ChemicalBook--->CAS DataBase List--->12071-83-9

12071-83-9

12071-83-9 Structure

12071-83-9 Structure
IdentificationMore
[Name]

Propineb
[CAS]

12071-83-9
[Synonyms]

[[(1-METHYL-1,2-ETHANEDIYL)BIS[CARBAMO-DITHIOATO]](2-)]ZINC HOMOPOLYMER
(1-methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complex
AGROCOL
AGROCOL(R)
AIRONE(R)
ANTRACOL
ANTRACOL(R)
ENERCOL
KORUNEB
Methylzineb
MEZINEB
PROPINEB
Zinc 1,2-propylenebis(dithiocarbamate)
ZINC PROPYLENEBISDITHIOCARBAMATE
airone
bay46131
bayer46131
lh30/z
lh3012
propinebe
[EINECS(EC#)]

235-134-0
[Molecular Formula]

C5H10N2S4
[MDL Number]

MFCD00055491
[Molecular Weight]

226.41
[MOL File]

12071-83-9.mol
Chemical PropertiesBack Directory
[Appearance]

Faintly yellow crystals or powder; becomes dark when heated. Decomposes in the presence of strong acids or bases. Insoluble in most common solvents.
[Melting point ]

157-159°C
[storage temp. ]

0-6°C
[solubility ]

DMSO (Slightly, Heated)
[form ]

Solid
[color ]

Off-White to Light Beige
[Merck ]

13,7911
[Major Application]

agriculture
environmental
[InChI]

1S/C5H10N2S4.Zn/c1-3(7-5(10)11)2-6-4(8)9;/h3H,2H2,1H3,(H2,6,8,9)(H2,7,10,11);/q;+2/p-2
[Contact allergens]

Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.
[InChIKey]

KKMLIVYBGSAJPM-UHFFFAOYSA-L
[SMILES]

CC1CNC(=S)S[Zn]SC(=S)N1
[CAS DataBase Reference]

12071-83-9(CAS DataBase Reference)
[EPA Substance Registry System]

12071-83-9(EPA Substance)
Hazard InformationBack Directory
[Uses]

Pesticides and plant growth
[Definition]

ChEBI: A polymeric complex of zinc with the propylene 1,2-bis(dithiocarbamate) anionic ligand. A fungicide, it is used to control a wide range of fungal diseases, including downy mildew, brown rot, black rot, red fire, leaf spot, and blight in crops such as grape , tomatoes, potatoes, berries, citrus, rice and tea.
[Uses]

Agricultural fungicide.
[Hazard]

Toxic by ingestion.
[Chemical Properties]

Faintly yellow crystals or powder; becomes dark when heated. Decomposes in the presence of strong acids or bases. Insoluble in most common solvents.
[Production Methods]

The commercial production of propineb involves synthesising a polymeric complex formed between zinc ions and propylene-bis-dithiocarbamate ligands. This process typically starts with the reaction of carbon disulfide with propylene diamine to form the dithiocarbamate moiety, which is then complexed with zinc salts to yield the active fungicidal compound.
[Agricultural Uses]

Fungicide: Used to control downy mildew, black rot, brown rot and other fungi on vines, apples, pears, citrus, berry fruit, stone fruit, tomatoes, potatoes, tobacco, vegetables, rice, ornamentals and tea. Not currently registered in the U.S. Used in more than a dozen European countries. There are more than 15 global suppliers.
[Trade name]

AIRONE®; ANTRACOL®; BAY®-46131; BAYER®-46131; LH 3012®; LH 30/Z®; MEZINEB®; PROPINEBE®; ZIPROMAT®
[Mechanism of action]

Contact action with protective properties and long residual activity. Multi-site activity.
[Pesticide Type]

Fungicide
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN3077 9/PG 3
[WGK Germany ]

WGK 2
[RTECS ]

ZH4950000
[HS Code ]

29302000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 2
STOT RE 2
[Toxicity]

LD50 in male rats, rabbits, cats (mg/kg): 8500, >2500, >2500 orally (Grewe)
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(1-Methyl-1,2-ethanediyl)bis-carbamodithioic acid zinc complex(12071-83-9).msds
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