| Identification | More | [Name]
Benoxacor | [CAS]
98730-04-2 | [Synonyms]
2-PHENYL-4,6-DICHLORO PYRIMIDINE
4,6-DICHLORO-2-PHENYLPYRIMIDINE
BENOXACOR
FENCLORIM
SOFIT
(+-)-2,2-dichloro-1-(3,4-dihydro-3-methyl-2h-1,4-benzoxazin-4-yl)ethanone
(+-)-4-(dichloroacetyl)-3,4-dihydro-3-methyl-2h-1,4-benzoxazine
4-dihydro-3-methyl-4-benzoxazin(+-)-2h-4-(dichloroacetyl)-3
(±)2,2-dichloro-1-(3,4-dichloro-3-methyl-2H-1，4-bensoxazin-4-yl)ethanone
primextras
BENOXACOR PESTANAL, 250 MG
BENOXACOR, 96%TC
(RS)-4-Dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine
benoxacor (bsi, draft e-iso)
BENOXACOR STANDARD
4-(Dichloroacetyl)-3-methyl-3,4-dihydro-2H-1,4-benzoxazine
CGA-154281 | [EINECS(EC#)]
619-372-6 | [Molecular Formula]
C10H6Cl2N2 | [MDL Number]
MFCD00754193 | [Molecular Weight]
225.07 | [MOL File]
98730-04-2.mol |
| Chemical Properties | Back Directory | [Melting point ]
105-107° | [Boiling point ]
240°C (rough estimate) | [density ]
1.3416 (rough estimate) | [vapor pressure ]
0.002Pa at 25℃ | [refractive index ]
1.6070 (estimate) | [Fp ]
>107 °C | [storage temp. ]
0-6°C | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | [form ]
neat | [pka]
1.20±0.40(Predicted) | [color ]
Pale Brown to Light Brown | [Water Solubility ]
38mg/L at 25℃ | [BRN ]
4190275 | [Henry's Law Constant]
1.3×102 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) | [Major Application]
agriculture
environmental | [InChI]
1S/C11H11Cl2NO2/c1-7-6-16-9-5-3-2-4-8(9)14(7)11(15)10(12)13/h2-5,7,10H,6H2,1H3 | [InChIKey]
PFJJMJDEVDLPNE-UHFFFAOYSA-N | [SMILES]
CC1COc2ccccc2N1C(=O)C(Cl)Cl | [LogP]
2.6 at 25℃ | [CAS DataBase Reference]
98730-04-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Benoxacor(98730-04-2) | [EPA Substance Registry System]
98730-04-2(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS09 | [Signal word ]
Warning | [Hazard statements ]
H317-H410 | [Precautionary statements ]
P261-P272-P273-P280-P302+P352-P333+P313 | [WGK Germany ]
2 | [RTECS ]
DM3029000 | [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HS Code ]
29349990 | [Storage Class]
13 - Non Combustible Solids | [Hazard Classifications]
Aquatic Chronic 1
Skin Sens. 1 | [Toxicity]
LD50 (mg/kg): >5000 orally in rats; >2010 dermally in rabbits; LC50 in rats (mg/l): >2000 by inhalation (Fed. Regist.) |
| Hazard Information | Back Directory | [Uses]
Herbicide safener. | [Definition]
ChEBI: Benoxacor is a benzoxazine. | [Flammability and Explosibility]
Nonflammable | [Synthesis]
The commercial production of benoxacor involves a multi-step synthetic process. A common
method for its synthesis is detailed in U.S. Patent 6,977,299 B2. The process involves the
synthesis of an o-nitrophenoxyketone, followed by hydrogenation to form a benzoxazine, which
is then acylated to yield benoxacor. | [Metabolic pathway]
In cell suspension cultures of corn (Zea mays) with
14C-benoxacor, benoxacor is rapidly metabolized to six
detectable metabolites within 0.5 h. Twelve
metabolites are detected in extracts from the treated
cells for 24 h. Of the three predominant metabolites
present, two metabolites are the catabolic
formylcarboxamide and carboxycarboxamide
derivatives of benoxacor. The third one is the mono
glutathione conjugate of benoxacor. This metabolite
consists of a single glutathione molecule linked via the
cysteinyl sulfhydryl group to the N-dichloroacetyl a-
carbon of benoxacor. A catabolic a-hydroxyacetamide
derivative is detected as well as its amino acid conjugates either containing glutathione residue or
presumably derived from the glutathione residue.
A disaccharide conjugate is identified as
S-(O-diglycoside)glutathione conjugate. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
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