ChemicalBook--->CAS DataBase List--->88-45-9

88-45-9

88-45-9 Structure

88-45-9 Structure
IdentificationMore
[Name]

2,5-Diaminobenzenesulfonic acid
[CAS]

88-45-9
[Synonyms]

1,4 DIAMINOBENZENE 2 SULFONIC ACID
1,4-PHENYLENEDIAMINE-2-SULPHONIC ACID
1,4-PHENYLENEDIAMINE-3-SULFONIC ACID
2,5-DIAMINOBENZENESULFONIC ACID
PARA PHENYLENE DIAMINE SULFONIC ACID
P-PHENYLENEDIAMINESULFONIC ACID
2,5-diamino-benzenesulfonicaci
2,5-diaminobenzenesulphonic acid
P-phenylene-diamine-ortho-sulphonic acid
p-Phenylenediamine-3-sulfonic acid
2,5-DIAMINOBENZENESULFONIC ACID, TECH., 90%
p-Phenylenediamine-2-sulfonic acid
2,5-Diaminobenzolsulfonsure
p-Phenylenediamine-5-sulfonic acid
2-Sulfo-1,4-phenylenediamine
1,4-Diamino-2-benzenesulfonic acid
2,5-Diaminophenyl-1-sulfonic acid
2,5-Diaminobenzene-1-sulfonic acid
[EINECS(EC#)]

201-832-9
[Molecular Formula]

C6H8N2O3S
[MDL Number]

MFCD00007904
[Molecular Weight]

188.2
[MOL File]

88-45-9.mol
Chemical PropertiesBack Directory
[Appearance]

violet powder
[Melting point ]

298-300 °C (dec.) (lit.)
[Boiling point ]

500°C
[density ]

1.366 (estimate)
[vapor pressure ]

0Pa at 25℃
[refractive index ]

1.6490 (estimate)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

2.308g/L in organic solvents at 20 ℃
[form ]

solid
[pka]

5.17±0.10(Predicted)
[color ]

White to Light gray to Light orange
[Water Solubility ]

4g/L at 26℃
[BRN ]

2970398
[InChI]

1S/C6H8N2O3S/c7-4-1-2-5(8)6(3-4)12(9,10)11/h1-3H,7-8H2,(H,9,10,11)
[InChIKey]

HEAHMJLHQCESBZ-UHFFFAOYSA-N
[SMILES]

Nc1ccc(N)c(c1)S(O)(=O)=O
[LogP]

0.146 at 26℃
[CAS DataBase Reference]

88-45-9(CAS DataBase Reference)
[EPA Substance Registry System]

88-45-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 2583 8/PG 2
[WGK Germany ]

2
[RTECS ]

DB5900100
[TSCA ]

TSCA listed
[HS Code ]

2921.59.8090
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Skin Corr. 1B
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Reactive Blue 74-->disodium 5-((4-acetylamino-2-sulphophenyl)azo)-6-amino-4-hydroxynaphthalene-2-disulphonate-->Reactive Blue 49-->REACTIVE BLUE 2-->hexasodium 4-amino-3,6-bis[[4-[[4-chloro-6-[(3-sulphonatophenyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulphonatophenyl]azo]-5-hydroxynaphthalene-2,7-disulphonate-->Benzenesulfonic acid, 2-[[2-(methylamino)-1-naphthalenyl]azo]-5-nitro-, monosodium salt-->Acid Yellow 158:1-->Reactive Blue 94-->4-Amino-3-[[4'-[(2,7-diamino-1-naphtyl)azo]-1,1'-biphenyl-4-yl]azo]-5-hydroxy-6-[(4-nitro-2-sulfophenyl)azo]-2,7-naphthalenedisulfonic acid trisodium salt-->Levafix Brilliant Blue E-B-->Reactive Orange 29-->REACTIVE ORANGE 14-->Direct Red 75 tetrasodium salt-->Acid Red 34-->1-amino-4-(4-amino-2-sulphoanilino)-9,10-dihydro-9,10-dioxoanthracene-2-sulphonic acid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,5-Diaminobenzenesulfonic acid(88-45-9).msds
Hazard InformationBack Directory
[Chemical Properties]

violet powder
[Uses]

2,5-Diaminobenzenesulfonic acid was used in preparation of a polymeric dye, required for laccase-mediated dyeing of cotton.
[General Description]

2,5-Diaminobenzenesulfonic acid is a dye precursor. Electrochemical copolymerization of 2,5-diaminobenzensulfonic acid and aniline by cyclic voltammetry on IrO2 coated titanium electrodes was reported.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

Weigh 39g of iron powder added to 1000mL four flask, add water 300mL stirring, add 6g of ammonium chloride and 4mL concentrated hydrochloric acid, warming to 95 ℃, slowly add nitro to add speed to regulate the temperature to maintain above 90 ℃, add too f
Spectrum DetailBack Directory
[Spectrum Detail]

2,5-Diaminobenzenesulfonic acid(88-45-9)MS
2,5-Diaminobenzenesulfonic acid(88-45-9)1HNMR
2,5-Diaminobenzenesulfonic acid(88-45-9)IR1
2,5-Diaminobenzenesulfonic acid(88-45-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,5-Diaminobenzenesulfonic acid, tech., 90%(88-45-9)
[Sigma Aldrich]

88-45-9(sigmaaldrich)
[TCI AMERICA]

1,4-Phenylenediamine-2-sulfonic Acid,>98.0%(LC)(T)(88-45-9)
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