ChemicalBook--->CAS DataBase List--->3279-76-3

3279-76-3

3279-76-3 Structure

3279-76-3 Structure
IdentificationMore
[Name]

2-Hydroxy-6-methylpyridine
[CAS]

3279-76-3
[Synonyms]

6-METHYL-2-PYRIDINONE
6-METHYLPYRIDIN-2(1H)-ONE
AKOS BBS-00002969
TIMTEC-BB SBB004345
2(1H)-Pyridinone,6-methyl-
2(1H)-Pyridone, 6-methyl-
2(1H)-Pyridone,6-methyl-
2-Hydroxy-6-methylpyridin
2-Methyl-6-pyridone
6-Hydroxy-α-picoline
6-Methyl-1H-pyridin-2-one
6-Methyl-2(1H)-pyridone
6-Methyl-2-hydroxypyridine
6-Methyl-2-pyridyl alcohol
6-Methylpyridinone
2-Hydroxy-6-methylpyridine, 97+%
2-Hydroxy-6-methylpyridine
6-Methyl-2-pyridinol
2-HYDROXY-6-METHYLPYRIDINE (2-HYDROXY-6-PICOLINE)
6-hydroxy-2-methylpyridine
[EINECS(EC#)]

221-919-5
[Molecular Formula]

C6H7NO
[MDL Number]

MFCD00456278
[Molecular Weight]

109.13
[MOL File]

3279-76-3.mol
Chemical PropertiesBack Directory
[Appearance]

white to cream-colored crystalline powder
[Melting point ]

157-159 °C (lit.)
[Boiling point ]

131-133C
[density ]

1.1143 (rough estimate)
[refractive index ]

1.5040 (estimate)
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

Crystalline Powder
[pka]

12.12±0.10(Predicted)
[color ]

White to cream
[BRN ]

107073
[InChI]

InChI=1S/C6H7NO/c1-5-3-2-4-6(8)7-5/h2-4H,1H3,(H,7,8)
[InChIKey]

JEAVIRYCMBDJIU-UHFFFAOYSA-N
[SMILES]

C1(=O)NC(C)=CC=C1
[CAS DataBase Reference]

3279-76-3(CAS DataBase Reference)
[NIST Chemistry Reference]

2(1H)-Pyridinone, 6-methyl-(3279-76-3)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S22:Do not breathe dust .
[WGK Germany ]

3
[F ]

10
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT
[HS Code ]

29333999
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

6-Methyl-2-pyridinol(3279-76-3).msds
Questions And AnswerBack Directory
[Application]

2-Hydroxy-6-methylpyridine is a heterocyclic organic compound with wide applications in organic synthesis. This product is basic and can catalyze the silylation of alcohols; it can also deprotect acetals.
Hazard InformationBack Directory
[Chemical Properties]

white to cream-colored crystalline powder
[Uses]

2-Hydroxy-6-methylpyridine reacts with carboxylic acids RCOOH to give an equilibrium mixture of products M(2)(O(2)CR)(n)(mhp)(4-n) where R = 2-thienyl and phenyl. mhp is the anion formed from deprotonation of 2-hydroxy-6-methylpyridine.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 71, p. 1186, 1949 DOI: 10.1021/ja01172a014
[General Description]

2-Hydroxy-6-methylpyridine reacts with carboxylic acids RCOOH to give an equilibrium mixture of products M(2)(O(2)CR)(n)(mhp)(4-n) where R = 2-thienyl and phenyl. mhp is the anion formed from deprotonation of 2-hydroxy-6-methylpyridine.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Hydroxy-6-methylpyridine(3279-76-3)MS
2-Hydroxy-6-methylpyridine(3279-76-3)1HNMR
2-Hydroxy-6-methylpyridine(3279-76-3)13CNMR
2-Hydroxy-6-methylpyridine(3279-76-3)IR1
2-Hydroxy-6-methylpyridine(3279-76-3)IR2
2-Hydroxy-6-methylpyridine(3279-76-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Hydroxy-6-methylpyridine, 97%(3279-76-3)
[Alfa Aesar]

2-Hydroxy-6-methylpyridine, 98%(3279-76-3)
[Sigma Aldrich]

3279-76-3(sigmaaldrich)
[TCI AMERICA]

2-Hydroxy-6-methylpyridine,>97.0%(T)(3279-76-3)
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