ChemicalBook--->CAS DataBase List--->80-11-5

80-11-5

80-11-5 Structure

80-11-5 Structure
IdentificationMore
[Name]

N-Methyl-N-nitrosotoluene-4-sulphonamide
[CAS]

80-11-5
[Synonyms]

DIAZALD
DIAZALD(R)
DIAZOGEN
DIAZOMETHANE PRECURSOR
N-METHYL-N-NITROSO-P-TOLUENESULFONAMIDE
n-methyl-n-nitrosotoluene-4-sulphonamide
N-METHYL-N-(P-TOLYLSULFONYL)NITROSAMIDE
N-NITROSO-N-METHYL-P-TOLUENESULFONAMIDE
N-NITROSO-P-TOLUENESULFOMETHYLAMIDE
P-TOLUENESULFONYL-N-METHYL-N-NITROSAMIDE
P-TOLUENESULFONYL-N-METHYL-N-NITROSOAMIDE
P-TOLYLSULFOMETHYLNITROSAMIDE
P-TOLYLSULFONYLMETHYLNITROSAMIDE
Benzenesulfonamide, N,4-dimethyl-N-nitroso-
Benzenesulfonamide,N,4-dimethyl-N-nitroso-
Diazale
diazalo
Methylnitroso-p-toluenesulfonamide
n,4-dimethyl-n-nitroso-benzenesulfonamid
N,4-dimethyl-N-nitroso-Benzenesulfonamide
[EINECS(EC#)]

201-252-6
[Molecular Formula]

C8H10N2O3S
[MDL Number]

MFCD00002050
[Molecular Weight]

214.24
[MOL File]

80-11-5.mol
Chemical PropertiesBack Directory
[Appearance]

pale yellow crystalline powder
[Melting point ]

~58 °C
[Boiling point ]

320.5±35.0 °C(Predicted)
[density ]

1.3844 (rough estimate)
[refractive index ]

1.5690 (estimate)
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Dichloromethane (Sparingly), DMSO (Slightly), Ethyl Acetate
[form ]

Solid
[pka]

-19.25±0.70(Predicted)
[color ]

Pale Yellow to Yellow
[Stability:]

Stable, but heat sensitive; may also be light sensitive. Incompatible with strong oxidizing agents, alkalies.
[Merck ]

13,9621
[CAS DataBase Reference]

80-11-5(CAS DataBase Reference)
[NIST Chemistry Reference]

N-methyl-n-nitroso, p-toluene sulfonamide(80-11-5)
[EPA Substance Registry System]

80-11-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H335-H317-H315-H242-H319
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P-P210-P220-P234-P280-P370+P378-P403+P235-P411-P420-P501-P261-P272-P280-P302+P352-P333+P313-P321-P363-P501
[Hazard Codes ]

E,Xi,Xn
[Risk Statements ]

R2:Risk of explosion by shock, friction, fire or other sources of ignition.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S15:Keep away from heat .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S35:This material and its container must be disposed of in a safe way .
S36/37:Wear suitable protective clothing and gloves .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3234 4.1/PG 2
[WGK Germany ]

2
[RTECS ]

XT5950000
[TSCA ]

TSCA listed
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29350090
[Hazardous Substances Data]

80-11-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tosyl chloride-->Benzenesulfonicacid, 4-methyl-, 1-methylhydrazide-->(Z)-Potassiummethanediazotate-->Nitrous acid, cyclopentyl ester-->Methylamine-->N-Methyl-p-toluenesulfonamide
[Preparation Products]

methyl 2-(7-hydroxybenzofuran-3-yl)acetate-->7-Methoxy-3(2H)-benzofuranone-->N-Nitroso-di-iso-propylamine-->tert-butyl 2-oxo-8-azaspiro[4.5]decane-8-carboxylate-->1-(4-bromophenyl)-2-chloroethan-1-one-->3,4-Dimethoxy-3-cyclobutene-1,2-dione-->Bicyclo[3.3.2]decan-9-one-->methyl 2-amino-4,6-dimethoxybenzoate
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Diazald(80-11-5).msds
Hazard InformationBack Directory
[Chemical Properties]

pale yellow crystalline powder
[Uses]

In the laboratory preparation of diazomethane. Directions for use: de Boer, Backer, Rec. Trav. Chim. 73, 232 (1954).
[Uses]

N-Methyl-N-nitroso-p-toluenesulfonamide is Diazomethane precursor.
[Definition]

ChEBI: N,4-dimethyl-N-nitrosobenzenesulfonamide is a sulfonamide.
[Purification Methods]

Crystallise diazald from *benzene by addition of pet ether and store it in a refrigerator. It is soluble in most organic solvents and liberates diazomethane on treatment with alkali. Store it in the cold. [deBoer & Backer Org Synth 34 96 1954, Beilstein 11 I 29.]
Spectrum DetailBack Directory
[Spectrum Detail]

N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)MS
N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)1HNMR
N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)13CNMR
N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)IR1
N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)IR2
N-Methyl-N-nitrosotoluene-4-sulphonamide(80-11-5)IR3
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

80-11-5(sigmaaldrich)
80-11-5 suppliers list
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: BeiJing Hwrk Chemicals Limted  
Telephone: 0757-86329057 18934348241
Website: www.hwrkchemical.com/
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Beijing Ouhe Technology Co., Ltd  
Telephone: 13552068683 13522913783
Website: www.ouhetech.cn/
Company Name: JinYan Chemicals(ShangHai) Co.,Ltd.  
Telephone: 13817811078
Website: www.jingyan-chemical.com
Company Name: Shanghai Longsheng chemical Co.,Ltd.  
Telephone: 58099637 13585536065
Website: www.shlshg.com
Company Name: Nanjing Chemlin Chemical Co., Ltd  
Telephone: 025-83697070 13770331960
Website: www.echemlin.cn
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Chemsky (shanghai) International Co.,Ltd  
Telephone: 021-50135380
Website: www.shchemsky.com
Company Name: XiaoGan ShenYuan ChemPharm co,ltd  
Telephone: 15527621225; 15527621225
Website: http://www.farchem.com/
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: HuiFeiChem(WuXi) PharmaTech Co.,Ltd  
Telephone: 0510-0510-83593305
Website: http://www.huifeichem.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Shanghai Sunway Pharmaceutical Technology Co., Ltd  
Telephone: 13761987713
Website: www.sunwaypharm.cn
Company Name: Spectrum Chemical Manufacturing Corp.  
Telephone: 021-021-021-67601398-809-809-809 15221380277
Website: www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us
Tags:80-11-5 Related Product Information
79-20-9 36635-61-7 99-76-3 13630-19-8 1333-07-9 96-33-3 1910-42-5 70-55-3 67-56-1 143390-89-0 41663-84-7 63-74-1 75-05-8 477600-73-0 640-61-9 7757-82-6 74-83-9 80-11-5