Triphenylsilyl chloride
- CAS No.
- 76-86-8
- Chemical Name:
- Triphenylsilyl chloride
- Synonyms
- Chlorotriphenylsilane;P3;TRIPHENYLCHLOROSILANE;TPCS;TRIPHENLCHLOROSILANE;Triphenylchlorsoilane;chlorotriphenyl-silan;TRIPHENYLSILYL CHLORIDE;silane,chlorotriphenyl-;triphenylchlorosilicane
- CBNumber:
- CB0191735
- Molecular Formula:
- C18H15ClSi
- Molecular Weight:
- 294.85
- MDL Number:
- MFCD00000496
- MOL File:
- 76-86-8.mol
- MSDS File:
- SDS
| Melting point | 91-94 °C(lit.) |
|---|---|
| Boiling point | 378 °C |
| Density | 1.14 |
| Flash point | >200°C |
| storage temp. | Refrigerator |
| solubility | acetone: 0.1 g/mL, clear |
| form | crystal |
| Specific Gravity | 1.16 |
| color | white |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 1820487 |
| InChIKey | MNKYQPOFRKPUAE-UHFFFAOYSA-N |
| CAS DataBase Reference | 76-86-8(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| NIST Chemistry Reference | Triphenylchlorosilane(76-86-8) |
| EPA Substance Registry System | Silane, chlorotriphenyl- (76-86-8) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34-37 | |||||||||
| Safety Statements | 26-36/37/39-45-24/25 | |||||||||
| RIDADR | UN 3261 8/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | VV2720000 | |||||||||
| F | 10-21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29310095 | |||||||||
| NFPA 704 |
|
Triphenylsilyl chloride price More Price(17)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 114162 | Chlorotriphenylsilane 96% | 76-86-8 | 5g | $47.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 114162 | Chlorotriphenylsilane 96% | 76-86-8 | 25g | $108 | 2024-03-01 | Buy |
| TCI Chemical | T0939 | Triphenylchlorosilane >95.0%(GC) | 76-86-8 | 5g | $25 | 2024-03-01 | Buy |
| TCI Chemical | T0939 | Triphenylchlorosilane >95.0%(GC) | 76-86-8 | 25g | $92 | 2024-03-01 | Buy |
| Alfa Aesar | A13678 | Chlorotriphenylsilane, 96% | 76-86-8 | 5g | $22.65 | 2024-03-01 | Buy |
Triphenylsilyl chloride Chemical Properties,Uses,Production
?Acute toxicity
IV- mouse LD50: 56 mg/kg
Description
Triphenylsilyl chloride is a white to off-white crystal or powder with acrid ordor of hydrogen chloride, used for synthesis of pharmaceutical intermediates.
Physical properties
mp 92–94°C; bp 240–243°C/35 mmHg.
Uses
A wide variety of Grignard reagents and organolithium complexes
participate in reactions with Ph3SiCl to afford organosilanes.
Thus the reaction of allylmagnesium chloride with Ph3SiCl gives the allylsilane in high yield (eq 3).However, when hydrosilyl
Grignard reagents are employed, reduction to the silane
occurs (eq 4).Azaallyl anion6 and diazolithium salts can each
be silylated to give the anticipated silane adducts (eqs 5 and 6).
Similarly, arylsilanes8 and alkynylsilanes are produced upon
silylation of the appropriate metalated13 carbanions with Ph3SiCl
(eqs 7–11).
Uses
Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.
Purification Methods
Likely impurities are tetraphenylsilane, small amounts of hexaphenyldisiloxane and traces of triphenylsilanol. Purify it by distillation at 2mm, then crystallise it from EtOH-free CHCl3, and from pet ether (b 30-60o) or hexane by cooling in a Dry-ice/acetone bath. [Allen & Modena J Chem Soc 3671 1957, Curran et al. J Am Chem Soc 72 4471 1950, Speier & Zimmerman J Am Chem Soc 77 6395 1955, Thomas & Rochow J Am Chem Soc 79 1843 1957, Beilstein 16 IV 1484.]
Triphenylsilyl chloride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15371 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
View Lastest Price from Triphenylsilyl chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-07-01 | Triphenylsilyl chloride
76-86-8
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2022-07-26 | Triphenylchlorosilane
76-86-8
|
US $9.32-8.04 / kg | 200kg | 98.41% | 8000 tons per year | Iota silicone oil (Anhui) Co.,ltd. | |
 |
2021-09-25 | Triphenylsilyl chloride
76-86-8
|
US $9.90 / KG | 1KG | 99% | 10 mt | Hebei Guanlang Biotechnology Co., Ltd. |
-
- Triphenylsilyl chloride
76-86-8
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- Triphenylchlorosilane
76-86-8
- US $9.32-8.04 / kg
- 98.41%
- Iota silicone oil (Anhui) Co.,ltd.
-
- Triphenylsilyl chloride
76-86-8
- US $9.90 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.