ChemicalBook--->CAS DataBase List--->88-60-8

88-60-8

88-60-8 Structure

88-60-8 Structure
IdentificationMore
[Name]

6-tert-Butyl-m-cresol
[CAS]

88-60-8
[Synonyms]

2-TERT-BUTYL-5-METHYLPHENOL
5-METHYL-2-TERT-BUTYLPHENOL
6-T-BUTYL-M-CRESOL
6-TERT-BUTYL-3-METHYLPHENOL
6-TERT-BUTYL-M-CRESOL
6-TERT-BUTYL META-CRESOL
TIMTEC-BB SBB007878
1-tert-butyl-2-hydroxy-4-methyl-benzen
2-(1,1-dimethylethyl)-5-methyl-pheno
2-(1,1-dimethylethyl)-5-methylphenol
2-(1,1-dimethylethyl)-5-methyl-Phenol
2-1,1-dimethylethyl-5-methyl-phenol
2-t-Butyl-5-methylphenol
2-tert-butyl-5-methyl-pheno
3-Methyl-6-tert-butylphenol
6-tert.-Butyl-m-kresol
6-tert-butyl-m-creso
m-Cresol, 6-tert-butyl-
m-cresol,6-tert-butyl-
Phenol,2-(1,1-dimethylethyl)-5-methyl-
[EINECS(EC#)]

201-842-3
[Molecular Formula]

C11H16O
[MDL Number]

MFCD00002308
[Molecular Weight]

164.24
[MOL File]

88-60-8.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless viscous liquid
[Melting point ]

20 °C
[Boiling point ]

117-118 °C12 mm Hg(lit.)
[density ]

0.964 g/mL at 25 °C(lit.)
[vapor pressure ]

3Pa at 23℃
[refractive index ]

n20/D 1.519(lit.)
[Fp ]

222 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[Water Solubility ]

Insoluble in water
[form ]

Notspecified
[pka]

11.45±0.10(Predicted)
[color ]

Colorless to Red to Green
[Specific Gravity]

0.9590.964
[Odor]

at 0.10 % in dipropylene glycol. russian leather
[Odor Type]

animal
[InChI]

1S/C11H16O/c1-8-5-6-9(10(12)7-8)11(2,3)4/h5-7,12H,1-4H3
[InChIKey]

XOUQAVYLRNOXDO-UHFFFAOYSA-N
[SMILES]

Cc1ccc(c(O)c1)C(C)(C)C
[LogP]

3.97
[CAS DataBase Reference]

88-60-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 2-(1,1-dimethylethyl)-5-methyl-(88-60-8)
[EPA Substance Registry System]

6-tert-Butyl-m-cresol (88-60-8)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
[Hazard Codes ]

Xn,C
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3145 8/PG 3
[WGK Germany ]

2
[RTECS ]

SK1578180
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29071990
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
[Hazardous Substances Data]

88-60-8(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Zinc chloride-->tert-Butanol-->Isobutylene-->m-Cresol-->Benzenemethanol, 3-bromo-4-(1,1-dimethylethyl)--->3-T-BUTOXYTOLUENE-->Phenol,2,6-bis(1,1-dimethylethyl)-3-methyl--->2-tert-butyl-5-methylanisole-->methyl 3-bromo-4-tert-butylbenzoate-->3-BROMO-4-TERT-BUTYLBENZOICACID-->4-tert-butyl-m-cresol-->4,6-Di-tert-butyl-m-cresol-->Sulfuric acid
[Preparation Products]

4,4'-Thiobis(6-tert-butyl-m-cresol)-->Thymol
Hazard InformationBack Directory
[General Description]

A clear colorless liquid. Flash point 116°F. Melting point 74°F. Less dense than water and insoluble in water. Used as a disinfectant, to make rubber, as a lubricating oil additive, and for many other uses.
[Reactivity Profile]

Phenols, such as MONO-TERT-BUTYL-M-CRESOL(88-60-8), do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.
[Air & Water Reactions]

Flammable. Insoluble in water.
[Health Hazard]

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Chemical Properties]

clear colorless viscous liquid
[Uses]

6-Tert-Butyl-m-cresol is used as organic synthesis intermediate used in the production of phenolic antioxidants CA, antioxidant 300, and antioxidant BBM.
[Synthesis Reference(s)]

Tetrahedron Letters, 31, p. 6977, 1990 DOI: 10.1016/S0040-4039(00)97220-4
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

6-tert-Butyl-m-cresol(88-60-8).msds
Spectrum DetailBack Directory
[Spectrum Detail]

6-tert-Butyl-m-cresol(88-60-8)MS
6-tert-Butyl-m-cresol(88-60-8)1HNMR
6-tert-Butyl-m-cresol(88-60-8)13CNMR
6-tert-Butyl-m-cresol(88-60-8)IR1
6-tert-Butyl-m-cresol(88-60-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

6-tert-Butyl-m-cresol, 98%(88-60-8)
[Sigma Aldrich]

88-60-8(sigmaaldrich)
[TCI AMERICA]

6-tert-Butyl-m-cresol,>97.0%(GC)(88-60-8)
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