ChemicalBook--->CAS DataBase List--->111-91-1

111-91-1

111-91-1 Structure

111-91-1 Structure
IdentificationMore
[Name]

Bis(2-chloroethoxy)methane
[CAS]

111-91-1
[Synonyms]

BIS(2-CHLOROETHOXY)METHANE
DICHLOROETHYL FORMAL
1,1’-(methylenebis(oxy))bis(2-chloro-ethan
1,1’-(methylenebis(oxy))bis(2-chloroethane)
1,1’-[methylenebis(oxy)]bis[2-chloro-ethan
1,1’-[methylenebis(oxy)]bis[2-chloro-Ethane
1-Chloro-2-[(2-chloroethoxy)methoxy]ethane
2,2-Dichloroethylformal
beta,beta,-dichlorodiethylformal
bis(2-chloroethoxy)-methan
bis(2-chloroethoxy)methane,[liquid]
Bis(2-chloroethyl) formal
bis(2-chloroethyl)formal
Bis(beta-chloroethyl) formal
bis(betachloroethyl)formal
bis(beta-chloroethyl)formal
bis(chloro-2ethoxy)methane
Di-2-chloroethyl formal
di-2-chloroethylformal
dichlorodiethylformal
[EINECS(EC#)]

203-920-2
[Molecular Formula]

C5H10Cl2O2
[MDL Number]

MFCD00045293
[Molecular Weight]

173.04
[MOL File]

111-91-1.mol
Chemical PropertiesBack Directory
[Appearance]

Bis(2-chloroethoxy)methane is a colorless liquid.
[Melting point ]

-32.3°C
[Boiling point ]

112°C/20mm
[density ]

1.23
[vapor pressure ]

1 at 53 °C (Weast, 1986)
[refractive index ]

1.45
[storage temp. ]

Refrigerator, under inert atmosphere
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

Oil
[color ]

Colorless liquid
[Water Solubility ]

81,000 mg/L at 25 °C using method of Moriguchi (1975)
[Henry's Law Constant]

(x 10-7 atm?m3/mol): 3.78 (calculated, U.S. EPA, 1980a)
[LogP]

1.6 at 20℃
[CAS DataBase Reference]

111-91-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Methane, bis(2-chloroethoxy)-(111-91-1)
[EPA Substance Registry System]

111-91-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)Skull and Crossbones (GHS06)
GHS08,GHS06
[Signal word ]

Danger
[Hazard statements ]

H312-H373-H301-H330-H370
[Precautionary statements ]

P260-P264-P270-P307+P311-P321-P405-P501-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P260-P314-P501-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P363-P501
[Hazard Codes ]

Xi,T
[Risk Statements ]

25
[Safety Statements ]

45
[RIDADR ]

2810
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Hazardous Substances Data]

111-91-1(Hazardous Substances Data)
[Toxicity]

Acute oral LD50 for rats 65 mg/kg (quoted, RTECS, 1985).
Hazard InformationBack Directory
[General Description]

A colorless liquid. Boiling point 217.5°C, Flash point 230°F. Density 1.23 g/cm3. May be toxic by ingestion or inhalation. Severely irritates skin, eyes, and mucous membranes. Used as a solvent.
[Reactivity Profile]

BIS(2-CHLOROETHOXY)METHANE, [LIQUID], the b-chloroethyl acetal of formaldehyde, is incompatible with oxidizing agents.
[Air & Water Reactions]

Slightly soluble in water.
[Health Hazard]

ACUTE/CHRONIC HAZARDS: Toxic by inhalation and ingestion; Strong irritant.
[Potential Exposure]

The chloroalkyl ethers have a wide variety of industrial uses in organic synthesis, treatment of textiles; the manufacture of polymers; polysulfide rubbers, and insecticides; as degreasing agents and solvents; and in the preparation of ion exchange resins.
[Fire Hazard]

Not Flammable.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.
[Incompatibilities]

The aqueous solution is a strong acid; keep away from bases and alkaline material. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with mineral acids causes decomposition.
[Description]

Bis(2-chloroethoxy)methane is a colorlessliquid. Molecular weight=173.1; Boiling point=218℃;Freezing/Melting point=233℃; Flash point=110℃(oc). Hazard Identification (based on NFPA-704 M RatingSystem): Health 2, Flammability 1, Reactivity 0. Slight solubility in water; solubility=0.8%.
[Chemical Properties]

Bis(2-chloroethoxy)methane is a colorless liquid.
[Waste Disposal]

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. Destroy by high-temperature incineration with HCl scrubber.
[Uses]

Manufacture of insecticides, polymers; degreasing solvent; intermediate for polysulfide rubber.
[Environmental Fate]

Biological. Using settled domestic wastewater inoculum, bis(2-chloroethoxy)methane (5 and 10 mg/L) did not degrade after 28 d of incubation at 25 °C (Tabak et al., 1981).
Chemical/Physical. At influent concentrations of 10, 1.0, 0.1, and 0.01 mg/L, the GAC adsorption capacities were 50, 11, 2.6, and 0.6 mg/g, respectively (Dobbs and Cohen, 1980).
[storage]

Color Code—Green: General storage may be used.Store in tightly closed containers in a cool, well-ventilatedarea away from oxidizers. Sources of ignition, such assmoking and open flames, are prohibited where this chemical is used, handled, or stored in a manner that could createa potential fire or explosion hazard.
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