| Identification | More | [Name]
Chlorodiphenylmethane | [CAS]
90-99-3 | [Synonyms]
1,1'-(chloromethylene)bisbenzene
1,1-DIPHENYLCHLOROMETHANE
1,1-DIPHENYLMETHYL CHLORIDE
AKOS BBS-00004295
ALPHA-CHLORODIPHENYLMETHANE
BENZHYDRYL CHLORIDE
CHLORODIPHENYLMETHANE
DIPHENYLCHLOROMETHANE
DIPHENYLMETHYL CHLORIDE
[Chloro(phenyl)methyl]benzene
1,1’-(chloromethylene)bis-benzen
alpha-chloroditan
Benzene,1,1’-(chloromethylene)bis-
Methane, chlorodiphenyl-
Benzhydryl chloride, (Chlorodiphenylmethane
Benzhydrylchloride,98%
Benzenebis[1,1'-[chloromethylene]]
Benzhydryl chloride, Diphenylchloromethane | [EINECS(EC#)]
202-031-7 | [Molecular Formula]
C13H11Cl | [MDL Number]
MFCD00000855 | [Molecular Weight]
202.68 | [MOL File]
90-99-3.mol |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to yellow liquid | [Melting point ]
15-17 °C(lit.) | [Boiling point ]
140 °C3 mm Hg(lit.) | [density ]
1.14 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.595(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [solubility ]
Chloroform (Soluble), Methanol (Sparingly) | [form ]
Liquid | [color ]
Clear colorless to yellow | [Specific Gravity]
1.14 | [Water Solubility ]
slightly soluble | [BRN ]
607925 | [InChI]
1S/C13H11Cl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,13H | [InChIKey]
ZDVDCDLBOLSVGM-UHFFFAOYSA-N | [SMILES]
ClC(c1ccccc1)c2ccccc2 | [CAS DataBase Reference]
90-99-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1,1'-(chloromethylene)bis-(90-99-3) | [EPA Substance Registry System]
90-99-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29036990 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B | [Hazardous Substances Data]
90-99-3(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to yellow liquid | [Uses]
Chlorodiphenylmethane was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives. | [Uses]
Chlorodiphenylmethane was used as initiator during the controlled radical polymerization of styrene catalyzed by ionic iron complex. It was also used as the starting reagent in the synthesis of trimethylhydroquinone derivatives. | [Application]
Benzhydryl chloride is used as a pharmaceutical intermediate, such as diphenhydramine intermediate. | [Preparation]
Chlorodiphenylmethane was synthesized by the radical substitution reaction between diphenylmethane and chlorine gas. | [Purification Methods]
Diphenylmethyl chloride (benzhydryl chloride) [90-99-3] M 202.7, m 17.0o, b 140o/3mm, 1 6 7o/17mm, n 1.5960. Dry the chloride with Na2SO4 and fractionally distil it under reduced pressure. [Beilstein 5 H 590, 5 I 278, 5 II 500, 5 III 1790, 5 IV 1847.] |
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