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64-19-7

64-19-7 Structure

64-19-7 Structure
IdentificationMore
[Name]

Acetic acid glacial
[CAS]

64-19-7
[Synonyms]

CHLORINE IODIDE
CHLOROIODIDE
IODINE CHLORIDE
IODINE MONOCHLORIDE
IODINE MONOCHLORIDE SOLUTION, WIJS
IODINE-MONOCHLORIDE, WIJS
IODINE SOLUTION ACCORDING TO WIJS
IODOCHLORIDE
IODOMONOCHLORIDE
WIJS CHLORIDE
WIJS' CHLORIDE
WIJS IODINE SOLUTION
WIJ'S IODINE SOLUTION
WIJS REAGENT
WIJS' REAGENT
WIJS SOLUTION
WIJS' SOLUTION
Acetasol
aceticacid(non-specificname)
aceticacid(solutionsgreaterthan10%)
[EINECS(EC#)]

232-236-7
[Molecular Formula]

C2H4O2
[MDL Number]

MFCD00011354
[Molecular Weight]

60.05
[MOL File]

64-19-7.mol
Chemical PropertiesBack Directory
[Description]

Acetic acid is a colourless liquid or crystal with a sour, vinegar-like odour and is one of the simplest carboxylic acids and is an extensively used chemical reagent. Acetic acid has wide application as a laboratory reagent, in the production of cellulose acetate mainly for photographic film and polyvinyl acetate for wood glue, synthetic fibres, and fabric materials. Acetic acid has also been of large use as a descaling agent and acidity regulator in food industries.
[Appearance]

Clear colorless liquid
[Appearance]

Description: Acetic acid is a colorless liquid or crystals with a sour, vinegar-like odor. Pure compound is a solid below 17 C. Often used in an aqueous solution. Glacial acetic acid contains 99% acid.
[mp ]

16.2 °C(lit.)
[bp ]

117-118 °C(lit.)
[density ]

1.049 g/mL at 25 °C(lit.)
[vapor density ]

2.07 (vs air)
[vapor pressure ]

11.4 mm Hg ( 20 °C)
[FEMA ]

2006
[refractive index ]

n20/D 1.371(lit.)
[Fp ]

104 °F
[storage temp. ]

Store at RT.
[Water Solubility ]

miscible
[Usage]

Acetic acid is used as table vinegar, as preservative and as an intermediate in the chemical industry, e.g. acetate fibers, acetates, acetonitrile, pharmaceuticals, fragrances, softening agents, dyes (indigo) etc. Product Data Sheet
[Merck ]

14,55
[Uses]

Glacial Acetic Acid is an acidulant that is a clear, colorless liquid which has an acid taste when diluted with water. It is 99.5% or higher in purity and crystallizes at 17°c. It is used in salad dressings in a diluted form to provide the required acetic acid. It is used as a preservative, acidulant, and flavoring agent. It is also termed acetic acid, glacial.
[CAS DataBase Reference]

64-19-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Acetic acid(64-19-7)
[EPA Substance Registry System]

64-19-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R42:May cause sensitization by inhalation.
R35:Causes severe burns.
R10:Flammable.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

UN 1792 8/PG 2
[WGK Germany ]

3
[RTECS ]

NN1650000
[F ]

1-8-10
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29152100
[Safety Profile]

A human poison by an unspecified route. Moderately toxic by various routes. A severe eye and skin irritant. Can cause burns, lachrymation, and conjunctivitis. Human systemic effects by ingestion: changes in the esophagus, ulceration, or bleeding from the small and large intestines. Human systemic irritant effects and mucous membrane irritant. Experimental reproductive effects. Mutation data reported. A common air contaminant. A flammable liquid. A fire and explosion hazard when exposed to heat or flame; can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical, alcohol foam, foam and mist. When heated to decomposition it emits irritating fumes. Potentially explosive reaction with 5azidotetrazole, bromine pentafluoride, chromium trioxide, hydrogen peroxide, potassium permanganate, sodium peroxide, and phosphorus trichloride. Potentially violent reactions with acetaldehyde and acetic anhydride. Ignites on contact with potassium tert-butoxide. Incompatible with chromic acid, nitric acid, 2-amino-ethanol, NH4NO3, ClF3, chlorosulfonic acid, (O3 + diallyl methyl carbinol), ethplenediamine, ethylene imine, (HNO3 + acetone), oleum, HClO4, permanganates, P(OCN)3, KOH, NaOH, xylene
[Hazardous Substances Data]

64-19-7(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Etanol-->Methanol-->Nitrogen-->Iodomethane-->Oxygen-->Activated carbon-->CARBON MONOXIDE-->Potassium dichromate-->(3R,4S)-1-Benzoyl-3-(1-methoxy-1-methylethoxy)-4-phenyl-2-azetidinone-->PETROLEUM ETHER-->PASSION FLOWER OIL-->Acetylene-->Acetaldehyde-->MERCURY-->N-BUTANE-->Cobalt acetate-->(2S)-1-(3-Acetylthio-2-methyl-1-oxopropyl)-L-proline-->5-(Acetamido)-N,N'-bis(2,3-dihydroxypropyl)-2,4,6-triiodo-1,3-benzenedicarboxamide-->MANGANESE(II) ACETATE-->Mixed acid
[Preparation Products]

