ChemicalBook--->CAS DataBase List--->89-86-1

89-86-1

89-86-1 Structure

89-86-1 Structure
IdentificationMore
[Name]

2,4-Dihydroxybenzoic acid
[CAS]

89-86-1
[Synonyms]

2 4-DIHYDROXYBENZENECARBOXYLIC ACID
2,4-DIHYDROXYBENZOIC ACID
3,4-DIHYDROXYBENZOIC ACID
4-HYDROXYSALICYLIC ACID
BETA-RESORCYCLIC
BETA-RESORCYCLIC ACID
BETA-RESORCYLIC ACID
B-RESORCYLIC ACID
RARECHEM AL BE 0221
RESORCINOL-4-CARBOXYLIC ACID
2,4-Dhba
2,4-dihydroxy-benzoicaci
4-Carboxyresorcinol
4-Hydroxysalicyicacid
Benzoic acid, 2,4-dihydroxy-
beta-Resorcinolic acid
beta-resorcinolicacid
BRA
Coupler 320
p-Hydroxysalicylic acid
[EINECS(EC#)]

201-946-9
[Molecular Formula]

C7H6O4
[MDL Number]

MFCD00002451
[Molecular Weight]

154.12
[MOL File]

89-86-1.mol
Chemical PropertiesBack Directory
[Appearance]

cream to slightly beige or pink crystalline powder
[Melting point ]

208-211 °C (dec.) (lit.)
[Boiling point ]

237.46°C (rough estimate)
[density ]

1.3725 (rough estimate)
[vapor pressure ]

0Pa at 25℃
[FEMA ]

3798
[refractive index ]

1.6710 (estimate)
[Fp ]

200 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

8g/l
[form ]

Crystalline Powder
[pka]

3.11, 8.55, 14.0(at 25℃)
[color ]

Cream to slightly beige or pink
[Odor]

at 100.00?%. mild phenolic
[biological source]

synthetic
[Water Solubility ]

8 g/L (20 ºC)
[JECFA Number]

908
[Merck ]

14,8157
[BRN ]

1946213
[Cosmetics Ingredients Functions]

SKIN CONDITIONING - EMOLLIENT
SKIN CONDITIONING - MISCELLANEOUS
[InChI]

1S/C7H6O4/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3,8-9H,(H,10,11)
[InChIKey]

UIAFKZKHHVMJGS-UHFFFAOYSA-N
[SMILES]

OC(=O)c1ccc(O)cc1O
[LogP]

0.98 at 23℃ and pH3.5
[CAS DataBase Reference]

89-86-1(CAS DataBase Reference)
[NIST Chemistry Reference]

2,4-Dihydroxybenzoic acid(89-86-1)
[EPA Substance Registry System]

89-86-1(EPA Substance)
Questions And AnswerBack Directory
[Uses]

2,4-Dihydroxybenzoic acid is a useful synthetic intermediate. An organic building block for plastics and rubber products.
[Toxicity]

GRAS (FEMA).
[Usage limits]

FEMA (mg/kg): cold drink: 450; Meat, dairy, processed vegetables, 100; fudge, gel, pudding, snack food, beverages, breakfast cereals, fats, cheeses, poultry products, fish, spices, sweet sauce, dairy products, meat soup, fruit ice Egg products, jams, jelly, rehydrated vegetables, 500; soup: 250; jelly sugar: 3333; instant coffee and tea: 12.5; sugar substitute: 12500; seasoning spices: 25000.
[Chemical properties]

It appears as white needle crystal. It will contain crystal water upon crystallization from the water. It appears as an anhydride at 100 ℃. Melting point 218-219 ° C (it has a melting point of 213 ° C upon thermal shock). Soluble in hot water, ethanol, ether. Cooking in water, acid or salt solution will remove carbon dioxide. It exhibits red color upon reaction with ferric chloride.
[Application]

  • The product has the chemical properties of both resorcinol and salicylic acid. It can be used in chemical reagents for colorimetric determination of iron, titanium and other elements; for organic synthesis, it is mainly used for dyes and pharmaceutical intermediates. 2, 4-dihydroxybenzoic acid is a major raw material during the production of acidic medicated pink 3BM, which consumes 157 kg per ton of dye (by 100%).
  • Used as a dye intermediate, medicine and reagents
  • Used as dyes, pharmaceuticals, pesticide intermediates
[Preparation]

It is derived from the hydroxylation of resorcinol.
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

1
[RTECS ]

VH3708050
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29182990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Skin Sens. 1
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium bicarbonate-->Resorcinol-->2,3-Dihydroxybenzoic acid-->2,5-Dihydroxybenzoic acid
[Preparation Products]

2,6-Dihydroxybenzoic acid-->4-Methoxysalicylic acid-->2,4-Dimethoxybenzoic acid-->Methyl 2,5-dihydroxybenzoate-->Methyl 2,4-dihydroxybenzoate-->3,6-Dihydroxyxanthone-->3,6-Dimethoxyxanthone-->Methyl 2,4-dimethoxybenzoate-->2,4,5-Trihydroxybenzoic acid-->2,4-Dihydroxybenzamide-->Mulberrin-->2-Bromo-5-methoxyphenol-->Protocatechuic acid-->Mordant Red 15
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

beta-Resorcylic acid(89-86-1).msds
Hazard InformationBack Directory
[Occurrence]

Reported present in avocados, beer, red wine, roast coffee, sherry, smoked sausage and white wine
[Purification Methods]

Crystallise the acid from water. [Beilstein 10 IV 1420.]
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-Dihydroxybenzoic acid(89-86-1)MS
2,4-Dihydroxybenzoic acid(89-86-1)1HNMR
2,4-Dihydroxybenzoic acid(89-86-1)IR1
2,4-Dihydroxybenzoic acid(89-86-1)IR2
2,4-Dihydroxybenzoic acid(89-86-1)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,4-Dihydroxybenzoic acid, 97%(89-86-1)
[Alfa Aesar]

2,4-Dihydroxybenzoic acid, 97%(89-86-1)
[Sigma Aldrich]

89-86-1(sigmaaldrich)
[TCI AMERICA]

2,4-Dihydroxybenzoic Acid,>98.0%(T)(89-86-1)
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