| Identification | Back Directory | [Name]
BISMUTH NEODECANOATE | [CAS]
34364-26-6 | [Synonyms]
Coscat 83
NeoBi 200
NeoBi 200BA
BISMUTH NEODECANOATE
Bismut(Ⅲ)Neodecanoate
Bismuth trineodecanoate
BISMUTH(III)NEODECANOATE
bismuth(3+) neodecanoate
New decanoic acid bisMuth
BISMUTH NEODECANOATE, TECH
Neodecanoic acid bismuth salt
Neodecanoicacid,bismuth(3+)salt
neodecanoicacid,bismuth(3++)salt
Bismuth(III) neodecanoate, superconductor grade
Bismuth(III)neodecanoate,superconductorgrade~60%inneodecanoicacid(15-20%Bi) | [EINECS(EC#)]
251-964-6 | [Molecular Formula]
C30H57BiO6 | [MDL Number]
MFCD00070469 | [MOL File]
34364-26-6.mol | [Molecular Weight]
722.75 |
| Chemical Properties | Back Directory | [Appearance]
viscous light yellow liquid | [Boiling point ]
300 °C(lit.)
| [density ]
1.145 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.479(lit.)
| [Fp ]
>230 °F
| [form ]
liquid | [color ]
viscous | [Stability:]
Stable. Incompatible with strong oxidizing agents. Decomposes exothermically at temperatures around 300 C. | [Water Solubility ]
2.76μg/L at 20.1℃ | [InChI]
InChI=1S/3C10H20O2.Bi/c3*1-4-5-6-7-8-10(2,3)9(11)12;/h3*4-8H2,1-3H3,(H,11,12);/q;;;+3/p-3 | [InChIKey]
TUQRJVHQQXIPMN-UHFFFAOYSA-K | [SMILES]
[Bi](OC(=O)C(C)(C)CCCCCC)(OC(=O)C(C)(C)CCCCCC)OC(=O)C(C)(C)CCCCCC | [EPA Substance Registry System]
Bismuth(III) neodecanoate (34364-26-6) |
| Hazard Information | Back Directory | [Chemical Properties]
viscous light yellow liquid | [Uses]
PU catalysts | [Characteristics]
-
Bismuth dodecanoate is an environmentally friendly alternative to lead- and tin-containing catalysts. It exhibits better hydrolytic stability than organotin compounds and lowers the selectivity of reactions with water.
-
It promotes the NCO/OH reaction, suppresses NCO side reactions, and reduces the formation of CO₂ bubbles.
-
The combination of bismuth and zinc produces a synergistic effect, thereby lowering costs.
| [Application]
Bismuth neodecanoate can be used as a catalyst to synthesize:
Thermoplastic polyurethanes by reacting polycaprolactone diols, diisocyanates, and diols with anthracene group.
Polysiloxanes from hydroxy-terminatedpoly(dimethylsiloxanes) and ethyl silicate. | [Preparation]
Synthesis of Bismuth Neodecanoate
In total, 16.31 g (0.03500 mol) of bismuth oxide and 36.17 g (0.2100 mol) of neodecanoic acid were added to a three-necked flask immersed in an oil bath with continuous stirring. The mixture was heated to 120 °C. Then, 10.70 g (0.1050 mol) of acetic anhydride was added portion-wise into the reactor. The resulting mixture was stirred vigorously at 130 °C for 2 h. After the reaction, the generated acetic acid was evaporated, and the product bismuth neodecanoate was obtained with a yield of 98.23%. | [Flammability and Explosibility]
Notclassified | [reaction suitability]
core: bismuth
reagent type: catalyst | [References]
[1] Chen, Y., Zhao, G., Wang, S., He, Y., Han, S., Du, C., Li, S., Fan, Z., Wang, C., & Wang, J. (2019). Platelet-membrane-camouflaged bismuth sulfide nanorods for synergistic radio-photothermal therapy against cancer†. Biomaterials Science, 8, 3450–3459. https://doi.org/10.1039/C9BM00599D
[2] Kang, Y., Yu*, X., Fan, X., Aodenggerile, Zhao, S., Tu, C., Yan, Z., Wang*, R., Li, W., & Qiu*, H. (2020). Tetramodal Imaging and Synergistic Cancer Radio-Chemotherapy Enabled by Multiple Component-Encapsulated Zeolitic Imidazolate Frameworks. ACS Nano, 14 4, 4336–4351. https://doi.org/10.1021/acsnano.9b09858
[3] Liu, H., Jiang, P., Zhang, K., & Dong, Y. (2018). Synthesis of Bismuth(III)Neodecanoate and Its Application to Poly(Vinyl Chloride) as a Thermal Stabilizer. Polymer-Plastics Technology and Engineering, 213 1, 1657–1664. https://doi.org/10.1080/03602559.2017.1410848 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Rhawn Reagent
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| Telephone: |
400-400-1332688 18019345275 |
| Website: |
http://www.rhawn.cn |
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