Hydroxy silicone oil emulsion-->Dye-fixing agent G-->1H-INDAZOL-7-AMINE-->5-Nitrothiophene-2-carboxylic acid-->4-BROMOPHENYLUREA-->3-Amino-4-bromopyrazole-->3-Hydroxy-2,4,6-tribromobenzoic acid-->2,3-Dimethylpyridine-N-oxide-->N-(6-CHLORO-3-NITROPYRIDIN-2-YL)ACETAMIDE-->Ethyltriphenylphosphonium acetate-->2-ACETYLAMINO-5-BROMO-6-METHYLPYRIDINE-->ISOQUINOLINE N-OXIDE-->2-Amino-5-bromo-4-methylpyridine-->ETHYLENEDIAMINE DIACETATE-->Zirconium acetate-->Chromic acetate-->γ-L-glutamyl-1-naphthylamide-->6-NITROPIPERONAL-->Levothyroxine sodium -->DL-GLYCERALDEHYDE-->METHYL-(3-PHENYL-PROPYL)-AMINE-->6-Nitroindazole-->3,3-Bis(3-methyl-4-hydroxyphenyl)indoline-2-on-->2-BROMO-2'-HYDROXYACETOPHENONE-->ALLOXAN MONOHYDRATE-->4-CHLORO-3-METHYL-1H-PYRAZOLE-->7-Nitroindazole-->5-BROMO-2-HYDROXY-3-METHOXYBENZALDEHYDE-->3,5-Dibromosalicylic acid-->4,5-Dichloronaphthalene-1,8-dicarboxylic anhydride-->2-Bromocinnamaldehyde-->4-(DIMETHYLAMINO)PHENYL THIOCYANATE-->10-Nitroanthrone-->Ethyl trichloroacetate-->1,3-Dithiane-->Cellulose diacetate plastifier-->4-(1H-PYRROL-1-YL)BENZOIC ACID-->(1R,2R)-(+)-1,2-Diaminocyclohexane L-tartrate-->Benzopinacole-->4-BROMOCATECHOL
Hazard InformationBack Directory
[General Description]

A colorless aqueous solution. Smells like vinegar. Density 8.8 lb/gal. Corrosive to metals and tissue.
[Reactivity Profile]

ACETIC ACID, [AQUEOUS SOLUTION] reacts exothermically with chemical bases. Subject to oxidation (with heating) by strong oxidizing agents. Dissolution in water moderates the chemical reactivity of acetic acid, A 5% solution of acetic acid is ordinary vinegar. Acetic acid forms explosive mixtures with p-xylene and air (Shraer, B.I. 1970. Khim. Prom. 46(10):747-750.).
[Air & Water Reactions]

Dilution with water releases some heat.
[Hazard]

Corrosive; exposure of small amounts can severely erode the lining of the gastrointestinal tract; may cause vomiting, diarrhea, bloody feces and urine; cardiovascular failure and death.
[Health Hazard]

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
[Potential Exposure]

Acetic acid is widely used as a chemical feedstock for the production of vinyl plastics, acetic anhydride, acetone, acetanilide, acetyl chloride, ethyl alcohol, ketene, methyl ethyl ketone, acetate esters, and cellulose acetates. It is also used alone in the dye, rubber, pharmaceutical, food preserving, textile, and laundry industries. It is utilized, too; in the manufacture of Paris green, white lead, tint rinse, photographic chemicals, stain removers, insecticides, and plastics.
[Fire Hazard]

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 30 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing, and wash with soap immediately. When this chemical has been swallowed, get medical attention. If victim is conscious, administer water or milk. Do not induce vomiting. If this chemical has been inhaled, remove from exposure, begin (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. If swallowed, do not induce vomiting. Transfer promptly to a medical facility. Medical observation recommended for 24 to 48 hours following inhalation overexposure, as pulmonary edema may be delayed.
[Shipping]

UN2789 Acetic acid, glacial or Acetic acid solution, with .80 % acid, by mass, hazard class: 8; labels: 8-Corrosive material, 3-flammable liquid. UN2790 acetic acid solution, not ,50% but not .80% acid, by mass, hazard class: 8; labels: 8-Corrosive material; acetic acid solution, with .10% and ,50%, by mass, hazard class: 8; labels: 8-Corrosive material
[Incompatibilities]

Vapor may form explosive mixture with air. Violent reaction with oxidizers, organic amines, and bases, such as hydroxides and carbonates. Incompatible with strong acids; aliphatic amines; alkanolamines, isocyanates, alkylene oxides; epichlorohydrin, acetaldehyde, 2-aminoethanol, ammonia, ammonium nitrate, chlorosulfonic acid, chromic acid; ethylene diamine, ethyleneimine, halides, peroxides, perchlorates, perchloric acid, permanganates, phosphorus isocyanate, phosphorus trichloride, potassium tert-butoxide, and xylene. Attacks cast iron, stainless steel; and other metals forming flammable/explosive hydrogen gas. Will attack many forms of rubber or plastic.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Acetic acid glacial(64-19-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Acetic acid glacial(64-19-7) MS
Acetic acid glacial(64-19-7) 13C NMR
Acetic acid glacial(64-19-7) 1H NMR
Acetic acid glacial(64-19-7) IR1
Acetic acid glacial(64-19-7) Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Acetic acid, for biochemistry, 99.8%(64-19-7)
[Alfa Aesar]

Acetic acid, glacial, ACS, 99.7+%(64-19-7)
[Sigma Aldrich]

64-19-7(sigmaaldrich)
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