| Identification | More | [Name]
BISMUTH(III) FLUORIDE | [CAS]
7787-61-3 | [Synonyms]
BISMUTH FLUORIDE
BISMUTH(III) FLUORIDE
BISMUTH(III) TRIFLUORIDE
BISMUTH TRIFLUORIDE
Bismuthine, trifluoro-
trifluoro-bismuthin
trifluoro-Bismuthine
Bismuth(III) fluoride anhydrous
Bismuthfluoride1
Bismuthfluorideanhydrousoffwhitepowder
Bismuthfluoridewhitegrayxtl
Bismuth(III) fluoride 99.99
BISMUTH(III) FLUORIDE 98%
Bismuth(III)fluoride,anhydrous,99%
BISMUTH FLUORIDE, 99.999%
Bismuth(III)fluoride(99.99+%-Bi)PURATREM
Bismuth(III) fluoride 99.999%
Bismuth(III) trifluoride 99.5%
BISMUTH(III) FLUORIDE: (99.999%-BI) PURATREM
Bismuth(III) fluoride, 99.999% (metals basis) | [EINECS(EC#)]
232-124-8 | [Molecular Formula]
BiF3 | [MDL Number]
MFCD00010893 | [Molecular Weight]
265.98 | [MOL File]
7787-61-3.mol |
| Chemical Properties | Back Directory | [Appearance]
White Crystal or crystalline powder | [Melting point ]
727 °C | [Boiling point ]
900°C | [density ]
8.3 g/mL at 25 °C(lit.)
| [refractive index ]
1.74 | [solubility ]
H2O: insoluble(lit.) | [form ]
Powder | [color ]
white-gray cubic crystals, crystalline | [Specific Gravity]
5.32 | [Water Solubility ]
Insoluble in water. Soluble in HF. | [Crystal Structure]
YF3 type | [Sensitive ]
Hygroscopic | [crystal system]
Nogata | [Merck ]
14,1265 | [Space group]
Pnma | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.656 | 0.702 | 0.484 | 90 | 90 | 90 | 0.2228 |
| [Exposure limits]
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3 | [InChI]
1S/Bi.3FH/h;3*1H/q+3;;;/p-3 | [InChIKey]
BRCWHGIUHLWZBK-UHFFFAOYSA-K | [SMILES]
F[Bi](F)F | [CAS DataBase Reference]
7787-61-3(CAS DataBase Reference) | [EPA Substance Registry System]
Bismuthine, trifluoro- (7787-61-3) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [Hazard Note ]
Corrosive | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28261990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
White Crystal or crystalline powder | [Physical properties]
Bismuth fluoride is a heavy, white (gray if impure) crystalline powder, practically insoluble in water. M.p. 725-730°C; d. 8.3. Cubic (dimorphous).
| [Uses]
In the preparation of bismuth pentafluoride, q.v. | [Uses]
It is used in the manufacturing of bismuth pentafluoride. Bismuth(III) fluoride is an attractive reagent and catalyst in organic synthesis owing to its low cost, and ease of handling. It is also used in polarography. | [Preparation]
The preparation method of Bismuth fluoride: Freshly precipitated bismuth hydroxide is evaporated to dryness several times in a Pt dish, using an excess of hydrofluoric acid. It is then calcined in a covered Pt crucible until the HF has completely evaporated.
| [reaction suitability]
reagent type: catalyst
core: bismuth |
|
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Alfa Aesar
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Energy Chemical
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Sigma-Aldrich
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Rhawn Reagent
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3A Chemicals
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400-668-9898 |
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www.3achem.com |
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