| Identification | More | [Name]
Benzophenone imine | [CAS]
1013-88-3 | [Synonyms]
BENZHYDRYLIDENEAMINE BENZOPHENONE IMINE BENZOPHENONIMINE DIPHENYLMETHANIMINE Benzenemethanimine,-phenyl- BENZOPHENONE IMINE 97% 90-97% Benzophone imine 1,1-Diphenylmethylenimine Benzhydrylidenimine Diphenylmethane imine Benzophenone imine, 97%, stabilized Benzophenone imine, stabilized Diphenylketimine Iminodiphenylmethane α-Phenylbenzenemethanimine BENZOPHENONE IMINE HCl | [EINECS(EC#)]
440-870-2 | [Molecular Formula]
C13H11N | [MDL Number]
MFCD00001760 | [Molecular Weight]
181.23 | [MOL File]
1013-88-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to light yellow-brownish liquid | [Melting point ]
-30 °C
| [Boiling point ]
151-153 °C10 mm Hg(lit.)
| [density ]
1.08 g/mL at 25 °C(lit.)
| [vapor pressure ]
0.082Pa at 20℃ | [refractive index ]
n20/D 1.618(lit.)
| [Fp ]
145 °C
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
DMSO (Slightly), Ethyl Acetate (Slightly) | [form ]
Liquid | [pka]
pK1:6.82 (25°C) | [color ]
Clear colorless to light yellow-brownish | [Water Solubility ]
0.3 g/L (25 ºC) | [BRN ]
1100371 | [InChIKey]
SXZIXHOMFPUIRK-UHFFFAOYSA-N | [CAS DataBase Reference]
1013-88-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenemethanimine, «alpha»-phenyl-(1013-88-3) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . R38:Irritating to the skin. R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S36:Wear suitable protective clothing . S61:Avoid release to the environment. Refer to special instructions safety data sheet . S37:Wear suitable gloves . | [RIDADR ]
UN3082 | [WGK Germany ]
3
| [HS Code ]
29252900 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to light yellow-brownish liquid | [Uses]
Benzophenone imine is useful in the preparation of nitrile ylide dimers.
| [Application]
Benzophenone imine is a multifunctional reagent in organic synthesis, its core role being as an ammonia equivalent and a protecting group for primary amines. It reacts with primary amines to form stable Schiff bases, thereby protecting the functional groups of primary amines and preventing them from undergoing side reactions in subsequent reactions. | [Synthesis Reference(s)]
Synthetic Communications, 18, p. 1501, 1988 DOI: 10.1080/00397918808081307 | [Flammability and Explosibility]
Notclassified |
|
|