| Identification | More | [Name]
(-)-MENTHYL CHLOROFORMATE | [CAS]
14602-86-9 | [Synonyms]
(1R,2S,5R)-(-)-MENTHYLCHLOROFORMATE
(-)-(1R)-MENTHYL CHLOROFORMATE
(1R)-(-)-MENTHYL CHLOROFORMATE
(-)-CHLOROFORMYLOXY-P-MENTHANE
MCF
(-)-MENTHYL CHLOROFORMATE
Chloroformic acid (1R)-menthyl ester~L-Menthyl chloroformate
L-p-menth-3-yl chloroformate
(-)-(1R)-Menthyl chloroformate (99% EE/GLC)
(1R)-(-)-MENTHYL CHLOROFORMATE 95+%
L-MenthylChloroformate
(1R)-Menthylester
Chloroformicacid
Carbonochloridic acid, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester
chloroformic acid (1r)-menthyl ester
(-)-Menthyloxycarbonyl chloride
(S)-Menthyl chloroformate
Chloroformic acid (1R,3R,4S)-p-menthane-3-yl ester
Chloroformic acid [[1R,2S,5R,(-)]-2-isopropyl-5-methylcyclohexyl] ester
(-)-Chloroformic acid 2-(1-methylethyl)-5-methylcyclohexyl ester | [EINECS(EC#)]
672-624-7 | [Molecular Formula]
C11H19ClO2 | [MDL Number]
MFCD00009694 | [Molecular Weight]
218.72 | [MOL File]
14602-86-9.mol |
| Chemical Properties | Back Directory | [Boiling point ]
108-109 °C11 mm Hg(lit.) | [density ]
1.031 g/mL at 20 °C(lit.)
| [vapor pressure ]
0.01 psi ( 20 °C)
| [refractive index ]
n20/D 1.459
| [Fp ]
158 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Sparingly), Methanol (Sparingly) | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Optical Rotation]
[α]20/D 83°, c = 1 in chloroform | [Sensitive ]
Moisture Sensitive | [BRN ]
2414686 | [InChI]
InChI=1S/C11H19ClO2/c1-7(2)9-5-4-8(3)6-10(9)14-11(12)13/h7-10H,4-6H2,1-3H3/t8-,9+,10-/m1/s1 | [InChIKey]
KIUPCUCGVCGPPA-KXUCPTDWSA-N | [SMILES]
C(Cl)(O[C@@H]1C[C@H](C)CC[C@H]1C(C)C)=O | [CAS DataBase Reference]
14602-86-9(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R23:Toxic by inhalation.
R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3277 6.1/PG 2
| [WGK Germany ]
3
| [F ]
10-19-21 | [HS Code ]
2915.90.5010 | [HazardClass ]
6.1 | [PackingGroup ]
II | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 3 Inhalation
Skin Corr. 1B |
| Hazard Information | Back Directory | [Uses]
Readily forms a chloroimidodicarbonate which asymmetrically chlorinates silyl enol ethers under mild conditions and in good yields. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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