| Identification | More | [Name]
1H,1H,2H,2H-Heptadecafluorodecyl acrylate | [CAS]
27905-45-9 | [Synonyms]
1H,1H,2H,2H-HEPTADECAFLUORODECYL ACRYLATE 1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ACRYLATE 1H,1H,2H,2H-PERFLUORODECYL ACRYLATE 2-(PERFLUOROOCTYL)ETHYL ACRYLATE 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-HEPTADECAFLUORODECYL ACRYLATE ACRYLIC ACID 1H,1H,2H,2H-HEPTADECAFLUORO-N-DECYL ESTER ACRYLIC ACID 1H,1H,2H,2H-PERFLUORODECYL ESTER DAIKIN R-1820 TETRAHYDROPERFLUORODECYL ACRYLATE 1,1,2,2-Tetrahydroperfluorodecylacrylate 2-propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylest 2-Propenoicacid,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecylester Acrylic acid 1H,1H,2H,2H-perfluorodecyl ester~1H,1H,2H,2H-Heptadecafluorodecyl acrylate Perfluorodecylacrylate 1H,1H,2H,2H-Heptadecafluorodecyl acrylate, stabilized, 97% acrylic acid 1h,1h,2h,2h-heptadecafluorodecyl ester 1H,1H,2H,2H-Perfluorodecyl acrylate 95% 1H,1H,2H,2H-Perfluorodecylacrylate95% Perfluoroalkylethylacrylate perfluorooctylethyl acrylate | [EINECS(EC#)]
248-722-7 | [Molecular Formula]
C13H7F17O2 | [MDL Number]
MFCD00042306 | [Molecular Weight]
518.17 | [MOL File]
27905-45-9.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Melting point ]
-3°C | [Boiling point ]
90 °C4 mm Hg(lit.)
| [density ]
1.637 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.337(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
0-6°C | [solubility ]
Chloroform, Methanol (Slightly), Water (Sparingly) | [form ]
Liquid | [color ]
Clear colorless | [Specific Gravity]
1.596 | [BRN ]
5173337 | [Stability:]
Light Sensitive | [InChI]
1S/C13H7F17O2/c1-2-5(31)32-4-3-6(14,15)7(16,17)8(18,19)9(20,21)10(22,23)11(24,25)12(26,27)13(28,29)30/h2H,1,3-4H2 | [InChIKey]
QUKRIOLKOHUUBM-UHFFFAOYSA-N | [SMILES]
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)CCOC(=O)C=C | [CAS DataBase Reference]
27905-45-9(CAS DataBase Reference) | [EPA Substance Registry System]
1,1,2,2-Tetrahydroperfluorodecyl acrylate (27905-45-9) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection . S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [F ]
10-23 | [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29161290 | [Storage Class]
6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 4 Inhalation Acute Tox. 4 Oral Carc. 2 Eye Dam. 1 Lact. Repr. 1B STOT RE 1 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
(Perfluorooctyl)ethyl Acrylate is a reagent used in the synthesis of parahydrophobic polymer coatings, as well as polymer brushes for controlling surface lubrication. | [Application]
1H,1H,2H,2H-Heptadecafluorodecyl acrylate can be applied as follows: (1) Coatings Industry: Due to their low surface tension and excellent heat resistance, 1H,1H,2H,2H-Heptadecafluorodecyl acrylate are commonly used in the preparation of high-performance surface coatings, such as water-repellent, oil-repellent, corrosion-repellent, anti-adhesive and temperature-resistant coatings[1-2]. (2) Lubricants: It can be used as a lubricant, especially where oil and water resistance is required. (3) Surface Modifiers: In surface modification of textiles, plastics and other materials, it can provide special surface properties such as anti-staining and anti-adhesion[3]. (4) Electronic encapsulation material: Due to its chemical inertness and heat resistance, it can also be used as encapsulation material for electronic products, such as liquid crystal displays and fibre optic manufacturing. | [Definition]
1H,1H,2H,2H-Heptadecafluorodecyl acrylate is a semi-volatile fluorinated organic compound and is in polluted air in Asia and the western United States during the spring. The structure of this substance contains multiple fluorine atoms and a terminal olefin unit. It has high chemical reactivity and is sensitive to intense light. Perfluorooctylethyl acrylate contains an unsaturated double-bond unit and can be used to prepare perfluoroacrylate polymers. | [Research]
Latex based upon fluorinated acrylates such as perfluorooctylethyl methacrylate (FMA) and perfluorooctylethyl acrylate (FA; 1H,1H,2H,2H-Heptadecafluorodecyl acrylate) and fluorine-free acrylates such as n-butyl methacrylate (BMA) was prepared using emulsion polymerization in the presence of octadecyltrimethylammonium bromide (C18TAB) and 2,2′-azobis(2-amidinopropane) dihydrochloride (V50) as water-soluble azo initiator[4].
| [References]
[1] VIRENDRA KUMAR. Fluorocarbon Coatings Via Plasma Enhanced Chemical Vapor Deposition of 1H,1H,2H,2H‐perfluorodecyl Acrylate ‐ 2, Morphology, Wettability and Antifouling Characterization[J]. Plasma Processes and Polymers, 2010. DOI:10.1002/PPAP.201000038. [2] N. YOSHINO. Syntheses and Reactions of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate[J]. Bulletin of the Chemical Society of Japan, 1993. DOI:10.1246/BCSJ.66.472. [3] JIYOUNG LEE . Robust and superomniphobic core-shell SiO2@poly(1H,1H,2H,2H-heptadecafluorodecyl methacrylate-co-methyl methacrylate) coating materials synthesized by thiol lactam initiated radical polymerization[J]. Progress in Organic Coatings, 2020. DOI:10.1016/j.porgcoat.2020.105851. [4] Reinhard F. Linemann. “Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and Tapping Mode Atomic Force Microscopy of Film Formation.” Macromolecules 32 6 (1999): 1715–1721.
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| Well-known Reagent Company Product Information | Back Directory | [Acros Organics]
1H,1H,2H,2H-Heptadecafluorodecyl acrylate, stabilized, 97%(27905-45-9) | [Alfa Aesar]
1H,1H,2H,2H-Perfluorodecyl acrylate, 96%, stab. with 100ppm 4-methoxyphenol(27905-45-9) | [Sigma Aldrich]
27905-45-9(sigmaaldrich) | [TCI AMERICA]
1H,1H,2H,2H-Heptadecafluorodecyl Acrylate (stabilized with MEHQ),>97.0%(GC)(27905-45-9) |
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