| Identification | More | [Name]
Tricobalt tetraoxide | [CAS]
1308-06-1 | [Synonyms]
COBALT BLACK
COBALTIC OXIDE
Cobalt(II
COBALT(III) OXIDE BLACK
COBALT (II) OXIDE
COBALT SESQUIOXIDE
Co3-O4
Cobalt oxide (Co3O4)
Cobalticcobaltousoxide
cobaltic-cobaltousoxide
cobalto-cobaltictetroxide
cobaltosicoxide
cobaltoxide(co3o4)
Tricobalttetroxide
COBALT(II III)OXIDE FOR THE DETER-&
COBALT(II,III) OXIDE, NANOPOWDER, 99.8% METALS BASIS COBALT (II,III) OXIDE, NANOPOWDER, 99.8% METALS BASIS
COBALT(II,III) OXIDE, 99.995%
CobaltOxidePure
CobaltOxideGr-(CobaltousOxideGr)
CobaltOxidePure-(CobaltousOxide) | [EINECS(EC#)]
215-157-2 | [Molecular Formula]
Co3O4-2 | [MDL Number]
MFCD00036266 | [Molecular Weight]
240.8 | [MOL File]
1308-06-1.mol |
| Chemical Properties | Back Directory | [Appearance]
Black fine powder | [Melting point ]
895 °C (dec.)(lit.)
| [Boiling point ]
3800°C | [bulk density]
0.57g/mL | [density ]
6.11 g/mL at 25 °C(lit.)
| [vapor pressure ]
0Pa at 20℃ | [storage temp. ]
Store at room temperature, keep dry and cool | [solubility ]
insoluble in H2O; soluble in acid solutions, alkaline solutions | [form ]
powder
| [color ]
Dark Gray | [Specific Gravity]
6.11 | [Water Solubility ]
Soluble in acids and alkalis. Insoluble in water. | [Crystal Structure]
Spinel type | [crystal system]
Cube | [Merck ]
14,2429 | [Space group]
Fd3m | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.80835 | 0.80835 | 0.80835 | 90 | 90 | 90 | 0.5282 |
| [Exposure limits]
ACGIH: TWA 0.02 mg/m3 | [Major Application]
battery manufacturing | [InChI]
InChI=1S/3Co.4O | [InChIKey]
LBFUKZWYPLNNJC-UHFFFAOYSA-N | [SMILES]
O([Co]=O)[Co]=O.O=[Co] | [CAS DataBase Reference]
1308-06-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Cobalt oxide(1308-06-1) | [EPA Substance Registry System]
1308-06-1(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS08 | [Signal word ]
Danger | [Hazard statements ]
H334-H350i-H412 | [Precautionary statements ]
P201-P273-P308+P313 | [Hazard Codes ]
Xn,T | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
R43:May cause sensitization by skin contact.
R49:May cause cancer by inhalation. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S53:Avoid exposure-obtain special instruction before use . | [RIDADR ]
1477 | [WGK Germany ]
1
| [RTECS ]
GG2500000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
9 | [HS Code ]
28220000 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Aquatic Chronic 3
Carc. 1A Inhalation
Resp. Sens. 1 |
| Questions And Answer | Back Directory | [Description]
Cobalt Oxide (II, III) is a kind oxide of cobalt. It has applications in enamels, semiconductors, grinding wheels. As an important inorganic material, it can be used in catalysis, superconductors, ceramics and other fields. It can also be used as catalyst and catalyst carrier, as electrode active material, for glass, porcelain colorants and pigments, as chemical industry oxidant and as a catalyst for organic synthesis, in senior goggles and other filter materials, in temperature and gas sensors, in electronic ceramics, in lithium ion battery electrode materials, magnetic materials, electrochromic devices, enamels, solar energy absorbers. Cobalt oxide nanoparticles can readily enter cells, and have the potential to be used for hyperthermic treatment, gene therapy and drug delivery. It is more commonly applied for energy storage such as Lithium-ion battery. It may also be used as a gas sensor in sensing toluene, acetone and some other toxic vapors.
| [Preparation]
Tricobalt tetroxide is obtained when cobalt(II) carbonate, cobalt(II) or cobalt(III) oxide, or cobalt hydroxide oxide, CoO(OH) is heated in air at temperatures above 265°C. The temperature must not exceed 800°C (see decomposition temperature above).
| [Reactions]
Heating above 900°C expels oxygen out of the molecule forming cobalt(II) oxide:
2Co3O4 6CoO + O2
Tricobalt tetroxide absorbs oxygen at lower temperatures, but there is no change in the crystal structure.)
The oxide is reduced to its metal by hydrogen, carbon or carbon monoxide.
Co3O4 + 4H2 3Co + 4H2O
Co3O4 + 4CO 3Co + 4CO2
| [Sources]
https://en.wikipedia.org/wiki/Cobalt(II,III)_oxide
https://www.alfa.com/zh-cn/catalog/040184/
https://en.wikipedia.org/wiki/Cobalt_oxide_nanoparticle
https://pubchem.ncbi.nlm.nih.gov/compound/6432046#section=Top
|
| Hazard Information | Back Directory | [Chemical Properties]
Black fine powder | [Physical properties]
Black cubic crystal; density 6.11 g/cm3; decomposes above 900°C, losing oxygen; insoluble in water; soluble in acids and alkalis. | [Uses]
In enamels; in semiconductors; in grinding wheels. | [Flammability and Explosibility]
Notclassified |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|