ChemicalBook--->CAS DataBase List--->769-10-8

769-10-8

769-10-8 Structure

769-10-8 Structure
IdentificationMore
[Name]

2-Fluoro-6-nitrotoluene
[CAS]

769-10-8
[Synonyms]

1-FLUOR-2-METHYL-3-NITROBENZENE
1-FLUORO-2-METHYL-3-NITRO-BENZENE
2-FLUORO-6-NITROTOLUENE
2-Fluoro-6-nitrotoluene 98%
2-Fluoro-6-nitrotoluene98%
2-NITRO-6-FLUOROTOLUENE
2-Fluoro-6-nitrotluene
2-methyl-3-fluoronitrobenzene
Benzene, 1-fluoro-2-methyl-3-nitro-
1-Nitro-2-methyl-3-fluorobenzene
[EINECS(EC#)]

212-203-3
[Molecular Formula]

C7H6FNO2
[MDL Number]

MFCD00007197
[Molecular Weight]

155.13
[MOL File]

769-10-8.mol
Chemical PropertiesBack Directory
[Appearance]

colorless to light yellow liqui
[Melting point ]

6.5-7 °C (lit.)
[Boiling point ]

97 °C/11 mmHg (lit.)
[density ]

1.27 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.523(lit.)
[Fp ]

192 °F
[storage temp. ]

Sealed in dry,Room Temperature
[form ]

clear liquid
[color ]

Light yellow to Amber to Dark green
[Specific Gravity]

1.270
[BRN ]

2361978
[InChI]

InChI=1S/C7H6FNO2/c1-5-6(8)3-2-4-7(5)9(10)11/h2-4H,1H3
[InChIKey]

GXPIVRKDWZKIKZ-UHFFFAOYSA-N
[SMILES]

C1(F)=CC=CC([N+]([O-])=O)=C1C
[CAS DataBase Reference]

769-10-8(CAS DataBase Reference)
Questions And AnswerBack Directory
[Preparation]

Using 2-fluoro-4-nitrotoluene as a raw material, 98% pure 2-fluoro-6-nitrotoluene can be obtained through reduction, salt formation (acid dissolution), nitration, diazotization, alcoholysis, and steam distillation.

Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

2811
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29049090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

5-FLUORO-2H-3,1-BENZOXAZINE-2,4(1H)-DIONE-->4-Fluoroindole-->2-Fluoro-5-nitrotoluene-->2-Fluoro-6-nitrobenzoic acid-->3-Fluoro-2-methylphenol-->4-FLUORO (1H)INDAZOLE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Fluoro-6-nitrotoluene(769-10-8).msds
Hazard InformationBack Directory
[Chemical Properties]

colorless to light yellow liqui
[Uses]

2-Fluoro-6-nitrotoluene has been used in the preparation of 4-fluoroindole via Leimgruber-Batcho procedure.
[Uses]

1-Fluoro-2-methyl-3-nitrobenzene
[General Description]

2-Fluoro-6-nitrotoluene undergoes reduction in the presence of stannous chloride, followed by benzoylation to yield N-(3-fluoro-o-tolyl)benzamide. 2-Fluoro-6-nitrotoluene undergoes reaction with concentrated nitric acid at 100°C to yield 2-fluoro-6-nitrobenzoic acid.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Fluoro-6-nitrotoluene(769-10-8)MS
2-Fluoro-6-nitrotoluene(769-10-8)1HNMR
2-Fluoro-6-nitrotoluene(769-10-8)IR1
2-Fluoro-6-nitrotoluene(769-10-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Fluoro-6-nitrotoluene, 98%(769-10-8)
[Alfa Aesar]

2-Fluoro-6-nitrotoluene, 98%(769-10-8)
[Sigma Aldrich]

769-10-8(sigmaaldrich)
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