| Identification | More | [Name]
Methyl nitroacetate | [CAS]
2483-57-0 | [Synonyms]
METHYL ALFA NITROACETATE
METHYL NITROACETATE
NITROACETIC ACID METHYL ESTER
Methyl 2-nitroacetate
Methyl a-nitroacetate
methyl2-nitroacetate
nitro-aceticacimethylester
Methylnitroacetate,98%
Methyl nitrozcetate | [EINECS(EC#)]
219-622-0 | [Molecular Formula]
C3H5NO4 | [MDL Number]
MFCD00075480 | [Molecular Weight]
119.08 | [MOL File]
2483-57-0.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
2
| [RTECS ]
AJ1093000
| [F ]
8 | [HS Code ]
29161995 |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline. | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 25, p. 266, 1960 DOI: 10.1021/jo01072a606 |
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