Tricyclo[3.3.1.13,7]decan-1-carbonsure
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- CAS-Nr.
- 828-51-3
- Bezeichnung:
- Tricyclo[3.3.1.13,7]decan-1-carbonsure
- Englisch Name:
- 1-Adamantanecarboxylic acid
- Synonyma:
- ADAMANTANE-1-CARBOXYLIC ACID;1-Adamantyl Carboxylic Acid;Adamantoic acid;1-AdamantanecarboxyL;adamantanecarboxylic acid;1-Adamantanecarboxylic;Adamantane-1-carboxylic acid 99%;Saxaint-K;AKOS BC-0655;1-ADAMANTOIC ACID
- CBNumber:
- CB3145173
- Summenformel:
- C11H16O2
- Molgewicht:
- 180.24
- MOL-Datei:
- 828-51-3.mol
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Tricyclo[3.3.1.13,7]decan-1-carbonsure Eigenschaften
- Schmelzpunkt:
- 172-174 °C (lit.)
- Siedepunkt:
- 253.08°C (rough estimate)
- Dichte
- 0.9976 (rough estimate)
- Brechungsindex
- 1.4910 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- Löslichkeit
- Chloroform, Methanol (Slightly)
- Aggregatzustand
- Crystalline Powder
- pka
- 4.86±0.20(Predicted)
- Farbe
- White to off-white
- Wasserlöslichkeit
- Insoluble in water. Solubility in methanol gives very faint turbidity. Soluble in ethanol, chloroform, and dichloromethane.
- BRN
- 1910637
- InChI
- InChI=1S/C11H16O2/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2,(H,12,13)
- InChIKey
- JIMXXGFJRDUSRO-UHFFFAOYSA-N
- SMILES
- C12(C(O)=O)CC3CC(CC(C3)C1)C2
- CAS Datenbank
- 828-51-3(CAS DataBase Reference)
- NIST chemische Informationen
- Adamantane-1-carboxylic acid(828-51-3)
Tricyclo[3.3.1.13,7]decan-1-carbonsure Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
white to off-white crystalline powder
Verwenden
1-Adamantanecarboxylic acid can be used as:
- A stabilizer in the synthesis of monodisperse, highly crystalline CoPt3?nanoparticles and porous platinum nanoparticles.
- An additive in polycondensation reactions to yield conjugated polymers as possible optoelectronic materials.
- An additive in the allylic substitution reaction, which is catalyzed by palladium in an aqueous medium.
läuterung methode
Possible impurities are trimethylacetic acid and C9 and C13 acids. Dissolve 15g of the acid in CCl4 (300mL) and shake with 110mL of 15N aqueous NH3 whereby the ammonium salt separates and is collected. Acid impurities form soluble ammonium salts. The salt is washed with cold Me2CO (20mL) and suspended in H2O (250mL). This is treated with 12N HCl and extracted with CHCl3 (100mL). The dried (Na2SO4) extract was evaporated and the residue was recrystallised from a mixture of MeOH (30mL) and H2O (ca 10mL) to give the pure acid (10-11g). [Koch & Haaf Org Synth Coll Vol V 20 1973.] It was also recrystallised from absolute EtOH and dried under vacuum at 100o. Alternatively, the acid (5g) is refluxed for 2hours with 15mL of MeOH and 2mL of 98% H2SO4 (cool when mixing this solution). Pour into 10 volumes of H2O and extract with the minimum volume of CHCl3 to give clear separation of phases. The extract is washed with H2O, dried (CaCl2) and distilled. The methyl ester is collected at 77-79o/1mm, m 38-39o. The ester is hydrolysed with the calculated amount of N KOH and refluxed until clear. Acidification with HCl provides the pure acid with 90% recovery. The amide crystallises from cyclohexane, m 189o. [Stetter et al. Chem Ber 92 1629 1959.] [Beilstein 9 IV 253.]
Tricyclo[3.3.1.13,7]decan-1-carbonsure Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Tricyclo[3.3.1.13,7]decan-1-carbonsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 488)Lieferanten
828-51-3(Tricyclo[3.3.1.13,7]decan-1-carbonsure)Verwandte Suche:
- 1-ADMANTANE CARBOXYLIC ACID
- 1-Adamantane-1-carboxylic acid
- 1-Adamantanecarboxylic acid ,99%
- 3-adamantanecarboxylicacid
- ricyclo[3.3.1.13,7]decane-1-carboxylic acid
- Tricyclo[3.3.1.13,7]-decane-1-carboxylic acid
- Tricyclo[3,3,1,1]3,7 decanecarbonoic acid
- 1-Adamantan Carboxylic Acid
- 1-adamantylmethanoic acid
- Adamantane-3-carboxylic acid
- 1-Adamantanecarboxylic acid 5g [828-51-3]
- 1-AdaMantanecarboxylic acid, 99% 5GR
- 1-ADAMANTANECARBOXYLIC ACID FOR SYNTHESI
- 1-Carboxyadamantane, Tricyclo[3.3.1.1~3,7~]decane-1-carboxylic acid
- 1-Adamantanecarboxylic acid 99%
- (1s,3s)-adamantane-1-carboxylic acid
- 1-AdaMantanecarboxylic Acid, 97+%
- AKOS BC-0655
- RARECHEM AQ TC 1001
- OTAVA-BB BB0111370036
- TRICYCLO[3.3.1.1(3,7)]DECANE-1-CARBOXYLIC ACID
- TRICYCLO[3.3.1.1]DECANE-1-CARBOXYLIC ACID
- Tricyclo[3.3.1.1(3,7)]decan-1-Carboxylic acid
- 1-ADAMANTANECARBOXYLIC ACID
- 1-ADAMANTOIC ACID
- 1-Carboxyadamantane
- 3-Adamantanecarboxylic acid
- LABOTEST-BB LT00436929
- Saxaint-K
- 1-adamantanecarboxylate
- 1-Adamantanecarboxylic acid, 99%, for synthesis
- 1-AdamantanecarboxylicAcid>
- 1-Adamantanecarboxylic
- Adamantane-1-carboxylic acid 99%
- adamantanecarboxylic acid
- Adamantoic acid
- 1-Adamantyl Carboxylic Acid
- ADAMANTANE-1-CARBOXYLIC ACID
- 1-AdamantanecarboxyL
- 1-Adamantanecarboxylic acid (6CI, 7CI, 8CI)
- 8-allyl-8-hydroxytricyclo decane
- 828-51-3
- C11H16O2
- C11H15O2
- Organic Building Blocks
- C11 to C12
- Carboxylic Acids
- Carbonyl Compounds
- Building Blocks
- Adamantanes
- C11 to C12
- Carbonyl Compounds
- Carboxylic Acids
- Organic acids
- Adamantanes
