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6313-33-3

6313-33-3 Structure

6313-33-3 Structure
IdentificationMore
[Name]

FORMAMIDINE HYDROCHLORIDE
[CAS]

6313-33-3
[Synonyms]

FORMAMIDINE HYDROCHLORIDE
formamidinium chloride
FORMAMIDINE HYDROCHLORIDE 95+%
FormamidineHCl
5-[(4-METHOXY-2-METHYL-PHENYL)METHYLIDENE]-1,3-DIMETHYL-2-SULFANYLIDENE-1,3-DIAZINANE-4,6-DIONE
[EINECS(EC#)]

228-639-2
[Molecular Formula]

CH5ClN2
[MDL Number]

MFCD00012865
[Molecular Weight]

80.52
[MOL File]

6313-33-3.mol
Questions And AnswerBack Directory
[Synthesis]

Hydrogen chloride (HCl) was added to formamidine acetate (FAAc) and reacted at 0°C (molar ratio HI: FAAc = 1.1:1). The HCl was slowly added to a round-bottom flask containing FAAc, and the mixture was stirred for 2 hours. After the reaction was complete, the reaction solvent was evaporated at 60°C using a rotary evaporator, and the product was recovered. The solid was washed with diethyl ether and recrystallized from ethanol. The resulting white precipitate was dried in a vacuum oven at 65°C for 24 hours. The product was stored in an argon-filled glove box.

Synthetic Route of Formamidine Hydrochloride

Figure: Synthetic Route of Formamidine Hydrochloride

Chemical PropertiesBack Directory
[Melting point ]

84-87 °C(lit.)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Soluble in Ethanol.
[form ]

Solid
[color ]

Off-White
[Water Solubility ]

almost transparency
[Sensitive ]

Hygroscopic
[BRN ]

3906935
[InChI]

InChI=1S/CH4N2.ClH/c2-1-3;/h1H,(H3,2,3);1H
[InChIKey]

NMVVJCLUYUWBSZ-UHFFFAOYSA-N
[SMILES]

C(=N)N.Cl
[CAS DataBase Reference]

6313-33-3(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P271-P261-P280
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

9-21
[HS Code ]

29252900
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Sodium carbonate-->Palladium-->Guanidine hydrochloride-->Cyanamide
[Preparation Products]

4-Hydroxypyrimidine-->4-Chloro-6-trifluoromethylpyrimidine-->4-Hydroxy-6-(trifluoromethyl)pyrimidine-->5-(AMINOMETHYL)PYRIMIDIN-4-AMINE-->4-AMINO-5-IMIDAZOLECARBOXAMIDE-->ETHYL 4-AMINO-5-IMIDAZOLECARBOXYLATE-->4(1H)-Pyrimidinone, 6-(methoxymethyl)- (9CI)-->6-FLUOROQUINAZOLIN-4-ONE-->7-BENZYL-5,6,7,8-TETRAHYDRO4-CHLORO-PYRIDO[3,4-D]PYRIMIDINE HYDROCHLORIDE-->7-CHLORO-4-QUINAZOLINOL-->5H-indeno[1,2-d]pyrimidine-->6-Methyl-1,2,4-triazin-5-ol
Hazard InformationBack Directory
[Chemical Properties]

White solid
[Uses]

5-Methyl-4,6-dihydroxypyrimidine was synthesized from formamidine hydrochloride. N-Formimino-n-glutamate was synthesized from formamidine hydrochloride. Formamidine hydrochloride was used in the synthesis of imidazoleglycerol phosphate (IGP).
[Materials Uses]

FORMAMIDINE HYDROCHLORIDE (FACl) improves the performance of perovskite solar cells (PSCs) and light-emitting diodes (LEDs) by enhancing the crystalline quality and uniformity of perovskite films, which leads to increased device efficiency and stability. In LEDs, FACl contributes to higher luminescence efficiency by reducing non-radiative recombination and optimizing the emission layer's properties.
[storage]

Formamidine hydrochloride should be sealed in dry room temperature.
Spectrum DetailBack Directory
[Spectrum Detail]

FORMAMIDINE HYDROCHLORIDE(6313-33-3)MS
FORMAMIDINE HYDROCHLORIDE(6313-33-3)1HNMR
FORMAMIDINE HYDROCHLORIDE(6313-33-3)13CNMR
FORMAMIDINE HYDROCHLORIDE(6313-33-3)IR1
FORMAMIDINE HYDROCHLORIDE(6313-33-3)IR2
FORMAMIDINE HYDROCHLORIDE(6313-33-3)IR3
FORMAMIDINE HYDROCHLORIDE(6313-33-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

6313-33-3(sigmaaldrich)
[TCI AMERICA]

Formamidine Hydrochloride,>95.0%(T)(6313-33-3)
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