TRIS(PENTAFLUOROPHENYL)BORANE
- CAS No.
- 1109-15-5
- Chemical Name:
- TRIS(PENTAFLUOROPHENYL)BORANE
- Synonyms
- Tris(Pentafluorophenyl)Borate;TRIS(PENTAFLUOROPHENYL)BORON;Tris(pentafL;Perfluorotriphenylboron;perfluorotriphenylborone;PERFLUOROTRIPHENYLBORANE;TRIS(PENTAFLUOROPHENYL)BORANE;Tri (pentafluorobenzene) borane;Tris(pentafluorophenyl)borane,95%;Tris(pentafluorophenyl)borane 95%
- CBNumber:
- CB1113297
- Molecular Formula:
- C18BF15
- Molecular Weight:
- 511.98
- MDL Number:
- MFCD00269813
- MOL File:
- 1109-15-5.mol
- MSDS File:
- SDS
Melting point | 126-131 °C (lit.) |
---|---|
Boiling point | 327.3±42.0 °C(Predicted) |
Density | 0.73 g/mL at 20 °C |
refractive index |
n |
Flash point | 7 °C |
storage temp. | Inert atmosphere,Store in freezer, under -20°C |
solubility | Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents. |
form | Powder |
color | White to light yellow-beige |
Specific Gravity | 1.7 |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
λmax | 306nm(Toluene)(lit.) |
Sensitive | Moisture Sensitive |
Merck | 14,9755 |
BRN | 2931347 |
InChIKey | OBAJXDYVZBHCGT-UHFFFAOYSA-N |
CAS DataBase Reference | 1109-15-5(CAS DataBase Reference) |
FDA UNII | I3WU5E2578 |
EPA Substance Registry System | Borane, tris(2,3,4,5,6-pentafluorophenyl)- (1109-15-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi,T,N,Xn,F | |||||||||
Risk Statements | 36/37/38-25-67-65-50/53-38-11 | |||||||||
Safety Statements | 60-61-62-45-37/39-26-36 | |||||||||
RIDADR | UN 1268 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29039990 | |||||||||
NFPA 704 |
|
TRIS(PENTAFLUOROPHENYL)BORANE price More Price(37)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 442593 | Tris(pentafluorophenyl)borane 95% | 1109-15-5 | 1g | $209 | 2024-03-01 | Buy |
Sigma-Aldrich | 442593 | Tris(pentafluorophenyl)borane 95% | 1109-15-5 | 5G | $620 | 2024-03-01 | Buy |
Sigma-Aldrich | 442593 | Tris(pentafluorophenyl)borane 95% | 1109-15-5 | 100G | $5420 | 2024-03-01 | Buy |
TCI Chemical | T2313 | Tris(pentafluorophenyl)borane >98.0%(NMR) | 1109-15-5 | 1g | $114 | 2024-03-01 | Buy |
TCI Chemical | T2313 | Tris(pentafluorophenyl)borane >98.0%(NMR) | 1109-15-5 | 5g | $396 | 2024-03-01 | Buy |
TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties,Uses,Production
Uses
Tris(pentafluorophenyl)borane (CAS# 1109-15-5) is a useful research chemical, used as a catalyst in the metal-free catalytic reductive cleavage of enol ethers via proposed mechanism of tandem hydrosilylation and silicon-assisted β-elimination. Tris(pentafluorophenyl)borane also appears as an ancillary ligand in luminescent isocyano Rh(I) complexes.
Chemical Properties
white powder
Uses
Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.
Uses
Catalyst in organic transformations; cocatalyst with group IV metallocene alkyls in olefin polymerization.
General Description
B(C6F5)3 is a Lewis acid, stronger than the inorganic parent molecule BF3. In contrast to the prominent Lewis acids, the pentafluorides of the heavier elements of group 15, B(C6F5)3 has no oxidizing properties. B(C6F5)3 forms adducts with neutral and weaker Lewis bases. B(C6F5)3 has the capability to easily accept anionic ligands bonded to metals.
TRIS(PENTAFLUOROPHENYL)BORANE Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | +86-29-81148696 +86-15536356810 | 1022@dideu.com | China | 3878 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9308 | 55 |
Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10311 | 58 |
Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd. | 0431-80514535 13634302652 | Extension@chemextension.com | CHINA | 967 | 58 |
HaBo Hong Kong Co., Limited. | +86-25-18512596065 | info@habotech.com | CHINA | 933 | 58 |
View Lastest Price from TRIS(PENTAFLUOROPHENYL)BORANE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-07-14 | TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
|
US $0.10 / KG | 1KG | 98.0% | 10 | Shaanxi Dideu Medichem Co. Ltd | ||
2022-10-10 | TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
2022-03-21 | Tris(perfluorophenyl)borane
1109-15-5
|
US $11.60 / KG | 1KG | 99% | 100KG | Hong Kong Tiansheng New Material Trading Co., Ltd |
- TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
- US $0.10 / KG
- 98.0%
- Shaanxi Dideu Medichem Co. Ltd
- TRIS(PENTAFLUOROPHENYL)BORANE
1109-15-5
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- Tris(perfluorophenyl)borane
1109-15-5
- US $11.60 / KG
- 99%
- Hong Kong Tiansheng New Material Trading Co., Ltd
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