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59-50-7

59-50-7 Structure

59-50-7 Structure
IdentificationMore
[Name]

4-Chloro-3-methylphenol
[CAS]

59-50-7
[Synonyms]

2-CHLORO-5-HYDROXYTOLUENE
3-Methyl-4-chlorophenol
4-CHLORO-3-CRESOL
4-CHLORO-3-METHYLHYDROXYBENZENE
4-CHLORO-3-METHYLPHENOL
4-CHLORO-M-CRESOL
4-CMC
6-CHLORO-3-HYDROXYTOLUENE
CHLORO(4-)-3-METHYLPHENOL
PARA CHLORO META CRESOL
P-CHLORO-M-CRESOL
PCMC
1-Chloro-2-methyl-4-hydroxybenzene
2-Chloro-hydroxytoluene
4-chloro-1-hydroxy-3-methylbenzene
4-chloro-3-methyl-pheno
4-chloro-3-methylphenol(p-chlorocresol)
4-Chloro-5-methylphenol
4-chloro-m-creso
ai3-00075
[EINECS(EC#)]

200-431-6
[Molecular Formula]

C7H7ClO
[MDL Number]

MFCD00002323
[Molecular Weight]

142.58
[MOL File]

59-50-7.mol
Chemical PropertiesBack Directory
[Appearance]

White (pure) or pink crystalline solid. Crystals turn pink on exposure to air and light. Phenolic odor.
[Appearance]

white or pink crystals
[Melting point ]

63-65 °C(lit.)
[mp ]

63-65 °C(lit.)
[Boiling point ]

235 °C(lit.)
[bp ]

235 °C(lit.)
[density ]

1.370
[refractive index ]

1.5449 (estimate)
[Fp ]

118 °C
[storage temp. ]

-20°C
[solubility ]

methanol: soluble1g/10 mL, clear, colorless
[form ]

Tablets
[color ]

White
[PH]

6.5 (1g/l, H2O, 20℃)
[Stability:]

Stable. Incompatible with brass, oxidizing agents, copper, copper alloys.
[Water Solubility ]

4 g/L (20 ºC)
[Merck ]

14,2133
[BRN ]

1237629
[InChIKey]

CFKMVGJGLGKFKI-UHFFFAOYSA-N
[Contact allergens]

Chlorocresol is a biocide used for its disinfectant and preservative properties, in topicals or cutting fluid.
[Uses]

P-chloro-m-cresol is used as a preservative in a wide number of topical preparations and is a rare cause of allergic contact dermatitis and CoU, the mechanism of which remains uncertain.
[CAS DataBase Reference]

59-50-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 4-chloro-3-methyl-(59-50-7)
Hazard InformationBack Directory
[Chemical Properties]

white or pink crystals
[Uses]

antiinfectant
[Uses]

Disinfectant; pharmaceutic aid (preservative).
[General Description]

A pinkish to white crystalline solid with a phenolic odor. Melting point 64-66°C. Shipped as a solid or in a liquid carrier. Soluble in aqueous base. Toxic by ingestion, inhalation or skin absorption. Used as an external germicide. Used as a preservative in paints and inks.
[Reactivity Profile]

CHLOROCRESOL(59-50-7)S are incompatible with bases, acid chlorides, acid anhydrides, and oxidizing agents. Corrodes steel, brass, copper and copper alloys .
[Air & Water Reactions]

Hygroscopic. Soluble in aqueous base.
[Hazard]

Irritant to skin.
[Health Hazard]

Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
[Potential Exposure]

Chlorinated phenol fungicide, microbiocide, and germicide used to control bacteria, yeasts, and fungi.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions) if breathing has stopped, and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Do not induce vomiting when formulations containing petroleum solvents are ingested. Otherwise, give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Fire Hazard]

Combustible material: may burn but does not ignite readily. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
[Shipping]

UN2669 Chlorocresols solution, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3437 Chlorocresols solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.
[Incompatibilities]

Chlorocresols react with boranes, alkalies, aliphatic amines, amides, nitric acid, sulfuric acid. Contact with oxidizing agents may cause a fire and explosion hazard. Heat produces phosgene, hydrogen chloride and chlorine gases. Corrosive to aluminum, copper, tin, and other chemically active metals.
[Waste Disposal]

A good candidate for rotary kiln incineration at a temperature range of 820 to 1600C and residence times of seconds for liquids and gases, and hours for solids.
Safety DataBack Directory
[Hazard Codes ]

Xn,N,T,F
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
R50:Very Toxic to aquatic organisms.
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R11:Highly Flammable.
R38:Irritating to the skin.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S16:Keep away from sources of ignition-No smoking .
S7:Keep container tightly closed .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

2
[RTECS ]

GO7100000
[TSCA ]

Yes
[HazardClass ]

6.1(a)
[PackingGroup ]

II
[HS Code ]

29081000
[Safety Profile]

Poison by intravenous, subcutaneous, and intraperitoneal routes. Moderately toxic by ingestion. An allergen. Mutation data reported. Incompatible with sodium hydroxide. When heated to decomposition it emits toxic fumes of Cl and phosgene. See also CRESOL and CHLOROPHENOLS.
[Hazardous Substances Data]

59-50-7(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Sulfuryl chloride-->m-Cresol
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

p-Chloro-m-cresol(59-50-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4-Chloro-3-methylphenol(59-50-7) IR1
4-Chloro-3-methylphenol(59-50-7) 13C NMR
4-Chloro-3-methylphenol(59-50-7) 1H NMR
4-Chloro-3-methylphenol(59-50-7) Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Chloro-3-methylphenol, 99+%(59-50-7)
[Alfa Aesar]

4-Chloro-3-methylphenol, 99%(59-50-7)
[Sigma Aldrich]

59-50-7(sigmaaldrich)
[TCI AMERICA]

4-Chloro-m-cresol,>99.0%(GC)(59-50-7)
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