kg | 1kg | 98% | 500kg | Nanjing Kaitian Chemical Co., LTD | ||
2021-08-12 | Dibenzyl diselenide
1482-82-2
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2021-07-02 | Dibenzyl Diselenide
1482-82-2
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
- Dibenzyldiselenide
1482-82-2
- US $0.00-0.00 / kg
- 98%
- Nanjing Kaitian Chemical Co., LTD
- Dibenzyl diselenide
1482-82-2
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- Dibenzyl Diselenide
1482-82-2
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd