| Identification | More | [Name]
4-Benzyloxyaniline hydrochloride | [CAS]
51388-20-6 | [Synonyms]
4-AMINOPHENYL BENZYL ETHER HYDROCHLORIDE
4-BENZYLOXY ANILINE HCL
4-BENZYLOXYANILINE HYDROCHLORIDE
4-BENZYLOXYANILINIUM CHLORIDE
P-BENZYLOXYANILINE HYDROCHLORIDE
TIMTEC-BB SBB000742
4-Aminodiphenyletherhydrochloride
4-BenzyloxyAnilideHydrochloride
4-Benzyloxy Anilide HCl
4-BENZYLOXYANILINE HYDROCHLORIDE 98%
Benzenamine, 4-(phenylmethoxy)-, hydrochloride | [EINECS(EC#)]
257-170-6 | [Molecular Formula]
C13H14ClNO | [MDL Number]
MFCD00012995 | [Molecular Weight]
235.71 | [MOL File]
51388-20-6.mol |
| Chemical Properties | Back Directory | [Appearance]
BROWNISH CRYSTALLINE POWDER | [Melting point ]
228 °C (dec.)(lit.) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Slightly soluble in water insoluble in ether sparingly soluble in methanol | [form ]
Crystalline Powder | [color ]
Brownish | [BRN ]
3633307 | [InChI]
InChI=1S/C13H13NO.ClH/c14-12-6-8-13(9-7-12)15-10-11-4-2-1-3-5-11;/h1-9H,10,14H2;1H | [InChIKey]
KQBDLOVXZHOAJI-UHFFFAOYSA-N | [SMILES]
C1(=CC=C(N)C=C1)OCC1=CC=CC=C1.Cl | [CAS DataBase Reference]
51388-20-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
BW7615000 | [Hazard Note ]
Irritant | [HS Code ]
29222900 |
| Hazard Information | Back Directory | [Chemical Properties]
BROWNISH CRYSTALLINE POWDER | [Uses]
4-(benzyloxy)aniline hydrochloride can be used in chemical synthesis studies. | [Synthesis]
(11-1) Synthesis of 4-benzyloxyaniline hydrochloride: 4.17 g of 4-nitrophenol was dissolved in 40 mL of ethanol, 2.5 g of potassium carbonate and 3.9 mL of benzyl bromide were added to the solution, and the mixture was heated and refluxed for 1.5 hours. After completion of the reaction, the reaction mixture was cooled, the precipitated crystals were collected by filtration and washed with deionized water. Subsequently, the resulting crude product was recrystallized from ethanol to give 6.4 g (94% yield) of colorless needle-like 4-nitrophenol benzyl ether. | [References]
[1] Patent: US5166403, 1992, A |
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