| Identification | More | [Name]
Cyclopropanecarboxylic acid | [CAS]
1759-53-1 | [Synonyms]
CPC-ACID
CYCLOPROPANECARBOXYLIC ACID
CYCLOPROPANE CARBOYLIC ACID
CYCLOPROPYL CARBOXYLIC ACID
CYCLOPROPYLMETHANOIC ACID
RARECHEM AL BO 0005
TRIMETHYLENECARBOXYLIC ACID
Carboxycyclopropane
Cyclopropionic acid
CYCLOPROPANECARBOXYLIC ACID, 99+%
Cyclopropyl Formic Acid
cyclopropanecarboxylic
Cyclopropanecarboxylic acid 98%
Cyclopropan carboxylic acid
CYCLOPROPANECARBOXYLIC ACID CIPROFLOXACIN
1-[[(1,1-dimethylethoxy)carbonyl]amino]-2-ethenyl-
CYCLOPROPANECARBOXYLIC ACID pure
Cyclopropanecarboxylic acid, 98+%
Cyclopropane-1-carboxylic acid | [EINECS(EC#)]
217-162-5 | [Molecular Formula]
C4H6O2 | [MDL Number]
MFCD00001287 | [Molecular Weight]
86.09 | [MOL File]
1759-53-1.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless to light yellow liquid | [Melting point ]
14-17 °C (lit.) | [Boiling point ]
182-184 °C (lit.) | [density ]
1.081 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.438(lit.)
| [Fp ]
161 °F
| [storage temp. ]
0-6°C | [solubility ]
soluble in Chloroform, Ethyl Acetate | [form ]
Liquid | [pka]
4.83(at 25℃) | [color ]
Clear colorless to light yellow | [PH]
3 (10g/l, H2O, 22℃) | [Detection Methods]
GC,NMR | [BRN ]
969839 | [InChIKey]
YMGUBTXCNDTFJI-UHFFFAOYSA-N | [LogP]
0.630 | [CAS DataBase Reference]
1759-53-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Cyclopropanecarboxylic acid(1759-53-1) | [EPA Substance Registry System]
1759-53-1(EPA Substance) |
| Questions And Answer | Back Directory | [Description]
Cyclopropanecarboxylic acid is a kind of organic acid. It is a clear liquid used as an intermediate for agrochemicals, pharmaceuticals, and other organic synthesis for the applications of electronics, chemicals, polymer additives, coatings, adhesives, surfactants, and other applications1. Moreover, its derivatives of are used against parasites in plants and animals. For example, the alkynyl esters of cyclopropane-carboxylic acid are used as pesticides. Similarly, cyclopropane carboxylic acid esters containing a polyhalogenated substituent are used as fungicides. The ethyl derivative is reagent used in the addition of cyclopropane and can act as annulation reagent for the conversion of aromatics to 2-methylindanones under Friedel-Crafts conditions2. | [Uses]
Cyclopropanecarboxylic acid is a monocarboxylic acid and a member of cyclopropanes. It is a conjugate acid of a cyclopropanecarboxylate.
|
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
GZ1100000
| [Hazard Note ]
Irritant/Corrosive | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29162000 | [Toxicity]
mouse,LD50,intraperitoneal,172mg/kg (172mg/kg),Journal of Pharmacy and Pharmacology. Vol. 21, Pg. 85, 1969. |
| Hazard Information | Back Directory | [Chemical Properties]
clear colourless to light yellow liquid | [Definition]
ChEBI: Cyclopropanecarboxylic acid is a monocarboxylic acid and a member of cyclopropanes. It is a conjugate acid of a cyclopropanecarboxylate. | [Preparation]
Cyclopropanecarboxylic acid has been prepared by the hydrolysis of cyclopropyl cyanide, although it is unnecessary to isolate the nitrile; by heating cyclopropanedicarboxylic acid; and by the action of alkali on ethyl γ-chlorobutyrate.7 The last two methods do not appear to be of practical importance. The oxidation of cyclopropyl methyl ketone with sodium hypobromite is reported to be an excellent preparative method for this acid.
Org. Synth. 1944, 24, 36
DOI: 10.15227/orgsyn.024.0036 |
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