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Palladium (II) Acetate

Palladium (II) Acetate Suppliers list
Company Name: Wuhan Pengo Technology.,Ltd.
Tel: +86-27-81330736 +86-13628634921
Email: sunny.w@boronicgroup.com
Products Intro: Product Name:Palladium diacetate
CAS:3375-31-3
Purity:99%,Pd>47.4% Package:5g,50g,100g,250g,500g,1kg,5kg
Company Name: Shanghai Bosheng Metal Materials Co. LTD
Tel: 18601346310;021-33360721
Email:
Products Intro: Product Name:Palladium acetate
CAS:3375-31-3
Purity:0.99 Package:10g;50g;500g;1000g
Company Name: SINOPRO.CO.LTD
Tel: 0082-42-721-7177
Email: michael@sinopro.co.kr
Products Intro: Product Name:Palladium(II) Acetate
CAS:3375-31-3
Purity:99%, 99.9% Package:1kg, 20kg, 100kg, 1MT
Company Name: Springchem New Material Technology Co.,Limited
Tel: +86-021-62885108
Email: info@spring-chem.com
Products Intro: Product Name:Palladium diacetate
CAS:3375-31-3
Purity:99%,99.5% Package:1kg,10kg,25kg
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-66670886
Email: info@dakenchem.com
Products Intro: Product Name:Palladium diacetate
CAS:3375-31-3
Purity:99% Package:100g,500g,1KG,10KG,100KG

Lastest Price from Palladium (II) Acetate manufacturers

  • Chloroauric acid
  • US $5.00 / Kg/Bag
  • 2021-09-07
  • CAS:3375-31-3
  • Min. Order: 1g
  • Purity: 99%
  • Supply Ability: 50tons per month
  • Palladium diacetate
  • US $15.00-10.00 / KG
  • 2021-08-12
  • CAS:3375-31-3
  • Min. Order: 1KG
  • Purity: 99%+ HPLC
  • Supply Ability: Monthly supply of 1 ton

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  • What is Palladium (II) Acetate?
  • Palladium(II) acetate is a chemical compound of palladium described by the formula [Pd(O2CCH3)2]n, abbreviated [Pd(OAc)2]n. It....
  • Apr 22,2021
  • Pd(OAc)2/Xantphos Catalyst System
  • A recent report by Eastgate and Blackmond on a Pd/Xantphos-catalyzed C?H arylation reaction suggested that under their reactio....
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Palladium (II) Acetate Chemical Properties
Melting point 205 °C
storage temp. Store below +30°C.
solubility Soluble as monomer in glacial acetic acid or as trimer in benzene.
form Various Forms In Red-(Powder/Flake/Crystalline/Beads)
color Red-brown
PH2-3 (H2O, 20℃)(aqueous suspension)
PH Range2.0 - 3.0 at 20 °C
Water Solubility insoluble
Sensitive Hygroscopic
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
λmax400nm(EtOH)(lit.)
Merck 14,6991
BRN 6086766
InChIKeyPCUVQHHZCJMCHO-UHFFFAOYSA-M
CAS DataBase Reference3375-31-3(CAS DataBase Reference)
EPA Substance Registry SystemAcetic acid, palladium(2+) salt (3375-31-3)
Safety Information
Hazard Codes Xi,Xn,C
Risk Statements 41-36/37/38-40-35
Safety Statements 26-39-36/37/39-45-36
RIDADR 3261
WGK Germany 2
RTECS AJ1900000
10-23
TSCA Yes
HS Code 28439090
ToxicityLD50 orally in Rabbit: >= 5110 mg/kg
MSDS Information
ProviderLanguage
Palladium diacetate English
SigmaAldrich English
ACROS English
ALFA English
Palladium (II) Acetate Usage And Synthesis
Reactions
  1. Efficient catalyst for the arylation of olefins (Heck reaction).
  2. Catalyst for cross-coupling reactions.
  3. Catalyst for C-H activation.
  4. Precatalyst for enantioselective decarboxylative protonation of allyl β-ketoesters. 
Chemical Propertiesbrown needles
Usessuzuki reaction
UsesPalladium (II) Acetate Trimer is used in Suzuki-Miyaura cross-coupling reactions. It also serves to catalyze the chemoselective reduction of nitroarenes.
UsesA catalyst for intramolecular coupling.
Safety ProfileModerately toxic by ingestion. When heated to decomposition it emits toxic vapors of palladium.
Purification MethodsIt recrystallises from CHCl3 as purple crystals. It can be washed with AcOH and H2O and dried in air. Large crystals are obtained by dissolving it in *C6H6, adding half its volume of AcOH and allowing it to evaporate slowly at room temperature. It forms green adducts with nitrogen donors, it dissolves in KI solution to form solid PdI2 and a red solution of PdI42-, but is insoluble in aqueous saturated NaCl, and NaOAc. It dissolves in HCl to form PdCl42-. It is soluble in CHCl3, CH2Cl2, Me2CO, MeCN, Et2O, but it is insoluble in H2O, and decomposes when warmed in alcohols in which it is also insoluble. [Morehouse et al. Chem Ind (London) 544 1964, Stephenson et al. J Chem Soc 3632 1965, Skapski & Smart J Chem Soc (D) 658 1970, Heck Acc Chem Res 12 146 1979.]
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