| Identification | More | [Name]
2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide | [CAS]
572-09-8 | [Synonyms]
2,3,4,6-TETRA-O-ACETYL-1-DEOXY-ALPHA-D-GLUCOPYRANOSYL BROMIDE
2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE
2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE BROMIDE
2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL
2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
2,3,4,6-TETRA-O-ACETYL-DEOXY-A-D-GLUCOPYRANOSYL BROMIDE
2,3,4,6-TETRA-O-ACETYLGLUCOSYLROMIDE
ACETOBROMO-ALPHA-D-GLUCOSE
ACETOBROMO-D-GLUCOSE
ACETOBROMOGLUCOSE
ALPHA-ACETOBROMO-D-GLUCOSE
BROMO 2,3,4,6-TETRA-O-ACETYL-A-D-GLUCOPYRANOSE
BROMO-2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE
BROMO 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSIDE
TETRA-O-ACETYL-A-D-GLUCOPYRANOSYL BROMIDE
TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL BROMIDE
acetobromo-a-d-glucose
alpha-d-glucopyranosylbromide,tetraacetate
α-D-Glucopyranosylbromide,tetraacetate
Acetobromglucose | [EINECS(EC#)]
209-339-0 | [Molecular Formula]
C14H19BrO9 | [MDL Number]
MFCD00063254 | [Molecular Weight]
411.2 | [MOL File]
572-09-8.mol |
| Chemical Properties | Back Directory | [Appearance]
White Fluffy Solid | [Melting point ]
86-89 °C
| [alpha ]
194.5 º (c=2,chloroform) | [Boiling point ]
0.125-30 °C(Press: 0.0005 Torr) | [density ]
1.49±0.1 g/cm3(Predicted) | [storage temp. ]
−20°C
| [form ]
Powder | [color ]
White to beige | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
decomposes | [Sensitive ]
Moisture Sensitive | [Merck ]
14,60 | [BRN ]
96669 | [InChIKey]
CYAYKKUWALRRPA-RGDJUOJXSA-N | [CAS DataBase Reference]
572-09-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
-
| [F ]
8-10-21 | [HS Code ]
29400090 |
| Hazard Information | Back Directory | [Chemical Properties]
White Fluffy Solid | [Uses]
An Intermediate in synthesis of ∫-glucosides | [Purification Methods]
If nicely crystalline, recrystallise it from Et2O/pentane or pet ether (b 40-60o). Alternatively dissolve it in diisopropyl ether (dried over CaCl2 for 24hours, then over P2O5 for 24hours) by shaking and warming (for as short a period as possible), and filter warm. Cool to ca 45o, then slowly to room temperature and finally at 5o for more than 2hours. Collect the solid, wash it with cold dry diisopropyl ether and dry it in a vacuum over Ca(OH)2 and NaOH. Store it dry in a desiccator in the dark. Solutions can be stabilised with 2% CaCO3. [Redemann & Niemann Org Synth 65 236 1987, Coll Vol III 11 1955, Beilstein 17/6 V 368.] |
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