| Identification | Back Directory | [Name]
Ruthenium acetylacetonate | [CAS]
14284-93-6 | [Synonyms]
Rutheniumpentanedionate
Tris(2,4-pentanedionato)
Ruthenium acetylacetonate
Acetylacetone Ruthenium Salt
Ruthenium 2,4-pentanedionate
Ruthenium(Ⅲ) acetylacetonate
TrisacetylacetonateRutheniuM
RutheniuM(Ⅲ)2,4-pentanedionate
RUTHENIUM(III) ACETYLACETONATE
Tris(acetylacetonato) ruthenium
RUTHENIUM(III) 2,4-PENTANEDIONATE
Ruthenium(III)acetylacetonate,99%
Acetylacetone Ruthenium(III) Salt
Ruthenium(III) acetylacetonate,97%
Rutheniumacetylacetonateredbrownxtl
TRIS(ACETYLACETONATO)RUTHENIUM(III)
RUTHENIUM (III) ACETYLACETONATE 99%
Tris(acetylaccetonato)rutheniuM (III)
2,4-Pentanedione ruthenium derivative
Tris(2,4-pentanedionato)ruthenium(III)
TRIS(PENTANE-2,4-DIONATO)RUTHENIUM(III)
tris(pentane-2,4-dionato-O,O')ruthenium
RUTHENIUM(III) ACETYLACETONATE FOR SYNTH
2,4-PENTANEDIONE, RUTHENIUM(III) DERIVATIVE
RutheniuM(III) 2,4-pentanedionate, Ru 24% Min
4-pentanedionato-o,o’)-tris((oc-6-11)-rutheniu
RutheniuM(III) acetylacetonate, Ru(CH3COCHCOCH3)3
Tris(acetylacetonato)ruthenium(III) dec. 230-235
RutheniuM(Ⅲ) acetylacetonate, 25% Ru, Product of UMicore
2,4-Pentanedione ruthenium(III) derivative, Ru(acac)3
RutheniuM (III)2,4-Pentanedionate [“RutheniuM Acetylacetonate”]
Acetylacetone Ruthenium(III) Salt
Ruthenium(III) Acetylacetonate
Ruthenium(III) 2,4-pentanedionate~Tris(acetylacetonato)ruthenium(III)~Tris(2,4-pentanedionato)ruthenium(III) | [EINECS(EC#)]
238-193-0 | [Molecular Formula]
C15H21O6Ru | [MDL Number]
MFCD00000030 | [MOL File]
14284-93-6.mol | [Molecular Weight]
398.39 |
| Chemical Properties | Back Directory | [Appearance]
dark-red crystals | [Melting point ]
260 °C (dec.)(lit.)
| [storage temp. ]
Store below +30°C. | [form ]
Crystalline | [color ]
White | [Water Solubility ]
Soluble in most organic solvents such as acetone, chlorinated hydrocarbons, alcohols, cyclohexane and benzene. Insoluble in water. | [InChI]
InChI=1S/3C5H8O2.Ru/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; | [InChIKey]
RTZYCRSRNSTRGC-LNTINUHCSA-K | [SMILES]
[Ru](O/C(/C)=C\C(=O)C)(O/C(/C)=C\C(=O)C)O/C(/C)=C\C(=O)C | [EPA Substance Registry System]
Ruthenium, tris(2,4-pentanedionato-.kappa. O,.kappa.O')-, (OC-6-11)-(14284-93-6) |
| Hazard Information | Back Directory | [Chemical Properties]
dark-red crystals | [Uses]
Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid. | [reaction suitability]
core: ruthenium
reagent type: catalyst | [Purification Methods]
Purify the complex by recrystallisation from *benzene. [Wilkinson J Am Chem Soc 74 6146 1952, Beilstein 1 IV 3677.] |
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