ChemicalBook--->CAS DataBase List--->14647-23-5

14647-23-5

14647-23-5 Structure

14647-23-5 Structure
IdentificationMore
[Name]

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
[CAS]

14647-23-5
[Synonyms]

1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE
[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II)
1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE
[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE
DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II)
1,2-Bis(diphenylphosphinoethane)nickel(II) chloride[Ni(dppe)Cl2]
1,2-Bis-(Diphenylphosphino)EthaneDichloroNickel
1,2-Bis-(Diphenylphosphino)Eth
1,2-Bis (diphenylphosphino)ethane]dichlornickel
1,2-Bis(diphenylphosphino)ethanenickel(II)chloride,99%
1.2-Bis(dipheny phosphine) ethane nickel(II)chloride
1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE[ NI(DPPE)2CL2]
NICL2(DPPE)/ 1,2-BIS(DIPHENY PHOSPHINE) ETHANE NICKEL(II)CHLORIDE
1,2-Bis-(diphenylphosphino)-ethane nickel chloride
1,2-Bis(diphenyl phosphine)ethane nickel(II)dichloride
Dichlorobis(1,2-diphenylphosphino)ethaneünickel(II)
[1,2-Bis(diphenylphosphino)ethane]dichloronickel(Ⅱ) ,99%
[EINECS(EC#)]

629-489-4
[Molecular Formula]

C26H24Cl2NiP2
[MDL Number]

MFCD00013313
[Molecular Weight]

528.02
[MOL File]

14647-23-5.mol
Chemical PropertiesBack Directory
[Appearance]

Orange to red crystalline powder
[Melting point ]

263-265 °C(lit.)
[storage temp. ]

Refrigerator
[solubility ]

Chloroform, Methanol (Sparingly)
[form ]

crystal
[color ]

orange
[Water Solubility ]

insoluble
[Detection Methods]

31P NMR
[Exposure limits]

NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
[Stability:]

Hygroscopic
[InChI]

InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2
[InChIKey]

XXECWTBMGGXMKP-UHFFFAOYSA-L
[SMILES]

[Ni+2].C(P(C1=CC=CC=C1)C1=CC=CC=C1)CP(C1=CC=CC=C1)C1=CC=CC=C1.[Cl-].[Cl-]
[CAS DataBase Reference]

14647-23-5(CAS DataBase Reference)
[Storage Precautions]

Moisture sensitive
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H302+H312+H332-H315-H319-H334-H335-H350
[Precautionary statements ]

P202-P280-P301+P312-P302+P352+P312-P305+P351+P338-P308+P313
[Hazard Codes ]

T,Xn
[Risk Statements ]

R45:May cause cancer.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R42/43:May cause sensitization by inhalation and skin contact .
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S52:Not recommended for interior use on large surface areas .
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

29319090
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Carc. 1B
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Triphenylphosphine-->1,2-Dichloroethane-->Lithium-->1,2-Dibromoethane-->Nickel(II) chloride hexahydrate-->Diphenylphosphine
Hazard InformationBack Directory
[Chemical Properties]

Orange to red crystalline powder
[Uses]

suzuki reaction
[reaction suitability]

core: nickel
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5)1HNMR
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5)IR
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5)Raman
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride(14647-23-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride, 99%(14647-23-5)
[Alfa Aesar]

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%(14647-23-5)
[Sigma Aldrich]

14647-23-5(sigmaaldrich)
[TCI AMERICA]

[1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride,>96.0%(T)(14647-23-5)
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