ChemicalBook--->CAS DataBase List--->1759-53-1

1759-53-1

1759-53-1 Structure

1759-53-1 Structure
IdentificationMore
[Name]

Cyclopropanecarboxylic acid
[CAS]

1759-53-1
[Synonyms]

CPC-ACID
CYCLOPROPANECARBOXYLIC ACID
CYCLOPROPANE CARBOYLIC ACID
CYCLOPROPYL CARBOXYLIC ACID
CYCLOPROPYLMETHANOIC ACID
RARECHEM AL BO 0005
TRIMETHYLENECARBOXYLIC ACID
Carboxycyclopropane
Cyclopropionic acid
CYCLOPROPANECARBOXYLIC ACID, 99+%
Cyclopropyl Formic Acid
cyclopropanecarboxylic
Cyclopropanecarboxylic acid 98%
Cyclopropan carboxylic acid
CYCLOPROPANECARBOXYLIC ACID CIPROFLOXACIN
1-[[(1,1-dimethylethoxy)carbonyl]amino]-2-ethenyl-
CYCLOPROPANECARBOXYLIC ACID pure
Cyclopropanecarboxylic acid, 98+%
Cyclopropane-1-carboxylic acid
[EINECS(EC#)]

217-162-5
[Molecular Formula]

C4H6O2
[MDL Number]

MFCD00001287
[Molecular Weight]

86.09
[MOL File]

1759-53-1.mol
Chemical PropertiesBack Directory
[Appearance]

clear colourless to light yellow liquid
[Melting point ]

14-17 °C (lit.)
[Boiling point ]

182-184 °C (lit.)
[density ]

1.081 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.438(lit.)
[Fp ]

161 °F
[storage temp. ]

0-6°C
[solubility ]

soluble in Chloroform, Ethyl Acetate
[form ]

Liquid
[pka]

4.83(at 25℃)
[color ]

Clear colorless to light yellow
[PH]

3 (10g/l, H2O, 22℃)
[Detection Methods]

GC,NMR
[BRN ]

969839
[InChI]

1S/C4H6O2/c5-4(6)3-1-2-3/h3H,1-2H2,(H,5,6)
[InChIKey]

YMGUBTXCNDTFJI-UHFFFAOYSA-N
[SMILES]

OC(=O)C1CC1
[LogP]

0.630
[CAS DataBase Reference]

1759-53-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Cyclopropanecarboxylic acid(1759-53-1)
[EPA Substance Registry System]

1759-53-1(EPA Substance)
Questions And AnswerBack Directory
[Description]

Cyclopropanecarboxylic acid (1759-53-1) is a kind of organic acid. It is a clear liquid used as an intermediate for agrochemicals, pharmaceuticals, and other organic synthesis for the applications of electronics, chemicals, polymer additives, coatings, adhesives, surfactants, and other applications1. Moreover, its derivatives of are used against parasites in plants and animals. For example, the alkynyl esters of cyclopropane-carboxylic acid are used as pesticides. Similarly, cyclopropane carboxylic acid esters containing a polyhalogenated substituent are used as fungicides. The ethyl derivative is reagent used in the addition of cyclopropane and can act as annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions2.
[Uses]

Cyclopropanecarboxylic acid (1759-53-1) is a monocarboxylic acid and a member of cyclopropanes. It is a conjugate acid of a cyclopropanecarboxylate.

Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 3265 8/PG 2
[WGK Germany ]

3
[RTECS ]

GZ1100000
[Hazard Note ]

Irritant/Corrosive
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29162000
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Skin Corr. 1B
[Toxicity]

mouse,LD50,intraperitoneal,172mg/kg (172mg/kg),Journal of Pharmacy and Pharmacology. Vol. 21, Pg. 85, 1969.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Zinc chloride-->Gamma Butyrolactone-->4-Chlorobutyronitrile-->4-Chlorobutyryl chloride-->Butyl butyrate-->Methyl 4-chlorobutyrate
[Preparation Products]

(1-Aminocyclopropyl)methanol-->Permethrin-->Cilastatin-->5-Cyclopropyl-2H-pyrazol-3-ylamine-->Deltamethrin-->(1R-cis)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane carboxylic acid-->Cycloprothrin-->(Bromomethyl)cyclopropane-->3-(1,2,2,2-tetrabromoethyl)-2,2-dimethyl cyclo-propane carboxylic acid-->Ethyl 2,2,3,3-tetramethylcyclopropane-carboxylate-->Cyclopropanecarbonyl Chloride-->Methyl cyclopropane carboxylate-->Cyclopropyl 4-methoxyphenyl ketone-->Ethyl 2,4-dibromobutyrate-->N-Methoxy-N-methylcyclopropanecarboxamide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Trimethylenecarboxylic acid(1759-53-1).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colourless to light yellow liquid
[Definition]

ChEBI: Cyclopropanecarboxylic acid is a monocarboxylic acid and a member of cyclopropanes. It is a conjugate acid of a cyclopropanecarboxylate.
[Preparation]

Cyclopropanecarboxylic acid (1759-53-1) has been prepared by the hydrolysis of cyclopropyl cyanide, although it is unnecessary to isolate the nitrile; by heating cyclopropanedicarboxylic acid; and by the action of alkali on ethyl γ-chlorobutyrate.7 The last two methods do not appear to be of practical importance. The oxidation of cyclopropyl methyl ketone with sodium hypobromite is reported to be an excellent preparative method for this acid.
Org. Synth. 1944, 24, 36
DOI: 10.15227/orgsyn.024.0036
[Biological Functions]

Cyclopropanecarboxylic acid has a hypoglycemic effect.
[Toxicity evaluation]

Cyclopropanecarboxylic acid is a flammable liquid, which is orally toxic and classified as a Category 4 acute oral toxicity. It exhibits moderate toxicity upon skin contact, with severe exposure potentially causing skin burns and eye damage.
Spectrum DetailBack Directory
[Spectrum Detail]

Cyclopropanecarboxylic acid(1759-53-1)MS
Cyclopropanecarboxylic acid(1759-53-1)1HNMR
Cyclopropanecarboxylic acid(1759-53-1)13CNMR
Cyclopropanecarboxylic acid(1759-53-1)IR1
Cyclopropanecarboxylic acid(1759-53-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Cyclopropanecarboxylic acid, 98%(1759-53-1)
[Alfa Aesar]

Cyclopropanecarboxylic acid, 98%(1759-53-1)
[Sigma Aldrich]

1759-53-1(sigmaaldrich)
[TCI AMERICA]

Cyclopropanecarboxylic Acid,>98.0%(GC)(1759-53-1)
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