ChemicalBook--->CAS DataBase List--->1013-88-3

1013-88-3

1013-88-3 Structure

1013-88-3 Structure
IdentificationMore
[Name]

Benzophenone imine
[CAS]

1013-88-3
[Synonyms]

BENZHYDRYLIDENEAMINE
BENZOPHENONE IMINE
BENZOPHENONIMINE
DIPHENYLMETHANIMINE
Benzenemethanimine,-phenyl-
BENZOPHENONE IMINE 97%
90-97%
Benzophone imine
1,1-Diphenylmethylenimine
Benzhydrylidenimine
Diphenylmethane imine
Benzophenone imine, 97%, stabilized
Benzophenone imine, stabilized
Diphenylketimine
Iminodiphenylmethane
α-Phenylbenzenemethanimine
BENZOPHENONE IMINE HCl
[EINECS(EC#)]

440-870-2
[Molecular Formula]

C13H11N
[MDL Number]

MFCD00001760
[Molecular Weight]

181.23
[MOL File]

1013-88-3.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to light yellow-brownish liquid
[Melting point ]

-30 °C
[Boiling point ]

151-153 °C10 mm Hg(lit.)
[density ]

1.08 g/mL at 25 °C(lit.)
[vapor pressure ]

0.082Pa at 20℃
[refractive index ]

n20/D 1.618(lit.)
[Fp ]

145 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

DMSO (Slightly), Ethyl Acetate (Slightly)
[form ]

Liquid
[pka]

pK1:6.82 (25°C)
[color ]

Clear colorless to light yellow-brownish
[Water Solubility ]

0.3 g/L (25 ºC)
[BRN ]

1100371
[Major Application]

diagnostic assay manufacturing
hematology
histology
[InChI]

1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H
[InChIKey]

SXZIXHOMFPUIRK-UHFFFAOYSA-N
[SMILES]

N=C(c1ccccc1)c2ccccc2
[CAS DataBase Reference]

1013-88-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenemethanimine, «alpha»-phenyl-(1013-88-3)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi,N,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R38:Irritating to the skin.
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37:Wear suitable gloves .
[RIDADR ]

UN3082
[WGK Germany ]

3
[REACH Registrations]

Active
[HS Code ]

29252900
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Diethyl ether-->Ammonia-->Benzonitrile-->Benzophenone-->Titanium tetrachloride-->Phenylmagnesium bromide-->Benzophenone oxime-->Diphenylmethyl azide-->9-Fluorenone-->Diphenylketene-->Benzhydrylamine-->Iodobenzene-->Benzoic acid-->Phenylmagnesium chloride-->Bromobenzene
[Preparation Products]

N-(Diphenylmethylene)glycerine tert-butyl ester-->Ethyl 2-cyano-3,3-diphenylacrylate-->N-(Diphenylmethylene)glycine methyl ester
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Benzophenone imine(1013-88-3).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to light yellow-brownish liquid
[Uses]

Benzophenone imine is useful in the preparation of nitrile ylide dimers.
[Application]

Benzophenone imine is a multifunctional reagent in organic synthesis, its core role being as an ammonia equivalent and a protecting group for primary amines. It reacts with primary amines to form stable Schiff bases, thereby protecting the functional groups of primary amines and preventing them from undergoing side reactions in subsequent reactions.
[Synthesis Reference(s)]

Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307
[Flammability and Explosibility]

Notclassified
Spectrum DetailBack Directory
[Spectrum Detail]

Benzophenone imine(1013-88-3)1HNMR
Benzophenone imine(1013-88-3)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Benzophenone imine, 97%(1013-88-3)
[Sigma Aldrich]

1013-88-3(sigmaaldrich)
[TCI AMERICA]

Benzophenone Imine,>95.0%(GC)(1013-88-3)
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