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Stannic chloride pentahydrate

Physical Properties Uses Preparation
Stannic chloride pentahydrate
Stannic chloride pentahydrate structure
CAS No.
10026-06-9
Chemical Name:
Stannic chloride pentahydrate
Synonyms
Olovo Stanic;Stannic chloride hyd;TIN(IV) CHLORIDE 5H2O;STANNIC CHLORIDE 5H2O;stannicchloride,crystal;Tin(IV) chloride hydrate;Stannic chloride hydrated;tin chloride pentahydrate;STANNIC CHLORIDE 5HYD LUMP;Tin tetrachloride hydrated
CBNumber:
CB2397991
Molecular Formula:
Cl4H10O5Sn
Formula Weight:
350.6
MOL File:
10026-06-9.mol

Stannic chloride pentahydrate Properties

Melting point:
56 °C
Density 
2.040
form 
lumps
color 
Light Yellow
Water Solubility 
soluble
Merck 
14,8774
Stability:
Stable, but may decompose in contact with moisture or water. Incompatible with strong acids.
InChIKey
KHMOASUYFVRATF-UHFFFAOYSA-J
CAS DataBase Reference
10026-06-9(CAS DataBase Reference)
EPA Substance Registry System
Stannane, tetrachloro-, pentahydrate(10026-06-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C
Risk Statements  34-52/53
Safety Statements  26-36/37/39-45-7/8-61
RIDADR  UN 2440 8/PG 3
WGK Germany  3
RTECS  XP8870000
HazardClass  8
PackingGroup  III
HS Code  28273990
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Stannic chloride pentahydrate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 244678 Tin(IV) chloride pentahydrate 98% 10026-06-9 5g $38.5 2018-11-13 Buy
Sigma-Aldrich 244678 Tin(IV) chloride pentahydrate 98% 10026-06-9 1kg $249 2018-11-13 Buy
Strem Chemicals 93-5023 Tin(IV) chloride pentahydrate, 98% 10026-06-9 100g $34 2018-11-13 Buy
Strem Chemicals 93-5023 Tin(IV) chloride pentahydrate, 98% 10026-06-9 500g $129 2018-11-13 Buy
Sigma-Aldrich 244678 Tin(IV) chloride pentahydrate 98% 10026-06-9 100g $48.8 2018-11-13 Buy

Stannic chloride pentahydrate Chemical Properties,Uses,Production

Physical Properties

Colorless fuming liquid; corrosive; density 2.234 g/mL; freezes at –33°C; boils at 114.15°C; critical temperature 318.75°C; critical pressure 37.98 atm; critical volume 351 cm3/mol; soluble in cold water, evolving heat; decomposed by hot water; soluble in alcohol, benzene, toluene, chloroform, acetone and kerosene.
The pentahydrate is a yellowish-white crystalline solid or small, fused lumps; faint odor of HCl; density 2.04 g/cm3; decmposes at 56°C; very soluble in water; soluble in ethanol.

Uses

Tin(IV) chloride is a mordant for dying fabrics; a stabilizer for perfume in soap; used in weighting silk; in ceramic coatings; in manufacturing blue print papers; and to produce fuchsin. Also, tin(IV) chloride is used in preparing many organotin compounds.

Preparation

Tin(IV) chloride is prepared by reacting tin or tin(II) chloride with chlorine:
Sn + 2Cl2 → SnCl4
SnCl2 + Cl2 → SnCl4

Chemical Properties

White solid. Soluble in water or alcohol.

Chemical Properties

Stannic chloride is a white to yellow powder with a faint odor of HCl.

Uses

Substitute for anhydrous stannic chloride where the presence of water is not objectionable

General Description

Stannic chloride pentahydrate is a white colored solid. Stannic chloride pentahydrate is soluble in water. Stannic chloride pentahydrate is toxic by ingestion, inhalation and skin absorption. Stannic chloride pentahydrate is used to make perfumes and dyes.

Air & Water Reactions

Soluble in water. Reacts with water to form Hydrochloric Acid in dense white fumes [Merck 11th ed. 1989].

Reactivity Profile

Acidic salts, such as STANNIC CHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Hazard

Toxic material

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

Safety Profile

A poison by intraperitoneal and intravenous routes. Mutation data reported. A corrosive liquid. When heated to decomposition it emits toxic vapors of tin and Cl-.

Potential Exposure

Hydrated stannic chloride is used for fixing certain textile dyes, and for treating silk to give weight to the fabric.

First aid

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.

Shipping

UN2440 Stannic chloride, pentahydrate, Hazard class: 8; Labels: 8-Corrosive material.

Incompatibilities

Reacts violently with water, forming corrosive hydrochloric acid and tin oxide fumes. Reacts with turpentine, alcohols, and amines, causing fire and explosion hazard. Attacks many metals; some forms of plastics, rubber, and coatings. Reacts with moist air to form hydrochloric acid and dense white fume.

Stannic chloride pentahydrate Preparation Products And Raw materials

Raw materials

Preparation Products


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