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15206-55-0

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15206-55-0 Structure

Identification	More
[Name] Methyl benzoylformate
[CAS] 15206-55-0
[Synonyms] BENZOYLFORMIC ACID METHYL ESTER METHYL ALPHA-OXO-PHENYLACETATE METHYL BENZOYLFORMATE METHYL PHENYLGLYOXALATE METHYL PHENYLGLYOXYLATE PHENYLGLYOXYLIC ACID METHYL ESTER alpha-Oxobenzeneacetic acid methyl ester alpha-oxo-benzeneaceticacimethylester Benzeneaceticacid,.alpha.-oxo-,methylester Benzeneaceticacid,-oxo-,methylester Glyoxylic acid, phenyl-, methyl ester Methyl oxophenylacetate Vicure 55 Ethyl-2-thienylglyoxylate PhenylglyoxalicAcidMethylester Methyl Phenyl Glyoxylate (Methyl Benzoyl formate) ACETOCURE MBF METHYLBENZOYLFORMATE(PHENYLGLYOXYLICACIDMETHYLESTER) -Oxophenylessigsuremethylester METHYL-A-OXO-PHENYLACETATE
[EINECS(EC#)] 239-263-3
[Molecular Formula] C9H8O3
[MDL Number] MFCD00008443
[Molecular Weight] 164.16
[MOL File] 15206-55-0.mol

Chemical Properties	Back Directory
[Appearance] CLEAR YELLOW LIQUID
[Melting point ] 16°C
[Boiling point ] 246-248 °C (lit.)
[density ] 1.163 g/mL at 20 °C(lit.)
[vapor pressure ] <0.1 hPa (20 °C)
[refractive index ] n20/D 1.528
[Fp ] >230 °F
[storage temp. ] Store below +30°C.
[form ] Liquid
[color ] Clear yellow
[Specific Gravity] 1.161.155
[Water Solubility ] 2g/L at 20℃
[BRN ] 1100868
[Cosmetics Ingredients Functions] NAIL CONDITIONING
[InChI] 1S/C9H8O3/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6H,1H3
[InChIKey] YLHXLHGIAMFFBU-UHFFFAOYSA-N
[SMILES] COC(=O)C(=O)c1ccccc1
[LogP] 1.9 at 23℃
[CAS DataBase Reference] 15206-55-0(CAS DataBase Reference)
[NIST Chemistry Reference] Benzeneacetic acid, «alpha»-oxo-, methyl ester(15206-55-0)
[EPA Substance Registry System] 15206-55-0(EPA Substance)

Questions And Answer	Back Directory
[Uses] Methyl benzoylformate is a useful research chemical.

Safety Data	Back Directory
[Symbol(GHS) ] GHS08
[Signal word ] Danger
[Hazard statements ] H317-H334-H340
[Precautionary statements ] P501-P261-P272-P202-P201-P280-P284-P302+P352-P308+P313-P362+P364-P304+P340-P333+P313-P405
[Safety Statements ] S24/25:Avoid contact with skin and eyes .
[WGK Germany ] 1
[Autoignition Temperature] >500 °C
[TSCA ] TSCA listed
[REACH Registrations] Active
[HS Code ] 29183000
[Storage Class] 10 - Combustible liquids
[Toxicity] LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rat > 5000 mg/kg

Raw materials And Preparation Products	Back Directory
[Raw materials] Benzene-->Styrene-->Benzoylformic acid-->Benzoyl cyanide-->4,4,4-Trifluoro-3-hydroxy-1-phenyl-but-2-en-1-one-->2,2-dimethoxy-1-phenylethanone-->Benzoylacetonitrile-->Methoxy-phenyl-acetic acid methyl ester-->2-Methoxyacetophenone-->a-Diazo-benzeneacetic acid Methyl ester-->Phenylglyoxal-->Methyl DL-mandelate-->(S)-(+)-Methyl mandelate-->(R)-(-)-Methyl mandelate-->Methyl oxalyl chloride
[Preparation Products] 1-Methyl-3-(a-cyclopentylmandeloyloxy)pyrrolidinehydrochloride-->Methyl a yclopentylmandelate-->1,2-Ethanedione, 1-phenyl-2-(1-piperidinyl)- Piperidine, 1-(oxophenylacetyl)- (9CI)-->(R)-(-)-alpha-(Trifluoromethyl)benzyl alcohol

Material Safety Data Sheet(MSDS)	Back Directory
[msds information] Methyl phenylglyoxylate(15206-55-0).msds

Hazard Information	Back Directory
[Chemical Properties] CLEAR YELLOW LIQUID
[Definition] ChEBI: The methyl ester of phenylglyoxylic acid with methanol. Metabolite observed in cancer metabolism.
[Flammability and Explosibility] Notclassified
[Purification Methods] Purify the ester by radial chromatography (diethyl ether/hexane, 1:1), and dry it at 110-112o/6mm. [Meyers & Oppenlaender J Am Chem Soc 108 1989 1986, Beilstein 10 IV 2738.]

Spectrum Detail	Back Directory
[Spectrum Detail] Methyl benzoylformate(15206-55-0)MS Methyl benzoylformate(15206-55-0)¹HNMR Methyl benzoylformate(15206-55-0)¹³CNMR Methyl benzoylformate(15206-55-0)IR1 Methyl benzoylformate(15206-55-0)Raman

Well-known Reagent Company Product Information	Back Directory
[Acros Organics] Methyl benzoylformate, 99%(15206-55-0)
[Sigma Aldrich] 15206-55-0(sigmaaldrich)
[TCI AMERICA] Methyl Benzoylformate,>97.0%(GC)(15206-55-0)

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