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Palladium (II) Acetate

Reactions
Palladium (II) Acetate
Palladium (II) Acetate structure
CAS No.
3375-31-3
Chemical Name:
Palladium (II) Acetate
Synonyms
pd(oac)2;[Pd(CH3COO)2]3;PaladiumAcetate;palladousacetate;palladiym acetate;PALLADIUM ACETATE;bisacetylpalladium;alladium diacetate;diacetatopalladium;diacetoxypalladium
CBNumber:
CB1187458
Molecular Formula:
C4H6O4Pd
Formula Weight:
224.51
MOL File:
3375-31-3.mol

Palladium (II) Acetate Properties

Melting point:
205 °C
storage temp. 
Store at R.T.
solubility 
Soluble as monomer in glacial acetic acid or as trimer in benzene.
form 
Various Forms In Red-(Powder/Flake/Crystalline/Beads)
color 
Red-brown
PH
2-3 (H2O, 20℃)(aqueous suspension)
Water Solubility 
insoluble
Sensitive 
Hygroscopic
λmax
400nm(EtOH)(lit.)
Merck 
14,6991
BRN 
6086766
InChIKey
PCUVQHHZCJMCHO-UHFFFAOYSA-M
CAS DataBase Reference
3375-31-3(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, palladium(2+) salt(3375-31-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,Xn,C
Risk Statements  41-36/37/38-40-35
Safety Statements  26-39-36/37/39-45-36
RIDADR  3261
WGK Germany  2
RTECS  AJ1900000
10-23
TSCA  Yes
HS Code  28439090
Toxicity LD50 orally in Rabbit: >= 5110 mg/kg
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H413 May cause long lasting harmful effects to aquatic life Hazardous to the aquatic environment, long-term hazard Category 4
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P310 Immediately call a POISON CENTER or doctor/physician.
P321 Specific treatment (see … on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Palladium (II) Acetate price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 205869 Palladium(II) acetate reagent grade, 98% 3375-31-3 1g $85.5 2018-11-13 Buy
Sigma-Aldrich 205869 Palladium(II) acetate reagent grade, 98% 3375-31-3 2g $125 2018-11-13 Buy
TCI Chemical A1424 Palladium(II) Acetate >98.0%(T) 3375-31-3 1g $102 2018-11-22 Buy
TCI Chemical A1424 Palladium(II) Acetate >98.0%(T) 3375-31-3 5g $338 2018-11-22 Buy
Alfa Aesar 010516 Palladium(II) acetate, Pd 45.9-48.4% 3375-31-3 5g $274 2018-11-16 Buy

Palladium (II) Acetate Chemical Properties,Uses,Production

Reactions

  1. Efficient catalyst for the arylation of olefins (Heck reaction).
  2. Catalyst for cross-coupling reactions.
  3. Catalyst for C-H activation.
  4. Precatalyst for enantioselective decarboxylative protonation of allyl β-ketoesters. 

Chemical Properties

brown needles

Uses

suzuki reaction

Uses

Palladium (II) Acetate Trimer is used in Suzuki-Miyaura cross-coupling reactions. It also serves to catalyze the chemoselective reduction of nitroarenes.

Uses

A catalyst for intramolecular coupling.

Purification Methods

It recrystallises from CHCl3 as purple crystals. It can be washed with AcOH and H2O and dried in air. Large crystals are obtained by dissolving it in *C6H6, adding half its volume of AcOH and allowing it to evaporate slowly at room temperature. It forms green adducts with nitrogen donors, it dissolves in KI solution to form solid PdI2 and a red solution of PdI42-, but is insoluble in aqueous saturated NaCl, and NaOAc. It dissolves in HCl to form PdCl42-. It is soluble in CHCl3, CH2Cl2, Me2CO, MeCN, Et2O, but it is insoluble in H2O, and decomposes when warmed in alcohols in which it is also insoluble. [Morehouse et al. Chem Ind (London) 544 1964, Stephenson et al. J Chem Soc 3632 1965, Skapski & Smart J Chem Soc (D) 658 1970, Heck Acc Chem Res 12 146 1979.]

Palladium (II) Acetate Preparation Products And Raw materials

Raw materials

Preparation Products


Palladium (II) Acetate Suppliers

Global( 368)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
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View Lastest Price from Palladium (II) Acetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-04-08 Palladium (II) Acetate
3375-31-3
US $100.00 / kg 100g 99.8% 20tons Hebei Jimi Trading Co., Ltd.
2018-07-23 Palladium (II) Acetate
3375-31-3
US $20.00 / KG 2KG 97% 5tons career henan chemical co

Palladium (II) Acetate Spectrum


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