ChemicalBook--->CAS DataBase List--->624-89-5

624-89-5

624-89-5 Structure

624-89-5 Structure
IdentificationMore
[Name]

Methylthioethane
[CAS]

624-89-5
[Synonyms]

ETHYL METHYL SULFIDE
ETHYL METHYL SULPHIDE
FEMA 3860
METHYL ETHYL SULFIDE
METHYLTHIOETHANE
(methylthio)-ethan
1-(Methylsulfanyl)ethane
2-Thiabutane
C2H5SCH3
ethane,(methylthio)-
Methyl ethyl sulphide
Sulfide, ethyl methyl
ETHYL METHYL SULFIDE 99+%
Ethylmethylsulfide,97%
methylethylsulfide,(methylthio)-ethane,2-thiabutane
1-(Methylthio)-ethane
Ethyl methyl thioether
Methylsulfanylethane
2-(Methylthio)ethane
[EINECS(EC#)]

210-868-4
[Molecular Formula]

C3H8S
[MDL Number]

MFCD00009268
[Molecular Weight]

76.16
[MOL File]

624-89-5.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

-106 °C (lit.)
[Boiling point ]

66-67 °C (lit.)
[density ]

0.842 g/mL at 25 °C(lit.)
[vapor pressure ]

272 mm Hg ( 37.7 °C)
[FEMA ]

3860
[refractive index ]

n20/D 1.440(lit.)
[Fp ]

5 °F
[storage temp. ]

Flammables area
[form ]

liquid
[color ]

Colorless to Light yellow
[Specific Gravity]

0.842
[Odor]

at 0.10 % in propylene glycol. sulfury garlic tomato coffee pyridene cabbage vegetable meaty
[Odor Threshold]

0.00023ppm
[Odor Type]

sulfurous
[Water Solubility ]

Miscible with alcohols and oils. Immiscible with water.
[Specific Heat Capacity]

Cp(liquid):144.6J/(g·K),at 25℃
[JECFA Number]

453
[BRN ]

1696871
[Henry's Law Constant]

4.2×10-3 mol/(m3Pa) at 25℃, Burkholder et al. (2019)
[InChI]

1S/C3H8S/c1-3-4-2/h3H2,1-2H3
[InChIKey]

WXEHBUMAEPOYKP-UHFFFAOYSA-N
[SMILES]

CCSC
[LogP]

1.54
[CAS DataBase Reference]

624-89-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethane, (methylthio)-(624-89-5)
[EPA Substance Registry System]

624-89-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)
GHS02
[Signal word ]

Danger
[Hazard statements ]

H225
[Precautionary statements ]

P210-P233-P303+P361+P353-P370+P378-P403+P235-P501
[Hazard Codes ]

F
[Risk Statements ]

R11:Highly Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[F ]

13
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29309090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Flam. Liq. 2
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium thiomethoxide-->3-(Methylthio)propionaldehyde-->Di-tert-butyl peroxide-->Methyl mercaptan
[Preparation Products]

2-Chloroethyl methyl sulfide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Methylthioethane(624-89-5).msds
Hazard InformationBack Directory
[Description]

Methylthioethane, also known as Ethyl methyl sulfide (abbreviation EMS), is an ether compound with a sulphur-type odour that can be used as a food additive, odourant, and fuel. The reaction products of photolysis of EMS, in decreasing order of importance, are C2H6, CH3SSC2H5, C2H6, CH3SSC2H5, C2H5SSC2H5, CH4, CH3SCH3, C2H5SC2H5, C3H8, C2H4, CH3SSCH3, C4H10, C2H5SH, and CH3SH. In addition, the destruction efficiencies of the EMS pyrolysis and oxidation in a flow reactor were 50% and 99%, respectively. Hydroperoxides and the corresponding peroxyl radicals are important intermediates in the partial oxidation of EMS during atmospheric chemistry and combustion processes.
[Chemical Properties]

clear colorless liquid
[Chemical Properties]

Methyl ethyl sulfide has a cabbage-like odor.
[Occurrence]

Reported found in tomato, cooked chicken, beef and pork, rum, bourbon, whiskey, cocoa and coffee
[Uses]

Ethyl Methyl Sulfide is used as a corrosion inhibitor for zinc metal which finds wide applications like electrode material in batteries, sacrificial anodes and metallic coatings. It is used in mixtures designed to odorize natural gas and is made to by-pass injection system.
[Aroma threshold values]

Aroma characteristics at 0.1%: sulfurous, tomato and cabbage vegetative with dimethyl sulfide, meaty and metallic nuances.
[Taste threshold values]

Taste characteristics at 0.25 to 2 ppm: sulfurous, vegetative, dimethyl sulfide-like sweet corn notes, eggy, meaty and clam nuances
[General Description]

Microwave spectra of the trans isomer of ethyl methyl sulfide and its 10 isotopic species has been investigated. Chlorination of ethyl methyl sulfide with N-chlorosuccinimide and sulfuryl chloride has been reported.
Spectrum DetailBack Directory
[Spectrum Detail]

Methylthioethane(624-89-5)MS
Methylthioethane(624-89-5)1HNMR
Methylthioethane(624-89-5)13CNMR
Methylthioethane(624-89-5)IR1
Methylthioethane(624-89-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Ethyl methyl sulfide, 97%(624-89-5)
[Sigma Aldrich]

624-89-5(sigmaaldrich)
[TCI AMERICA]

Ethyl Methyl Sulfide,>96.0%(GC)(624-89-5)
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