ChemicalBook--->CAS DataBase List--->7787-58-8

7787-58-8

Request For Quotation
7787-58-8 Structure

7787-58-8 Structure
IdentificationMore
[Name]

BISMUTH(III) BROMIDE
[CAS]

7787-58-8
[Synonyms]

BISMUTH BROMIDE
BISMUTH(III) BROMIDE
BISMUTH TRIBROMIDE
bismuth(ii)bromide
Bismuthine, tribromo-
Bismuthine,tribromo-
tribromo-bismuthin
BISMUTH(III) BROMIDE, 98+%
BISMUTH(III) BROMIDE, 99.999%
Bismuth(III)bromide,99%(metalsbasis)
Tribromobismuthine
[EINECS(EC#)]

232-121-1
[Molecular Formula]

BiBr3
[MDL Number]

MFCD00014195
[Molecular Weight]

448.69
[MOL File]

7787-58-8.mol
Chemical PropertiesBack Directory
[Appearance]

Light yellow-gray crystals or crystalline powder
[Melting point ]

218°C
[Boiling point ]

453°C
[density ]

5.7 g/mL at 25 °C(lit.)
[Fp ]

453°C
[solubility ]

reacts with H2O; soluble in dilacid, acetone; insoluble in ethanol
[form ]

powder
[color ]

Yellow
[Water Solubility ]

Decomposes in water.
[Sensitive ]

Hygroscopic
[Merck ]

13,1258
[Major Application]

material synthesis precursor
perovskite solar cells
[InChI]

InChI=1S/Bi.3BrH/h;3*1H/q+3;;;/p-3
[InChIKey]

TXKAQZRUJUNDHI-UHFFFAOYSA-K
[SMILES]

[Bi](Br)(Br)Br
[CAS DataBase Reference]

7787-58-8(CAS DataBase Reference)
[EPA Substance Registry System]

Bismuthine, tribromo- (7787-58-8)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H314-H335
[Precautionary statements ]

P260-P271-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

2827590000
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Bismuth-->Bismuth(III) Oxide-->Hydrobromic acid >33% in acetic acid
[Preparation Products]

O-BROMANIL-->Bismuth subcarbonate-->Tris(4-fluorophenyl)bismuthine
Hazard InformationBack Directory
[Chemical Properties]

Light yellow-gray crystals or crystalline powder
[Uses]

By virtue of their low toxicity and high versatility, hold considerable promise as catalysts for various organic transformations
[Uses]

It catalyzes the formation of cyclic carbonates.
[Production Methods]

Bismuth powder is placed in a retort, Br2 is poured over it, and the mixture is allowed to stand for a few days and then distilled. It is also possible to heat Br2 with Bi in a round-bottom flask equipped with a reflux condenser. Purification is by vacuum distillation.
[reaction suitability]

reagent type: catalyst
core: bismuth
[Synthesis]

Bismuth(III) bromide can be prepared by reacting bismuth(III) oxide with hydrobromic acid. It can also be synthesized by reacting powdered bismuth with bromine.
[References]

[1] Christian, Theresa M., et al. "Bismuth-induced raman modes in GaP1− xBix." Japanese Journal of Applied Physics 55.10 (2016): 108002.
[2] Saboor, Abdul, Shoaib Khalid, and Anderson Janotti. "Band-gap reduction and band alignments of dilute bismide III--V alloys." arXiv preprint arXiv:2411.19257 (2024).
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bismuth(III) bromide, 99% (metals basis)(7787-58-8)
[Sigma Aldrich]

7787-58-8(sigmaaldrich)
7787-58-8 suppliers list
Company Name: Shanghai Yunfu Nano Technology Co., LTD  Gold
Telephone: 021-15796584478 15796584478
Website: https://www.yfnano.com
Company Name: Chongqing Botao Biotechnology Co., LTD  Gold
Telephone: 15223382610
Website: https://www.jooe.com
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: 3B Pharmachem (Wuhan) International Co.,Ltd.  
Telephone: 18930552037
Website: www.chemicalbook.com/showsupplierproductslist13285/0_en.htm
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Telephone: 89508211 18501085097
Website: http://www.hwrkchemical.com
Company Name: BeiJing Hwrk Chemicals Limted  
Telephone: 0757-86329057 18934348241
Website: www.hwrkchemical.com/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Beijing HuaMeiHuLiBiological Chemical   
Telephone: 010-56205725
Website: www.huabeibiochem.com
Company Name: Beijing Universal Century Technology Co., Ltd.  
Telephone:
Website: www.chemicalbook.com/ShowSupplierProductsList16204/0_EN.htm
Company Name: Shanghai Meishui Chemical Technology Co., Ltd  
Telephone: 021-60549325 18616193163
Website: www.chemicalbook.com/ShowSupplierProductsList16215/0_EN.htm
Company Name: Shanghai Macklin Biochemical Co.,Ltd.  
Telephone: 15221275939 15221275939
Website: www.macklin.cn
Company Name: Sigma-Aldrich  
Telephone: 021-61415566 800-8193336
Website: https://www.sigmaaldrich.cn
Company Name: Shanghai YuanYe Biotechnology Co., Ltd.  
Telephone: 15026964105
Website: www.shyuanye.com
Company Name: Shanghai QianYan Bio-technology Co., Ltd  
Telephone: 02781293128
Website: www.chemicalbook.com/ShowSupplierProductsList19348/0_EN.htm
Tags:7787-58-8 Related Product Information
7440-69-9 7785-23-1 1315-11-3 88189-03-1 12048-51-0 603-33-8 10035-06-0 1304-76-3 1345-07-9 7787-60-2 7787-61-3 22306-37-2 7787-64-6 1304-82-1 12124-97-9 34364-26-6 142617-53-6 67874-71-9