ChemicalBook--->CAS DataBase List--->179897-94-0

179897-94-0

179897-94-0 Structure

179897-94-0 Structure
IdentificationMore
[Name]

5-Fluoro-2-methoxyphenylboronic acid
[CAS]

179897-94-0
[Synonyms]

2-METHOXY-5-FLUOROBENZENEBORONIC ACID
2-METHOXY-5-FLUOROPHENYLBORONIC ACID
3-FLUORO-6-METHOXYBENZENEBORONIC ACID
5-FLUORO-2-METHOXYBENZENEBORONIC ACID
5-FLUORO-2-METHOXYPHENYLBORONIC ACID
AKOS BRN-0214
CHEMBRDG-BB 4202998
RARECHEM AH PB 0134
2-Methoxy-5-Fluoro-Boronicacid
5-Fluoro-2-methoxylboronic acid
2-Methoxy-5-FluorobenzneneboronicAcid
4-Fluoroanisole-2-boronic acid
5-Fluoro-2-methoxyphenylboronic acid ,97%
[Molecular Formula]

C7H8BFO3
[MDL Number]

MFCD01863526
[Molecular Weight]

169.95
[MOL File]

179897-94-0.mol
Chemical PropertiesBack Directory
[Melting point ]

144-153 °C (lit.)
[Boiling point ]

337.1±52.0 °C(Predicted)
[density ]

1.26±0.1 g/cm3(Predicted)
[storage temp. ]

Storage temp. 2-8°C
[solubility ]

soluble in Methanol
[form ]

Crystalline Powder
[pka]

7.52±0.58(Predicted)
[color ]

White
[Detection Methods]

HPLC
[CAS DataBase Reference]

179897-94-0(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280g-P305+P351+P338
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29163990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->n-Butyllithium-->Triisopropyl borate-->4-Fluoroanisole
[Preparation Products]

5-Fluoro-2-methoxybenzonitrile
Hazard InformationBack Directory
[Chemical Properties]

White to off-white powder
[Uses]

5-Fluoro-2-methoxyphenylboronic Acid is an important building blocks in organic syntheses. A reagent for Suzuki coupling reactions and copper catalyzed arylation reactions. A bacterial mutagen.
[Uses]

Reactant for:• ;Suzuki couplings1,2• ;Copper catalyzed arylation3
[Uses]

suzuki reaction
[Synthesis]

There are two main methods to synthesize 5-fluoro-2-methoxyphenylboronic acid: 1) Reacting with p-fluoroanisole and n-butyllithium solution dissolved in THF at -60 . ℃, then react with triisopropyl borate at -70 ℃ and then acidify with hydrochloric acid t
Spectrum DetailBack Directory
[Spectrum Detail]

5-Fluoro-2-methoxyphenylboronic acid(179897-94-0)1HNMR
5-Fluoro-2-methoxyphenylboronic acid(179897-94-0)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

179897-94-0(sigmaaldrich)
179897-94-0 suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: BeiJing Hwrk Chemicals Limted  
Telephone: 0757-86329057 18934348241
Website: www.hwrkchemical.com/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Wuhan Chemwish Technology Co., Ltd  
Telephone: 86-027-67849912
Website: www.chemwish.com
Company Name: Capot Chemical Co., Ltd  
Telephone: +86 (0) 571 85 58 67 18
Website: www.capotchem.com
Company Name: Shanghai Sinch Parmaceuticals Tech. Co. Ltd.  
Telephone: +86-21-54098501
Website: www.sinch.com.cn
Company Name: Shanghai Longsheng chemical Co.,Ltd.  
Telephone: 58099637 13585536065
Website: www.shlshg.com
Company Name: Nanjing Chemlin Chemical Co., Ltd  
Telephone: 025-83697070 13770331960
Website: www.echemlin.cn
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: China DongFan Chemical Co.,LTD  
Telephone: 86-0571-85151182
Website: www.chemicalbook.com/ShowSupplierProductsList14819/0_EN.htm
Company Name: Syntechem Co.,Ltd  
Telephone:
Website: www.syntechem.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: China Langchem Inc.  
Telephone: 0086-21-58956006
Website: www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm
Company Name: Springchem New Material Technology Co.,Limited  
Telephone: +86-021-62885108
Website: http://www.spring-chem.com/
Company Name: Shanghai Sphchem Co., Ltd.  
Telephone: 021-56491756 13512199871
Website: http://www.panhongchem.com
Tags:179897-94-0 Related Product Information
104-47-2 105-13-5 100-07-2 123-11-5 2103-57-3 456-55-3 98-80-6 59-30-3 100-66-3 5720-07-0 586-37-8 7782-41-4 279263-10-4 459-60-9 149507-26-6 162101-31-7 179899-07-1 779331-47-4