| Identification | More | [Name]
2-Fluorotoluene | [CAS]
95-52-3 | [Synonyms]
2-FLUOROTOLUENE
O-FLUOROTOLUENE
1-Fluor-2-methylbenzol
1-fluoro-2-methyl-benzen
1-Fluoro-2-methylbenzene
1-fluoro-2-methyl-benzene
1-Methyl-2-fluorobenzene
2-fluoromethylbenzene
Benzene,1-fluoro-2-methyl-
benzene,2-fluoro-1-methyl-
o-fluoro-toluen
o-Fluortoluol
ortho-Fluorotoluene
Toluene, o-fluoro-
Toluene,o-fluoro-
o-Fluorotoluene 2-Fluorotoluene
2-FLUOROTOLUENE, 99+%
o-Flouorotoluene
o-Fluorotoluene,99%
2-Fluorotoluene 99% | [EINECS(EC#)]
202-428-5 | [Molecular Formula]
C7H7F | [MDL Number]
MFCD00000322 | [Molecular Weight]
110.13 | [MOL File]
95-52-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to slightly yellow liquid | [Melting point ]
-62 °C (lit.) | [Boiling point ]
113-114 °C (lit.) | [density ]
1.001 g/mL at 25 °C(lit.)
| [vapor density ]
3.8 (vs air)
| [vapor pressure ]
21 mm Hg ( 20 °C)
| [refractive index ]
n20/D 1.473(lit.)
| [Fp ]
55 °F
| [storage temp. ]
Flammables area | [form ]
Liquid | [color ]
Clear colorless to slightly yellow | [Specific Gravity]
1.001 | [explosive limit]
1.3%(V) | [Water Solubility ]
immiscible | [Merck ]
14,4180 | [BRN ]
1853362 | [Dielectric constant]
4.2199999999999998 | [LogP]
2.73-2.74 | [CAS DataBase Reference]
95-52-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1-fluoro-2-methyl-(95-52-3) | [EPA Substance Registry System]
95-52-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S33:Take precautionary measures against static discharges .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 2388 3/PG 2
| [WGK Germany ]
3
| [RTECS ]
XT2579000
| [Hazard Note ]
Flammable/Irritant | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29036990 | [Toxicity]
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 2000 mg/kg |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with an aromatic odor. May sink or float on water. | [Reactivity Profile]
2-FLUOROTOLUENE(95-52-3) is of generally low reactivity. Reacts with strong oxidizing agents and strong reducing agents. Also may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides [USCG, 1999]. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Health Hazard]
Inhalation of vapor may cause respiratory irritation. Prolonged and repeated vapor exposures may produce systemic toxic effects. | [Chemical Properties]
clear colorless to slightly yellow liquid | [Uses]
It is employed in organic synthesis. | [Synthesis]
The halogen exchange method reacts aromatic compounds with alkali metal fluorides (e.g., CsF and KF, etc.) and substituent groups, allowing the fluorine atom to replace other halogen groups (e.g., chlorine). The reaction method of halogen exchange between | [Purification Methods]
Dry o-fluorotoluene with P2O5 or CaSO4 and fractionally distil it through a silvered vacuum-jacketed glass column with 1/8th-in glass helices. A high reflux ratio is necessary because of the closeness of the boiling points of the o-, m-and p-isomers [Potter & Saylor J Am Chem Soc 37 90 1951]. [Beilstein 5 H 290, 5 III 676, 5 IV 799.] |
|
|