Methyl 3-(4-methoxyphenyl)-3-oxopropionate
- CAS No.
- 22027-50-5
- Chemical Name:
- Methyl 3-(4-methoxyphenyl)-3-oxopropionate
- Synonyms
- EINECS 244-732-0;CBI-BB ZERO/004684;MTHYL4-METHOXYBENZOYLACETATE;METHY 4-METHOXYBENZOYLACETATE;METHYL 4-METHOXYBENZOYLACETATE;Methyl 4-methoxy-β-oxobenzenepropanoate;Methyl-3-(p-methoxyphenyl)-3-oxopropionat;METHYL 3-(4-METHOXYPHENYL)-3-OXOPROPANOATE;Methyl 3-(4-methoxyphenyl)-3-oxopropionate;methyl 3-(p-methoxyphenyl)-3-oxopropionate
- CBNumber:
- CB2666336
- Molecular Formula:
- C11H12O4
- Molecular Weight:
- 208.21
- MDL Number:
- MFCD01082033
- MOL File:
- 22027-50-5.mol
- MSDS File:
- SDS
| Product description | Number | Pack Size | Price |
| Methyl3-(4-Methoxyphenyl)-3-oxopropionate | M338603 | 100mg | $45 |
| Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 126241 | 5g | $54 |
| Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 126241 | 1g | $18 |
| Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 126241 | 10g | $100 |
| 3-(4-Methoxyphenyl)-3-oxo-propionicacidmethylester | B823 | 100g | $131 |
| More product size | |||
| Melting point | 40-42°C |
|---|---|
| Boiling point | 135°C/0.27mm |
| Density | 1.147±0.06 g/cm3(Predicted) |
| storage temp. | Store at room temperature |
| pka | 10.31±0.25(Predicted) |
| Appearance | White to off-white Solid |
| CAS DataBase Reference | 22027-50-5(CAS DataBase Reference) |
| EPA Substance Registry System | Methyl 4-methoxy-.beta.-oxobenzenepropionate (22027-50-5) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P305+P351+P338 |
Methyl 3-(4-methoxyphenyl)-3-oxopropionate price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | M338603 | Methyl3-(4-Methoxyphenyl)-3-oxopropionate | 22027-50-5 | 100mg | $45 | 2021-12-16 | Buy |
| Matrix Scientific | 126241 | Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 22027-50-5 | 5g | $54 | 2021-12-16 | Buy |
| Matrix Scientific | 126241 | Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 22027-50-5 | 1g | $18 | 2021-12-16 | Buy |
| Matrix Scientific | 126241 | Methyl3-(4-methoxyphenyl)-3-oxo-propionate >95% | 22027-50-5 | 10g | $100 | 2021-12-16 | Buy |
| AK Scientific | B823 | 3-(4-Methoxyphenyl)-3-oxo-propionicacidmethylester | 22027-50-5 | 100g | $131 | 2021-12-16 | Buy |
Methyl 3-(4-methoxyphenyl)-3-oxopropionate Chemical Properties,Uses,Production
Chemical Properties
Pale yellow solid
Synthesis
616-38-6
100-06-1
22027-50-5
Step 1. A solution of p-methoxyacetophenone (30 g, 200 mmol, 1.00 eq.) was added to a 500-mL three-necked round-bottom flask. Sodium hydride (13.6 g, 340 mmol, 1.70 equiv, 60% dispersed in mineral oil) was added in batches. The reaction was stirred at 50 °C for 10 minutes. The reaction mixture was slowly poured into 400 mL of ice water and the resulting solution was washed with ether (50 mL x 2) and subsequently acidified with acetic acid. The aqueous phase was extracted with ethyl acetate (200 mL x 3) and the organic phases were combined. The organic phase was dried sequentially with saturated sodium bicarbonate solution and sodium sulfate. The organic phase was concentrated under reduced pressure to give 37 g (87% yield) of methyl 3-(4-methoxyphenyl)-3-oxopropionate as a yellow oil.
References
[1] Chemistry - A European Journal, 2017, vol. 23, # 41, p. 9716 - 9720
[2] Chemistry - A European Journal, 2018, vol. 24, # 32, p. 8092 - 8097
[3] Molecules, 2015, vol. 20, # 9, p. 17275 - 17287
[4] Synthesis (Germany), 2016, vol. 48, # 5, p. 772 - 782
[5] Angewandte Chemie - International Edition, 2017, vol. 56, # 43, p. 13319 - 13323
Methyl 3-(4-methoxyphenyl)-3-oxopropionate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | +86-（0）57185586718; +8613336195806 | sales@capot.com | China | 29735 | 60 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49975 | 58 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29798 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
| Baoji Guokang Healthchem co.,ltd | +8615604608665 15604608665 | dominicguo@gk-bio.com | CHINA | 9414 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 | info@dycnchem.com | China | 52846 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49944 | 58 |
View Lastest Price from Methyl 3-(4-methoxyphenyl)-3-oxopropionate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2020-01-01 | Methyl 3-(4-methoxyphenyl)-3-oxopropionate
22027-50-5
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- Methyl 3-(4-methoxyphenyl)-3-oxopropionate
22027-50-5
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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