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110-94-1

110-94-1 Structure

110-94-1 Structure
IdentificationMore
[Name]

1,5-Pentanedioic acid
[CAS]

110-94-1
[Synonyms]

1,3-PROPANEDICARBOXYLIC ACID
1,5-PENTADIOIC ACID
1,5-PENTANEDIOIC ACID
DICARBOXYLIC ACID C5
GLUTARIC ACID
GLUTARIC ACID AND ANHYDRIDE
N-PYROTARTARIC ACID
Pentandioic acid
PENTANEDIOIC ACID
PROPANE-1,3-DICARBOXYLIC ACID
RARECHEM AL BO 0175
a,-Propanedicarboxylicacid
glutaric
Glutarsaure
Glutaric acid,(Pentanedioic acid
propane-1,3-dica
Glutaric Acid, Reagent
Propane-1,5-dicarboxylic acid
Pentanedioic acid,Glutaric acid
Glutarsure
[EINECS(EC#)]

203-817-2
[Molecular Formula]

C5H8O4
[MDL Number]

MFCD00004410
[Molecular Weight]

132.11
[MOL File]

110-94-1.mol
Chemical PropertiesBack Directory
[Appearance]

white or off-white crystals
[Melting point ]

95-98 °C (lit.)
[mp ]

95-98 °C(lit.)
[bp ]

302 °C
[Boiling point ]

200 °C/20 mmHg (lit.)
[density ]

1,429 g/cm3
[vapor pressure ]

0.022 hPa (18.5 °C)
[refractive index ]

nD106 1.41878
[Fp ]

200°C/20mm
[storage temp. ]

2-8°C
[solubility ]

water: soluble5mg/mL, clear to slightly hazy, colorless to faintly yellow
[pka]

4.31(at 25℃)
[form ]

Crystalline Powder
[color ]

Orange
[Stability:]

Stable. Incompatible with bases, oxidizing agents, reducing agents.
[Water Solubility ]

430 g/L (20 ºC)
[Merck ]

14,4473
[BRN ]

1209725
[InChIKey]

JFCQEDHGNNZCLN-UHFFFAOYSA-N
[CAS DataBase Reference]

110-94-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Pentanedioic acid(110-94-1)
[EPA Substance Registry System]

110-94-1(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
[WGK Germany ]

1
[RTECS ]

MA3740000
[TSCA ]

Yes
[HS Code ]

29171990
[Hazardous Substances Data]

110-94-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Nitric acid-->Ammonium chloride-->POTASSIUM CYANIDE-->Cyclohexanone-->Paraffin wax-->Adipic acid-->Cyclopentanone-->Gamma Butyrolactone-->1,3-Propanediol-->Nitrogen Tetroxide-->2,3-Dihydrofuran-->Glutaronitrile-->oxidized paraffin(wax)-->6-oxohexanoic acid-->Succinic acid-->Cyclopentanol-->Cyclopentane
【Preparation Products】

Buspirone-->Cinmethylin-->Glutaric anhydride-->Azelaic acid-->LACCAIC ACID-->Baclofen
Hazard InformationBack Directory
[General Description]

Colorless crystals or white solid.
[Reactivity Profile]

GLUTARIC ACID(110-94-1) is a carboxylic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in GLUTARIC ACID(110-94-1) to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions This compound reacts with bases, oxidizing agents and reducing agents.
[Air & Water Reactions]

Water soluble.
[Fire Hazard]

Flash point data for this chemical are not available; however, GLUTARIC ACID is probably combustible.
[Chemical Properties]

white or off-white crystals
[Definition]

ChEBI: An alpha,omega-dicarboxylic acid that is a linear five-carbon dicarboxylic acid.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 78, p. 2489, 1956 DOI: 10.1021/ja01592a042
Organic Syntheses, Coll. Vol. 1, p. 290, 1941
Synthetic Communications, 10, p. 205, 1980 DOI: 10.1080/00397918008064223
[Purification Methods]

Crystallise the acid from *benzene, CHCl3, distilled water or *benzene containing 10% (w/w) of diethyl ether. Dry it under vacuum. [Beilstein 2 IV 1934.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,5-Pentanedioic acid(110-94-1).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Glutaric acid(110-94-1) Raman
Glutaric acid(110-94-1) 13C NMR
Glutaric acid(110-94-1) 1H NMR
Glutaric acid(110-94-1) IR1
Glutaric acid(110-94-1) MS
Glutaric acid(110-94-1) IR2
Glutaric acid(110-94-1) ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Glutaric acid, 99%(110-94-1)
[Alfa Aesar]

Glutaric acid, 99%(110-94-1)
[Sigma Aldrich]

110-94-1(sigmaaldrich)
[TCI AMERICA]

Glutaric Acid,>99.0%(GC)(T)(110-94-1)
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