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4-(Methylthio)phenylboronic acid

4-(Methylthio)phenylboronic acid
4-(Methylthio)phenylboronic acid structure
CAS No.
98546-51-1
Chemical Name:
4-(Methylthio)phenylboronic acid
Synonyms
AKOS BRN-0127;RARECHEM AH PB 0130;4-BORONOTHIOANISOLE;4-(Methylthio)phenyl;4-THIOANISOLEBORONIC ACID;THIOANISOLE-4-BORONIC ACID;4-Methylthiopenylboronic Acid;4-THIOMETHYLPHENYLBORONIC ACID;4-(METHYLTHIO)PHENYLBORONIC ACID;P-(METHYLTHIO)PHENYLBORONIC ACID
CBNumber:
CB1483149
Molecular Formula:
C7H9BO2S
Formula Weight:
168.02
MOL File:
98546-51-1.mol

4-(Methylthio)phenylboronic acid Properties

Melting point:
210-214 °C(lit.)
storage temp. 
0-6°C
form 
Crystalline Powder
color 
Off-white
BRN 
3247219
CAS DataBase Reference
98546-51-1(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  37/39-26-36-7/9
WGK Germany  3
Hazard Note  Irritant
HazardClass  IRRITANT
HS Code  29163990
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

4-(Methylthio)phenylboronic acid price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 456802 4-(Methylthio)phenylboronic acid ≥95% 98546-51-1 1g $24.8 2018-11-13 Buy
Sigma-Aldrich 456802 4-(Methylthio)phenylboronic acid ≥95% 98546-51-1 5g $83.8 2018-11-13 Buy
TCI Chemical M1458 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) 98546-51-1 1g $32 2018-11-22 Buy
TCI Chemical M1458 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) 98546-51-1 5g $96 2018-11-22 Buy
Alfa Aesar B23454 4-(Methylthio)benzeneboronic acid, 97% 98546-51-1 5g $79.4 2018-11-13 Buy

4-(Methylthio)phenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

Off-white crystalline powder

Uses

Reactant involved in:• ;Suzuki-Miyaura cross coupling reactions1 with 2-aryl-1-bromo-1-nitroethenes2 or alkynyl bromides3• ;Addition reactions with naphthyridine N-oxides4• ;Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives5• ;Sulfoxidation reactions6• ;Copper-catalyzed halogenation7

Uses

suzuki reaction

4-(Methylthio)phenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products


4-(Methylthio)phenylboronic acid Suppliers

Global( 237)Suppliers
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